File name: Pandora249s1_ChicagoIL_20241008_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20241009T145258.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20241008_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20241008 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241008T122853.3Z 9047.520062 50 1 55.08 2 84.85 103.11 145.52 79.41 0.00 1 0.00 1 0 25 6.605e-01 4.621e-02 2.545e-01 1.596e-02 1.040183e+00 9.464224e-03 1.341122e-02 -6.000000e+00 3.952333e-01 226.38 -2.00 3.53 -2.00 322.03 0.00e+00 -2.864375e-02 3.783756e-03 7.248434e-03 -6.000000e+00 1.764955e-02 283.16 -2.00 20.00 -2.00 321.51 0.00e+00 9.602 0.017 302.00 328.00 3 2.9570e-01 3.2448e-02 1.1036e-01 -6.0000e+00 9.7785e-01 1.9945e+00 3.8275e-02 5.4573e-02 -6.0000e+00 1.0586e+00 -2.2872e+00 2.3545e-02 3.4828e-02 -6.0000e+00 6.3152e-01 8.4105e-01 1.2772e-02 2.1365e-02 -6.0000e+00 2.7076e-01 1.1105e-05 -2.3060e-03 4.1960e-04 5.1446e-04 -6.0000e+00 2.0271e-02 -8.6427e-03 0.0000e+00 12 8 8 10 0 0 0.34 24.90 1.24 -0.00864 -0.02597 45 5 1 5 0 1223.960 32.25 19.96 24.90 16.98 9.5 911.54 900000 77373 17451 74349 -11814 85255 45227 -53562 90583 126333 16514 9999 95576 432411 18526 58425 10449 115163 18539 126678 104487 -8789 -58683 36700 66524 -38648 157506 150911 -2260 17567 900000 128124 -56030 -56887 55115 3710 -6431 30347 37353 6027 199697 -678 101749 106219 21786 3040 22020 -46546 150446 -4749 115874 900000 59693 29206 27743 103242 41846 85112 18339 9728 -23872 78161 225796 21716 24865 46935 19706 23645 30358 1349 14614 18537 73269 -3778 8830 3151 -45413 6140 -58974 -7544 -11448 -6643 14264 18158 31511 16931 14920 11370 11711 7556 -8857 10926 -2398 6759 11326 -7070 -11056 3854 6111 616 1441 -5839 -1064 -6992 2105 -1685 -1924 -396 -5965 -3088 -3546 -758 1257 -743 1425 -4591 303 864 -1897 1868 -2775 590 -274 770 642 5770 9920 1276 -1961 422 432 -2162 4811 2457 -428 1815 -2092 -1676 16 216 -747 367 -649 900000 4313 1606 3277 -996 2532 1983 -7045 3203 3395 1378 905 3785 6727 1703 3718 1079 4072 1652 3583 3399 -820 -8880 2336 3575 -6395 3564 3201 -185 1043 900000 2718 -8083 -8528 2572 268 -509 1846 2536 673 3672 -98 5181 4807 2064 314 1918 -7044 3511 -547 4326 900000 4736 3408 3539 6585 5143 6753 2653 1377 -4308 4985 3513 2872 3443 5330 2943 3531 4628 311 3274 4210 9575 -999 1841 608 -12788 1012 -20184 -1796 -3366 -2181 4327 5791 9363 6137 5733 4617 4700 3045 -3955 3773 -929 2503 4511 -3970 -7619 2662 4649 522 1184 -4742 -738 -4819 1349 -1187 -1440 -315 -5577 -3233 -4337 -1021 1785 -1106 2059 -6885 429 1248 -2943 2886 -4464 878 -390 1047 849 7073 11466 1657 -2963 731 867 -4538 10309 5852 -1137 5034 -6258 -5060 48 617 -2005 895 -1496 SS 20241008T124018.2Z 9047.527989 53 1 54.50 2 82.79 105.07 143.53 81.73 