File name: Pandora249s1_ChicagoIL_20241221_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20241222T055325.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora249_OF_v2d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20241221_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20241221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241221T135220.9Z 9121.578019 291 1 53.72 2 85.24 127.72 52.84 240.58 0.00 1 0.00 1 0 25 8.987e-01 9.977e-02 3.010e-01 2.971e-02 1.195604e+00 1.886023e-02 1.633275e-02 -6.000000e+00 5.579479e-01 222.74 -2.00 3.53 -2.00 321.24 0.00e+00 -4.801991e-02 3.850791e-03 2.331958e-03 -6.000000e+00 2.677127e-02 274.72 -2.00 20.00 -2.00 320.54 0.00e+00 10.197 0.020 302.00 328.00 3 -1.8206e-02 5.4232e-02 1.2941e-01 -6.0000e+00 1.3730e+00 2.9115e+00 6.3040e-02 1.1657e-01 -6.0000e+00 1.5022e+00 -2.6338e+00 3.5067e-02 2.9837e-02 -6.0000e+00 8.9169e-01 8.1396e-01 1.9264e-02 3.9857e-02 -6.0000e+00 3.7642e-01 5.1249e-06 -3.4329e-03 7.2662e-04 6.2650e-04 -6.0000e+00 2.9331e-02 -8.6989e-03 0.0000e+00 12 8 8 10 0 0 53.02 23.23 2.04 -0.00870 -0.03450 29 3 1 5 0 1852.230 31.25 19.98 23.23 -2.19 8.9 779.22 900000 45858 8180 97219 -22578 900000 -26615 -36389 24013 900000 88919 14281 213120 900000 45228 900000 79529 900000 49485 900000 117049 38991 -8439 33891 114136 -24257 900000 900000 -4479 149082 900000 900000 -46949 -41232 900000 -3022 -2833 900000 17220 -27980 189489 24476 168125 101177 28509 -6326 106630 -59537 900000 -39260 900000 419712 65425 64013 25901 246396 639 350240 12269 34200 -47435 414751 900000 -3649 203811 141829 -8787 30041 78951 -15600 29202 74267 900000 -35942 70916 46739 -50130 25027 -66670 20958 -10592 6071 60880 47558 254636 52716 58026 46707 61057 16453 -26037 5526 -670 63294 55838 -11299 2569 22987 38599 10891 2023 -13442 13983 -25580 11857 685 2469 5558 967 4562 -2956 9362 2204 -819 623 -5111 13157 4714 -8274 2787 -5944 -2079 -6603 -7046 87 11528 17870 -6475 -3394 -767 -3392 -8814 19082 3992 -4584 5070 -3600 -5911 -2996 3535 869 4252 3569 900000 8715 1948 7718 -4671 900000 -5058 -9279 4159 900000 10268 3573 7178 900000 7399 900000 9392 900000 6883 900000 6758 4502 -1572 4803 8986 -8722 900000 900000 -870 5086 900000 900000 -11582 -9739 900000 -420 -387 900000 2621 -8298 7460 5332 8383 8763 4340 -1162 5597 -15312 900000 -8449 900000 12117 6525 7056 4554 7113 166 10111 2608 5026 -13569 11973 900000 -709 5884 7779 -1983 4809 9345 -4872 7082 12006 900000 -15875 9417 6746 -16787 3829 -27330 4114 -3363 1910 12654 12356 8821 14305 15244 13754 15159 6032 -13530 1962 -249 13156 14185 -6589 1528 12874 20726 8112 1600 -11293 7872 -19569 6230 421 1568 3675 745 3938 -3234 10379 2863 -1139 855 -7260 15344 6070 -12517 3855 -8786 -2785 -8654 -8868 99 11382 16250 -7739 -4458 -1169 -6228 -19415 35201 9381 -12784 13757 -10052 -17080 -9184 9765 2283 9833 7696 SS 20241221T140400.7Z 9121.586119 294 1 54.37 2 83.55 129.81 54.75 243.19 0.00 1 0.00 1 0 25 6.261e-01 2.665e-02 2.129e-01 5.464e-03 1.036059e+00 3.185953e-03 1.166507e-02 -6.000000e+00 3.707428e-01 222.74 -2.00 3.53 -2.00 322.11 0.00e+00 -3.546599e-03 1.672140e-03 3.345735e-03 -6.000000e+00 1.646824e-02 274.72 -2.00 20.00 -2.00 321.71 0.00e+00 8.066 0.010 302.00 328.00 3 5.4643e-01 