File name: Pandora249s1_ChicagoIL_20241014_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20241015T054407.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20241014_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20241014 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241014T141650.9Z 9053.595033 201 1 38.32 2 68.01 125.23 145.98 336.29 0.00 1 0.00 1 0 25 2.434e-02 5.629e-03 5.285e-03 1.037e-03 3.870017e-01 5.443729e-04 4.684438e-03 -6.000000e+00 1.452047e-02 225.69 -2.00 3.53 -2.00 317.95 0.00e+00 3.899172e-04 9.681842e-05 1.348045e-04 -6.000000e+00 6.463140e-04 282.40 -2.00 20.00 -2.00 317.25 0.00e+00 2.648 0.000 302.00 328.00 3 3.4316e+00 1.4480e-03 3.2698e-02 -6.0000e+00 3.5876e-02 4.9500e-02 1.6367e-03 1.9987e-02 -6.0000e+00 3.8861e-02 -2.1266e-02 1.0564e-03 9.9072e-03 -6.0000e+00 2.3187e-02 5.5858e-03 5.4418e-04 2.8472e-03 -6.0000e+00 9.9110e-03 7.8014e-04 -4.6815e-04 3.1850e-05 3.5934e-05 -6.0000e+00 7.4572e-04 -8.6506e-03 0.0000e+00 12 1 1 12 1 1 99.99 24.81 0.27 -0.00865 -0.01217 165 24 1 5 0 230.820 32.25 19.92 24.81 14.59 9.4 895.47 900000 -6676 -11694 -4494 -9734 -6647 -10316 -10649 -4536 -3206 -7120 -5244 -6046 -1680 -3378 1003 -2372 997 -304 -457 1838 663 -1518 -497 603 -3045 106 -529 -794 -1185 1668 1476 -674 -1231 -261 -1402 -1410 -507 -284 -554 -502 -770 -33 -101 449 329 118 -623 298 420 794 1465 1438 1073 788 1268 902 907 480 642 689 1289 1837 1045 445 218 -158 124 525 337 -82 -331 -175 -397 -448 -260 44 -93 -528 -425 -1001 -1305 -1506 -1564 -1002 -972 -642 -303 -136 0 238 647 415 956 1087 567 521 503 21 -190 -384 -540 -104 99 -467 -915 -625 -476 -333 141 111 -155 26 38 127 488 657 532 211 -242 -448 -184 -152 24 456 373 660 1062 822 573 347 100 263 295 0 -147 -226 -122 -473 -339 -156 -386 -186 900000 -393 -777 -277 -591 -368 -603 -686 -309 -234 -565 -427 -553 -173 -416 136 -366 159 -47 -75 302 112 -266 -91 116 -641 22 -108 -156 -230 331 325 -168 -329 -69 -366 -383 -155 -95 -220 -226 -347 -15 -48 216 159 57 -302 143 204 405 801 848 629 488 808 592 599 315 414 450 883 1273 793 354 170 -118 90 392 279 -71 -306 -164 -364 -386 -218 33 -67 -389 -345 -872 -1206 -1526 -1595 -1079 -1118 -738 -361 -164 0 264 699 441 971 1139 618 604 620 28 -250 -512 -668 -125 117 -580 -1156 -829 -632 -468 202 171 -239 40 59 183 687 898 742 312 -363 -693 -283 -228 35 656 512 909 1438 1171 845 526 159 415 484 1 -258 -394 -218 -853 -602 -277 -658 -320 SS 20241014T142052.0Z 9053.597824 204 1 50.71 2 67.41 126.09 146.24 337.92 0.00 1 0.00 1 0 17 5.969e-02 9.232e-03 2.069e-02 3.113e-03 3.758741e-01 1.638790e-03 4.590520e-03 -6.000000e+00 3.560637e-02 225.69 -2.00 3.53 -2.00 318.61 0.00e+00 8.755536e-04 3.460926e-04 2.874865e-04 -6.000000e+00 1.585235e-03 282.40 -2.00 20.00 -2.00 317.92 0.00e+00 2.582 0.000 302.00 328.00 3 5.4825e+00 4.4355e-03 3.1965e-02 -6.0000e+00 8.7972e-02 8.5318e-02 5.0637e-03 1.9731e-02 -6.0000e+00 9.5299e-02 -4.1111e-02 3.4433e-03 9.7441e-03 -6.0000e+00 5.6862e-02 1.5862e-02 1.7948e-03 2.9249e-03 -6.0000e+00 2.4298e-02 1.0675e-04 -8.9517e-04 9.7615e-05 3.6467e-05 -6.0000e+00 1.8292e-03 -6.9873e-03 0.0000e+00 12 9 1 12 1 1 100.00 24.82 0.57 -0.00699 -0.01371 52 6 1 5 0 956.670 32.25 19.95 24.82 14.86 9.5 898.01 