0.00 1 0.00 1 0 25 6.959e-01 1.657e-02 1.814e-01 2.835e-03 8.870431e-01 1.619762e-03 9.929813e-03 -6.000000e+00 4.163103e-01 226.38 -2.00 3.53 -2.00 321.66 0.00e+00 2.882103e-03 9.046958e-04 1.076446e-03 -6.000000e+00 1.853858e-02 283.15 -2.00 20.00 -2.00 321.17 0.00e+00 7.344 0.007 302.00 328.00 3 4.8302e-01 6.0090e-03 8.6481e-02 -6.0000e+00 1.0300e+00 5.3570e-01 8.7323e-03 5.0234e-02 -6.0000e+00 1.1149e+00 -6.7933e-01 8.8328e-03 2.7101e-02 -6.0000e+00 6.6519e-01 2.7041e-01 4.0309e-03 9.6031e-03 -6.0000e+00 2.8414e-01 1.0724e-04 -1.2916e-03 7.6519e-05 1.3293e-04 -6.0000e+00 2.1328e-02 -9.1401e-03 0.0000e+00 12 8 8 10 0 0 44.44 24.93 0.48 -0.00914 -0.01885 176 18 1 5 0 309.590 32.25 20.06 24.93 17.87 9.6 918.61 900000 -177188 -236467 -186116 -215589 -235332 -247800 -260906 -77895 124902 -246315 -187474 -134115 -55859 -164085 -11730 -121099 -19748 -69921 -67793 65589 -70676 -103001 -71586 10789 -112805 15757 -49363 -16745 -96558 202385 15812 -54993 -29662 27453 -16062 -8271 11886 25101 20761 51356 5120 17284 18205 3182 15943 19779 -6314 45619 18227 24963 33012 22025 16200 20620 20183 19299 24605 7121 12308 1924 10718 25418 11789 14479 13472 6424 7108 7227 4826 5380 7757 10788 2119 5069 1229 -6129 573 -6822 -1187 -1966 400 -703 -244 1977 975 -587 -122 -79 -744 -841 329 -1816 -836 -860 -2841 -1929 -1426 -848 -465 -919 -1449 -879 -1706 -745 -2196 -1415 -1398 -1877 -552 -529 -325 178 -27 236 -105 388 325 120 272 381 623 611 644 849 1672 1385 1494 783 457 580 36 588 489 -173 -96 -78 -126 -598 -87 -186 -362 -738 900000 -1425 -3804 -1824 -2655 -3312 -3986 -5180 -274 345 -5448 -2591 -1348 -337 -3794 -74 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4.4692e-01 2.0895e-03 7.0785e-02 -6.0000e+00 6.9797e-01 1.5512e-01 2.8128e-03 4.0605e-02 -6.0000e+00 7.5553e-01 -1.5572e-01 2.8472e-03 2.1151e-02 -6.0000e+00 4.5077e-01 5.1095e-02 1.3842e-03 7.4529e-03 -6.0000e+00 1.9257e-01 4.5613e-04 -6.0997e-04 3.2858e-05 8.6740e-05 -6.0000e+00 1.4452e-02 -9.7307e-03 0.0000e+00 11 8 0 10 0 0 52.04 24.98 0.41 -0.00973 -0.01431 387 39 1 5 0 140.720 32.25 19.99 24.98 18.82 9.5 924.35 900000 -111909 -152022 -156079 -123283 -192048 -176714 -170954 -108094 -109282 -165715 -123458 -99535 -99936 -98116 -42742 -67420 -18276 -24168 -64695 -35393 -47660 -53094 -49262 -42322 -47537 -27932 -37021 -32149 -49865 -17927 -13007 -18843 -20363 -10008 -7032 -9781 -5862 3595 2602 5656 968 2654 -182 545 1309 3401 229 3171 476 3412 5111 5406 4541 3003 2742 3621 2430 253 973 1414 1928 3864 2389 2714 2817 1542 1522 1647 1062 1000 1543 1417 -289 351 -700 -2016 -1453 -2266 -990 -1654 -1170 -1125 -1313 -440 -752 -475 -21 341 452 450 1016 147 600 383 -183 -45 170 23 -99 -416 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