File name: Pandora249s1_ChicagoIL_20241216_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20241217T055357.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20241216_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20241216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241216T164224.3Z 9116.696115 392 1 56.04 2 67.00 163.94 103.92 328.28 0.00 1 0.00 1 0 17 1.913e-01 2.902e-02 7.664e-02 8.696e-03 3.179508e-01 4.480534e-03 4.025952e-03 -6.000000e+00 1.128798e-01 222.57 -2.00 3.53 -2.00 318.02 0.00e+00 3.588983e-04 7.743784e-04 1.390322e-04 -6.000000e+00 4.928650e-03 275.02 -2.00 20.00 -2.00 317.45 0.00e+00 2.540 0.000 302.00 328.00 3 6.9707e+00 1.1817e-02 2.9632e-02 -6.0000e+00 2.7767e-01 2.2005e-01 1.3374e-02 1.6545e-02 -6.0000e+00 3.0170e-01 -8.1188e-02 8.5348e-03 8.2651e-03 -6.0000e+00 1.7963e-01 3.7855e-02 4.3712e-03 2.3798e-03 -6.0000e+00 7.6860e-02 2.6348e-05 -1.0897e-03 2.7294e-04 3.1726e-05 -6.0000e+00 5.8534e-03 -1.6523e-02 0.0000e+00 12 9 8 11 8 0 99.21 25.00 -0.64 -0.01652 -0.02471 15 2 1 5 0 3735.300 32.25 20.01 25.00 16.31 9.4 906.00 900000 -10298 -35235 -3588 -37432 185416 -5834 -33277 -6813 21069 6895 -43078 19851 44894 -4363 -1260 -2513 21058 4748 43894 8252 535 -9261 3733 14125 -18664 2438 18457 8582 32306 2886 8240 394 -10362 1178 -2227 -10747 3074 2894 -4902 6304 -6611 2040 4364 2708 -7470 3002 -3619 3342 -4684 4247 11878 692 -1443 1136 12046 -1880 4295 2649 369 -4798 4274 9046 -501 3061 2211 -2097 668 -2523 -4205 -202 1147 7781 -3844 -1196 3995 -9455 -3030 -12799 -3756 -5036 -3294 -3109 251 4794 -382 2081 807 2469 1675 -1824 1026 -113 -2404 -367 -4033 -3056 18 3484 920 -444 -892 -223 -5126 2605 -1721 -325 -159 378 1613 250 4191 541 -280 -728 -2138 1428 1357 -1158 414 -2852 -270 -83 -248 781 2829 2635 857 416 334 -581 -1128 4219 3679 -1471 712 -2179 -1351 -83 467 -2331 -519 1043 900000 -889 -4128 -301 -4068 2001 -423 -3412 -593 1494 579 -6077 1607 3218 -589 -185 -405 3089 776 5508 1511 106 -2034 744 2671 -5112 548 3427 1659 4739 580 1691 95 -2935 295 -555 -2989 831 922 -1987 2576 -3302 970 2065 1304 -3965 1420 -1795 1522 -2308 1973 5438 378 -850 681 6649 -1214 2619 1617 227 -3121 2656 5784 -379 2315 1641 -1521 451 -1788 -3309 -169 1009 6531 -3543 -1013 2937 -7175 -2006 -9333 -2713 -4146 -2971 -3050 253 4874 -436 2452 1003 3057 2051 -2187 1102 -112 -2319 -352 -4329 -3607 23 4632 1287 -607 -1139 -262 -6184 3041 -2236 -438 -224 557 2265 378 6336 844 -420 -1122 -3106 1927 1857 -1705 637 -4700 -434 -130 -376 1119 3770 3351 1083 546 470 -880 -1794 6529 5893 -2595 1294 -3838 -2409 -148 816 -4444 -930 1778 SS 20241216T171020.8Z 9116.715518 408 1 54.50 2 65.87 170.83 106.35 333.86 0.00 1 0.00 1 0 17 8.407e-03 5.138e-03 5.366e-04 2.285e-04 3.085823e-01 1.191050e-04 3.801798e-03 -6.000000e+00 4.962389e-03 222.57 -2.00 3.53 -2.00 316.58 0.00e+00 2.471667e-04 1.433820e-05 6.066085e-05 -6.000000e+00 2.166273e-04 275.02 -2.00 20.00 -2.00 316.02 0.00e+00 2.429 0.000 302.00 328.00 3 1.2799e+00 3.0697e-04 2.8256e-02 -6.0000e+00 1.2207e-02 2.4347e-02 3.4316e-04 1.5598e-02 -6.0000e+00 1.3262e-02 -1.3609e-02 2.0206e-04 7.8050e-03 -6.0000e+00 7.8956e-03 3.9674e-03 9.7080e-05 2.2730e-03 -6.0000e+00 3.3800e-03 9.5230e-03 -3.6544e-04 7.0358e-06 3.0313e-05 -6.0000e+00 2.5720e-04 -1.9363e-02 0.0000e+00 10 0 0 10 0 0 99.98 25.06 0.30 -0.01936 -0.02211 1411 143 1 5 0 38.620 32.25 20.01 25.06 17.10 9.6 912.45 900000 -2024 -2003 -2779 -3056 -2788 -2493 -1717 -865 -1152 -1852 -1756 -1384 -891 -595 13 -80 270 763 605 894 956 933 570 521 255 -18 -297 26 305 583 1347 858 -38 -798 -886 -993 -885 -162 -337 -623 -629 -474 -401 -340 -258 -265 -386 -259 83 494 700 963 828 765 766 731 632 544 749 971 1105 1248 952 310 82 -130 -90 303 498 145 -128 -210 -154 -176 -179 -94 -13 -89 -375 -807 -1074 -1533 -1524 -1187 -911 -640 -270 -190 -112 211 372 424 758 945 737 668 414 -14 -172 -321 -517 -183 222 -299 -611 -752 -443 -340 20 132 -182 -93 -73 55 371 534 557 383 33 -238 -106 -80 71 423 375 622 1036 824 517 311 99 -2 170 -8 -86 -47 -4 -346 -372 -240 -399 -408 900000 -301 -317 -439 -491 -416 -371 -276 -141 -204 -342 -333 -283 -208 -147 4 -23 80 235 194 294 317 313 200 181 93 -7 -109 9 109 213 493 343 -15 -321 -369 -400 -401 -81 -189 -375 -389 -304 -263 -225 -170 -174 -250 -165 53 325 467 685 597 578 570 557 486 414 561 734 877 1026 812 276 71 -111 -74 252 435 136 -124 -207 -149 -168 -162 -80 -11 -75 -328 -736 -1057 -1595 -1627 -1295 -1026 -762 -324 -231 -135 246 414 448 785 992 811 765 512 -17 -225 -418 -648 -220 260 -359 -761 -988 -592 -465 28 192 -269 -136 -106 75 503 699 741 522 47 -342 -153 -116 100 582 506 823 1336 1105 724 440 147 -3 261 -13 -138 -77 -6 -576 -612 -392 -644 -637 SS 20241216T171447.9Z 9116.718610 411 1 54.41 2 65.75 171.94 106.70 334.77 0.00 1 0.00 1 0 17 1.598e-02 5.099e-03 5.883e-03 1.554e-03 3.092869e-01 8.068906e-04 3.798965e-03 -6.000000e+00 9.431596e-03 222.57 -2.00 3.53 -2.00 317.56 0.00e+00 1.953218e-04 1.243825e-04 7.847664e-05 -6.000000e+00 4.116956e-04 275.02 -2.00 20.00 -2.00 317.00 0.00e+00 2.418 0.000 302.00 328.00 3 4.7281e+00 2.1141e-03 2.8249e-02 -6.0000e+00 2.3201e-02 6.5137e-02 2.3746e-03 1.5768e-02 -6.0000e+00 2.5204e-02 -1.6777e-02 1.4827e-03 7.8980e-03 -6.0000e+00 1.5006e-02 4.8424e-03 7.5266e-04 2.2988e-03 -6.0000e+00 6.4247e-03 2.9951e-04 -3.5297e-04 4.8648e-05 2.9822e-05 -6.0000e+00 4.8877e-04 -2.0249e-02 0.0000e+00 10 0 0 10 0 0 100.00 25.07 0.13 -0.02025 -0.02290 202 20 1 5 0 269.320 32.25 20.01 25.07 17.48 9.6 916.17 900000 -2052 -3780 -3422 -5742 -8774 -3679 -5630 1811 2815 -4016 -3082 -888 163 -5351 1712 -265 558 2224 -307 2615 604 -1155 333 42 -2491 2100 -1646 70 -2457 2185 2305 -1848 -1841 -518 -1686 -953 -392 312 -364 653 -673 60 148 -504 -596 -42 -1275 315 -170 1067 1784 658 825 822 639 774 775 408 252 258 983 1885 1017 316 749 -497 4 316 -157 167 258 474 -118 -187 -432 -658 -151 -1519 -620 -1223 -1096 -1288 -1227 -620 -721 -260 -108 61 197 561 421 195 532 403 323 512 452 233 247 -129 -698 -224 -174 -361 -779 -570 -511 -467 219 211 15 58 -124 -167 20 89 375 225 85 -283 -8 151 173 427 533 501 773 690 204 200 23 270 239 -141 54 75 -88 -204 -247 -189 -375 -451 900000 -177 -352 -315 -502 -735 -293 -497 165 276 -436 -340 -104 22 -863 291 -50 110 450 -66 562 134 -263 78 10 -665 545 -432 17 -595 518 589 -536 -566 -156 -498 -288 -132 112 -156 313 -353 33 82 -282 -334 -23 -703 168 -92 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