1.1487e-02 9.7321e-02 -6.0000e+00 9.1434e-01 1.3846e+00 1.4746e-02 5.8295e-02 -6.0000e+00 9.9454e-01 -1.8180e+00 1.2680e-02 3.1696e-02 -6.0000e+00 5.9063e-01 7.3253e-01 6.1496e-03 1.0716e-02 -6.0000e+00 2.5241e-01 4.0129e-05 -2.5095e-03 1.4355e-04 1.9919e-04 -6.0000e+00 1.9191e-02 -1.1005e-02 0.0000e+00 12 8 8 10 0 0 38.60 23.25 0.70 -0.01101 -0.02986 106 11 1 5 0 512.880 31.25 19.25 23.25 -1.51 8.9 785.03 900000 -63267 -87088 12725 -60748 3276 -109636 -112688 -71968 900000 -90677 -98083 -28197 94731 -52539 900000 13068 76251 32602 47138 212146 54495 -13437 -21039 14881 -80057 345494 89367 1966 -26555 900000 122376 -26301 -23522 169138 -11392 34119 113616 52622 -633 185853 39574 78575 52135 23663 10572 71316 6477 264258 20199 108368 101452 61802 58111 46468 87826 29369 87820 21028 24653 3969 50016 70955 26008 44953 41143 15622 20786 34220 7846 18345 26483 33274 3426 18868 8618 -13342 7721 -15870 581 -3368 -1448 6780 2851 15418 5821 4979 651 6451 -480 -5968 -1230 -5818 -639 -2149 -7885 -5068 -3608 -1031 -2220 -2332 -3979 -2216 -4103 -2713 -3304 -2540 -1739 -4145 -811 -2168 -2206 -985 -229 -370 -523 843 -370 96 970 1128 1488 1768 2173 2659 2389 3575 1163 -75 269 760 123 2749 708 -83 667 -98 -898 -1041 -1 -593 -467 -1694 900000 -2511 -4385 216 -1823 44 -4299 -4637 -2056 900000 -3248 -3989 -655 780 -2264 900000 373 1218 821 1004 1130 950 -442 -764 396 -5620 1840 1038 50 -900 900000 1244 -1362 -1275 1441 -552 1036 1694 1681 -40 2078 2044 2803 2388 1386 681 2468 435 1407 1323 3232 3620 3620 3837 3687 4817 2956 4864 2150 2258 427 3489 4459 2922 4644 4623 2304 3044 4774 1608 3771 5303 6202 808 3426 1528 -2679 1254 -3617 134 -977 -487 2401 1148 5821 2551 2293 321 3006 -233 -2895 -538 -2612 -285 -1102 -5089 -3464 -2869 -911 -2112 -2179 -3469 -1690 -2954 -1946 -2519 -2040 -1500 -4093 -897 -2835 -2998 -1425 -338 -540 -748 1181 -540 145 1508 1740 2181 2666 3136 3705 3247 4716 1619 -118 460 1499 274 6013 1708 -218 1845 -281 -2443 -2819 -4 -1546 -1114 -3806 SS 20241221T141433.8Z 9121.593447 297 1 54.45 2 82.06 131.73 56.52 245.45 0.00 1 0.00 1 0 25 5.930e-01 2.042e-02 1.397e-01 2.739e-03 9.095498e-01 1.536476e-03 1.016333e-02 -6.000000e+00 3.500136e-01 222.74 -2.00 3.53 -2.00 321.53 0.00e+00 4.650775e-03 7.578079e-04 1.161752e-03 -6.000000e+00 1.526207e-02 274.72 -2.00 20.00 -2.00 321.11 0.00e+00 6.771 0.006 302.00 328.00 3 9.5335e-01 5.1214e-03 8.1693e-02 -6.0000e+00 8.6125e-01 6.5843e-01 7.2272e-03 4.9849e-02 -6.0000e+00 9.3578e-01 -8.8027e-01 7.4936e-03 2.7559e-02 -6.0000e+00 5.5717e-01 3.6288e-01 3.5361e-03 1.0088e-02 -6.0000e+00 2.3863e-01 1.0907e-04 -1.6913e-03 7.1344e-05 1.3845e-04 -6.0000e+00 1.8158e-02 -1.1188e-02 0.0000e+00 12 8 8 10 0 0 98.41 23.30 0.49 -0.01119 -0.02390 152 15 1 5 0 358.210 31.25 19.80 23.30 -0.78 8.9 789.07 900000 -210574 -203846 -155784 -199575 -91168 -212940 -227151 -207746 20013 -188716 -200459 -79714 49813 -149986 -4838 -50243 32978 -47967 -45347 31532 -22255 -73453 -63087 -33679 -97324 45287 -8042 -46588 -49156 900000 26001 -37713 -26992 61665 -6188 -6386 40710 14985 979 57694 31467 43308 19466 16159 11907 37138 10736 44036 22192 37840 37135 32144 26831 22192 24972 12480 28096 7104 14054 2146 17842 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