900000 -16007 -33168 -6154 -17495 6596 -19330 -16647 -819 23107 -11911 -20290 -496 14621 -11648 1070 -6198 6488 -281 5456 8900 -1035 -7831 -4003 644 -14326 4033 1211 -262 3706 12746 4849 -3349 -6324 4828 -4239 -2343 1022 48 -2597 2501 -1942 2445 1589 -1014 -678 749 -4121 2576 -1696 1441 3279 2894 1600 614 2775 438 2164 257 1221 -2195 3145 4446 714 710 1384 -690 -169 -165 -1278 -810 475 1273 -1133 -177 -53 -2820 -284 -4318 -1097 -2143 -1087 -1154 -862 378 -202 -107 184 186 159 -137 657 -123 1111 926 -778 548 -36 586 230 -220 -705 372 -304 -201 -735 -640 -582 24 -85 -96 83 80 -128 -57 -329 494 537 -512 -65 -419 -426 -151 366 221 889 1299 869 753 636 125 -117 1251 629 -195 115 -265 -304 -664 -85 -542 18 -520 900000 -807 -2124 -299 -887 246 -945 -864 -41 975 -741 -1429 -32 941 -1146 106 -726 713 -35 667 1083 -140 -1153 -593 97 -2626 627 189 -40 529 1741 790 -654 -1355 922 -862 -486 232 13 -858 889 -708 980 598 -394 -263 315 -1641 1052 -733 632 1382 1317 785 319 1459 241 1179 141 653 -1229 1762 2676 484 501 949 -457 -108 -109 -942 -659 406 1100 -978 -142 -39 -1928 -178 -2874 -779 -1746 -983 -1047 -830 382 -219 -123 218 224 188 -153 672 -118 1096 863 -808 629 -47 753 304 -282 -910 440 -355 -246 -963 -813 -778 33 -129 -154 130 134 -206 -85 -464 672 745 -754 -101 -674 -683 -236 549 317 1207 1819 1204 1095 924 195 -194 2102 1102 -336 208 -500 -587 -1297 -163 -1004 31 -890 SS 20241014T143438.6Z 9053.607391 210 1 53.18 2 65.38 129.08 146.98 343.64 0.00 1 0.00 1 0 17 5.254e-02 9.349e-03 1.506e-02 2.830e-03 3.495357e-01 1.475668e-03 4.269026e-03 -6.000000e+00 3.134094e-02 225.69 -2.00 3.53 -2.00 318.23 0.00e+00 9.042671e-04 2.807980e-04 1.076903e-04 -6.000000e+00 1.395378e-03 282.40 -2.00 20.00 -2.00 317.53 0.00e+00 2.384 0.000 302.00 328.00 3 5.6424e+00 3.9525e-03 2.9546e-02 -6.0000e+00 7.7433e-02 8.6157e-02 4.4913e-03 1.8170e-02 -6.0000e+00 8.3883e-02 -3.8301e-02 2.9209e-03 9.0126e-03 -6.0000e+00 5.0051e-02 1.3814e-02 1.5047e-03 2.6587e-03 -6.0000e+00 2.1387e-02 1.1379e-04 -7.2854e-04 8.8122e-05 3.2744e-05 -6.0000e+00 1.6101e-03 -6.7704e-03 0.0000e+00 12 8 8 10 0 0 99.94 24.87 0.04 -0.00677 -0.01224 20 2 1 5 0 2658.510 32.25 20.06 24.87 15.23 9.3 897.61 900000 -7842 -22516 4225 -20852 27384 -9621 -27063 1504 -3045 2659 -17568 -1890 9722 -1756 1492 -3402 2727 -2345 12339 6725 -1395 -5487 396 1211 -9575 2320 2541 -159 8873 6581 5306 -4008 -1474 807 -329 -3652 -216 134 -3486 1879 -2233 479 2031 -398 -555 916 -3853 1116 -895 2065 3626 1074 -74 143 3133 63 1689 -240 882 -1835 2295 3646 495 1191 691 -675 -160 -669 -211 -1 867 1527 -1337 -589 624 -2845 -633 -3752 -1429 -2301 -1825 -903 -526 535 -289 338 -46 503 80 -270 597 393 758 1060 -344 171 422 915 -338 -183 -919 -366 -895 -495 -751 -1038 -109 137 674 232 819 -123 -244 199 -148 1076 384 -426 -516 -751 -589 62 164 291 922 948 887 481 589 71 -481 948 978 -395 -122 -314 -557 -165 140 -423 -174 -172 900000 -491 -1740 247 -1456 1103 -566 -2061 96 -219 187 -1566 -159 842 -199 186 -487 389 -370 1750 1037 -235 -975 69 222 -2051 448 477 -29 1455 1150 1028 -935 -356 189 -76 -901 -58 43 -1356 711 -948 206 881 -178 -248 403 -1756 481 -397 927 1719 560 -41 84 1833 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