File name: Pandora249s1_ChicagoIL_20250310_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20250311T060924.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora249_OF_v3d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20250310_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20250310 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250310T124310.0Z 9200.529977 210 1 54.77 2 84.82 99.96 107.00 322.39 0.00 1 0.00 1 0 25 7.324e-01 5.185e-02 3.108e-01 1.997e-02 1.171328e+00 1.224841e-02 1.510421e-02 -6.000000e+00 4.489360e-01 225.74 -2.00 3.53 -2.00 322.16 0.00e+00 -3.890709e-02 4.300358e-03 1.286897e-03 -6.000000e+00 1.968493e-02 274.81 -2.00 20.00 -2.00 321.67 0.00e+00 9.591 0.016 302.00 328.00 3 3.8249e-01 4.0075e-02 1.2065e-01 -6.0000e+00 1.1064e+00 2.3309e+00 4.7737e-02 1.0097e-01 -6.0000e+00 1.1993e+00 -2.5472e+00 3.1471e-02 3.2222e-02 -6.0000e+00 7.1651e-01 9.1452e-01 1.7461e-02 3.6851e-02 -6.0000e+00 3.0614e-01 8.1086e-06 -2.6370e-03 4.9901e-04 5.8801e-04 -6.0000e+00 2.2806e-02 -1.4104e-02 0.0000e+00 12 8 8 10 0 0 23.31 24.57 1.53 -0.01410 -0.03392 35 4 1 5 0 1564.590 32.00 20.00 24.57 11.85 9.3 876.29 900000 125073 45061 101809 -31188 900000 -8656 -30101 64679 27976 42943 25409 137953 900000 40676 76215 52937 142908 137010 405915 165946 519 -51292 16158 87255 -62065 137075 98065 3025 15397 900000 900000 -49091 -36808 82153 29878 38618 125863 130957 4874 242715 48520 152155 160950 78150 -15422 69406 -14333 900000 -22602 208970 900000 43620 5539 21351 123685 20640 125601 5990 73845 -22934 100146 900000 -1277 101376 140181 6297 25868 49243 1091 37086 42406 155020 -21280 27020 78163 -46307 27917 -43341 -18114 312 -5659 22902 20424 81194 25081 27556 15948 11157 -4340 -4095 11506 1402 7824 14661 -15833 -2354 3073 12151 -4818 -6703 -11212 1775 -7877 9426 -1515 -3782 -3193 -12123 -1754 -2755 2320 557 94 800 1124 898 4788 -4575 1518 -1778 -1324 -465 495 3578 6292 8702 2691 -3831 -809 -466 -3163 4913 3403 -1275 1499 -78 -2043 -167 -3256 -34 1703 1071 900000 4864 3432 3629 -3335 900000 -631 -3170 3430 2423 3416 2470 4389 900000 3379 4446 3836 4042 3875 7892 3227 44 -7253 1314 4164 -14701 4361 3987 257 980 900000 900000 -6595 -4489 2904 1637 1911 2892 3472 560 4719 4460 4841 4267 4144 -1826 3190 -1444 900000 -2597 4063 900000 3817 705 2781 6253 3090 6594 967 5313 -3835 4673 900000 -191 5913 5724 992 3521 5841 238 6273 7173 8440 -6289 4361 6535 -11975 3365 -11545 -4367 75 -1695 5922 5957 13735 7803 8626 5675 4100 -1780 -1568 3557 474 2632 5245 -9082 -1396 2014 8222 -4094 -5683 -9112 1125 -5070 5132 -969 -2618 -2372 -11008 -1671 -3123 2869 766 134 1144 1571 1246 6526 -7107 2278 -2717 -1907 -625 631 4292 7156 9492 3213 -5527 -1346 -904 -7159 11330 7916 -3378 4134 -226 -6113 -487 -9410 -87 4337 2538 SS 20250310T125424.5Z 9200.537783 213 1 54.34 2 82.77 101.88 108.22 324.68 0.00 1 0.00 1 0 17 6.630e-01 1.685e-02 1.805e-01 3.222e-03 9.684096e-01 1.853781e-03 1.061506e-02 -6.000000e+00 3.966129e-01 225.74 -2.00 3.53 -2.00 321.78 0.00e+00 2.483538e-03 9.783678e-04 2.546442e-03 -6.000000e+00 1.743601e-02 274.81 -2.00 20.00 -2.00 321.37 0.00e+00 7.335 0.007 302.00 328.00 3 5.8047e-01 6.5776e-03 9.0399e-02 -6.0000e+00 9.8452e-01 7.0116e-01 9.9016e-03 5.9177e-02 -6.0000e+00 1.0680e+00 -8.5751e-01 1.0828e-02 3.1508e-02 -6.0000e+00 6.3253e-01 3.3924e-01 4.9898e-03 1.0747e-02 -6.0000e+00 2.6914e-01 8.6921e-05 -1.2830e-03 8.4829e-05 1.4775e-04 -6.0000e+00 2.0330e-02 -1.4735e-02 0.0000e+00 12 8 8 10 0 0 44.36 24.58 0.53 -0.01474 -0.02438 151 15 1 5 0 359.840 32.00 20.00 24.58 12.29 9.3 879.74 900000 -261703 -140581 -185532 -209709 -121627 -236036 -248331 -198599 900000 -224369 -225525 -42610 1951 -172176 -22527 -89189 -20254 -58602 -103870 12242 -86179 -94335 -87347 -77014 -138876 27532 -43630 -13690 -110169 900000 21966 -57502 -33687 32733 -25758 -7424 43278 24043 -9048 63942 7861 23367 14242 12214 19547 30485 10061 48025 9857 20862 41409 19995 21846 23862 26735 15398 29540 6812 17722 -863 16075 24778 8644 16896 16314 9645 5048 12004 7067 6535 11184 10863 5123 6040 3351 -6555 -71 -10794 -1101 -2474 230 135 -35 3704 979 57 474 214 -33 -159 308 -2640 -891 -501 -2560 -1982 -512 -1021 -479 -1145 -1053 -1129 -1927 -1622 -1832 -1116 -1075 -2361 -748 -696 -850 -149 -299 100 -202 381 347 -335 279 204 724 1278 1148 990 1525 1484 1140 564 353 579 365 364 668 -260 -63 224 15 -502 -98 -340 -495 -988 900000 -4781 -843 -1748 -2335 -521 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20.00 -2.00 320.47 0.00e+00 5.983 0.004 302.00 328.00 3 5.2202e-01 2.2086e-03 7.2851e-02 -6.0000e+00 8.8051e-01 2.1765e-01 3.0820e-03 4.5036e-02 -6.0000e+00 9.5473e-01 -2.2673e-01 3.3735e-03 2.4445e-02 -6.0000e+00 5.6699e-01 8.2082e-02 1.6345e-03 9.3768e-03 -6.0000e+00 2.4090e-01 3.9699e-04 -6.1928e-04 3.4114e-05 1.0416e-04 -6.0000e+00 1.8229e-02 -1.5497e-02 0.0000e+00 11 8 0 10 0 0 20.97 24.61 0.47 -0.01550 -0.02015 359 36 1 5 0 151.910 32.00 20.00 24.61 12.96 9.4 884.25 900000 -179084 -154377 -215699 -181954 -226852 -226415 -189634 -162320 -145906 -195157 -144860 -134061 -131955 -116864 -62189 -68404 -63138 -41490 -79824 -28373 -53859 -49640 -45984 -57394 -68928 -35584 -40870 -31882 -68236 -20704 -11488 -27151 -21395 -16519 -14978 -5270 -3985 65 4498 2923 -1800 4862 3719 193 1487 1980 3770 6513 1870 3747 6434 4782 4887 4939 4697 3303 4035 414 1100 992 1772 5211 3101 3173 4208 1680 1207 2496 1554 1694 1680 2065 201 -521 -732 -1889 -1275 -3473 -1679 -1680 -791 -987 -1103 -247 -655 -349 -30 489 241 32 703 -65 -19 47 -359 -68 206 77 -150 -177 -704 -367 -50 -758 -1000 -854 -665 -400 105 -111 -181 -40 -90 -32 315 570 312 139 -111 -32 221 261 133 486 495 434 775 552 75 28 123 166 47 -222 -130 61 4 -265 -172 -111 -188 -59 900000 -951 -732 -1974 -1151 -2178 -2251 -1457 -1082 -1015 -2449 -1260 -1316 -1689 -1699 -665 -935 -941 -557 -1696 -377 -944 -864 -834 -1284 -1867 -721 -879 -630 -2077 -463 -291 -972 -819 -624 -555 -187 -160 3 247 191 -138 373 302 17 130 179 351 631 207 455 866 737 833 916 928 689 848 89 228 207 393 1151 803 911 1246 516 387 859 614 752 732 909 94 -227 -289 -696 -464 -1414 -791 -868 -474 -670 -753 -178 -506 -283 -25 411 199 25 516 -46 -14 38 -311 -69 227 95 -183 -210 -822 -385 -53 -773 -1084 -978 -814 -502 148 -167 -283 -66 -146 -51 479 900 478 224 -186 -54 358 404 209 737 725 620 1122 883 130 52 237 346 99 -481 -297 144 9 -612 -404 -247 -408 -121 SS 20250310T131548.8Z 9200.552648 221 1 54.51 2 78.90 105.61 110.36 329.19 0.00 1 0.00 1 0 17 3.312e-01 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