File name: Pandora249s1_ChicagoIL_20250416_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20250417T055535.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora249_OF_v3d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20250416_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20250416 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250416T115743.3Z 9237.498418 220 1 9.77 2 81.81 83.46 85.51 227.69 0.00 1 0.00 1 0 25 6.086e-01 1.941e-02 3.063e-01 6.408e-03 1.019023e+00 3.691882e-03 1.127962e-02 -6.000000e+00 3.669261e-01 228.43 -2.00 3.53 -2.00 321.74 0.00e+00 1.016092e-02 1.978674e-03 5.480865e-03 -6.000000e+00 1.591325e-02 278.64 -2.00 20.00 -2.00 321.31 0.00e+00 6.588 0.005 302.00 328.00 3 8.2705e-01 1.3060e-02 9.4211e-02 -6.0000e+00 9.1360e-01 8.7076e-01 1.8562e-02 7.9687e-02 -6.0000e+00 9.8826e-01 -1.1067e+00 1.9087e-02 3.0360e-02 -6.0000e+00 5.8701e-01 4.4680e-01 8.8273e-03 1.7974e-02 -6.0000e+00 2.4869e-01 1.1548e-04 -1.6758e-03 1.5844e-04 1.6037e-04 -6.0000e+00 1.8660e-02 -1.1321e-02 0.0000e+00 12 9 9 12 1 1 87.05 24.21 0.51 -0.01132 -0.02391 26 15 1 5 0 361.680 31.75 20.01 24.21 8.00 9.1 849.08 900000 -200922 -255808 -166521 -121753 -124684 -222669 -205086 -88101 -44597 -214227 -190668 -66751 -4157 -128068 -47445 -106171 22759 64675 -82148 -54601 -58122 -84100 -67615 32396 -101214 117975 24087 -88098 -55025 103556 7395 -40997 -48374 -6032 -18040 -34671 72940 55778 31518 62604 25719 52189 20842 45582 6161 40601 9233 48937 3543 27959 52143 38529 27160 29996 21955 21525 34547 17880 13540 11664 11779 23855 18117 22621 16475 11239 11909 11542 6168 11969 10732 11550 1541 5365 2606 -5240 -2295 -8109 -546 -28 -139 -307 446 1334 -103 715 1536 1285 15 -379 -533 -3007 1742 -3292 -3443 -3060 -1798 -603 -657 -669 -1333 -378 -903 -1219 -2081 -1328 -2440 -2426 -1718 -948 -1254 -260 -64 -169 -648 41 11 288 228 668 892 1353 823 1758 1200 2161 1879 856 1000 503 742 872 566 129 -214 203 -451 -521 -79 -293 -550 -1596 900000 -3538 -8572 -2270 -968 -921 -4174 -3262 -550 -279 -4137 -3249 -417 -26 -2691 -566 -2714 181 404 -2100 -1160 -1235 -2259 -1563 283 -3415 737 226 -2532 -1238 647 139 -1511 -2146 -177 -575 -1321 1048 1115 945 1565 1012 1663 938 1623 331 1598 525 2018 252 1747 2899 2744 2376 2736 2263 2273 3173 1866 1413 1232 1325 2713 2535 3406 2790 2057 2277 2423 1549 3171 3051 3254 452 1371 609 -1218 -523 -2204 -166 -10 -55 -139 219 689 -57 410 901 758 9 -211 -280 -1580 910 -2046 -2552 -2492 -1712 -647 -690 -745 -1367 -341 -758 -1039 -1887 -1265 -2542 -2818 -2108 -1339 -1856 -407 -101 -264 -994 62 16 469 383 1108 1408 2007 1267 2590 1725 3014 2708 1303 1784 971 1497 1913 1342 311 -548 533 -1207 -1389 -203 -701 -1286 -3521 SS 20250416T121335.1Z 9237.509434 225 1 54.52 2 78.87 86.07 87.68 230.38 0.00 1 0.00 1 0 25 5.369e-01 8.538e-03 2.618e-02 7.649e-04 7.974346e-01 4.209369e-04 9.018231e-03 -6.000000e+00 3.237634e-01 228.43 -2.00 3.53 -2.00 320.55 0.00e+00 2.943450e-03 1.688445e-04 7.620680e-04 -6.000000e+00 1.403888e-02 278.64 -2.00 20.00 -2.00 320.04 0.00e+00 5.002 0.002 302.00 328.00 3 4.8231e-01 1.2819e-03 6.5092e-02 -6.0000e+00 8.0614e-01 1.6559e-01 1.6851e-03 4.3396e-02 -6.0000e+00 8.7196e-01 -1.7786e-01 1.7153e-03 2.2532e-02 -6.0000e+00 5.1793e-01 6.3975e-02 8.4832e-04 8.6278e-03 -6.0000e+00 2.1947e-01 1.0022e-03 -6.0461e-04 2.0229e-05 9.1148e-05 -6.0000e+00 1.6461e-02 -1.2676e-02 0.0000e+00 11 8 0 10 0 0 10.17 24.23 0.38 -0.01268 -0.01722 619 63 1 5 0 88.060 31.75 20.01 24.23 9.23 9.3 859.47 900000 -192355 -175806 -183591 -172887 -185186 -196208 -187540 -150419 -127419 -157762 -143080 -117403 -91678 -99819 -64992 -61565 -46115 -53434 -57601 -31466 -37289 -47814 -47085 -34177 -51012 -30127 -35618 -28688 -42271 -14208 -15232 -18366 -12681 -7168 -11696 -7994 -6767 -3596 -1391 4218 2111 3549 3492 3640 1697 3951 2775 4736 2895 4626 6831 5021 4533 3497 3619 2910 2829 1305 999 585 2202 2972 2584 2660 2446 1410 1207 1363 1139 1074 925 891 174 -224 -813 -1557 -1405 -2178 -1435 -1318 -1076 -1500 -1627 -1056 -947 -374 -163 374 572 897 725 190 430 130 -74 201 199 82 -123 -292 -482 -264 -140 -995 -955 -1011 -533 -387 9 -12 -350 -92 -1 180 523 562 427 164 -209 -164 67 190 110 355 404 573 960 617 314 178 103 145 133 -93 -188 -67 -80 -344 -288 -79 -119 -91 900000 -1669 -1478 -1743 -1573 -1851 -2283 -2238 -1413 -1064 -1965 -1761 -1401 -1121 -1742 -1013 -1111 -819 -1140 -1383 -610 -784 -1159 -1226 -859 -1636 -818 -1028 -777 -1403 -420 -562 -841 -619 -343 -583 -405 -391 -245 -113 379 216 383 395 422 206 485 361 645 436 765 1139 958 961 814 892 752 742 342 256 152 603 913 836 949 907 532 472 579 550 539 497 485 92 -110 -391 -694 -621 -1058 -750 -820 -723 -1142 -1256 -864 -824 -320 -144 331 494 782 594 151 346 115 -71 213 230 100 -158 -366 -586 -289 -154 -1132 -1085 -1215 -647 -514 13 -18 -555 -151 -2 285 828 877 653 263 -350 -275 109 294 171 531 583 842 1427 964 535 314 198 286 268 -193 -415 -148 -180 -773 -628 -168 -246 -186 SS 20250416T121904.8Z 9237.513250 228 1 54.48 2 77.85 86.97 88.46 231.29 0.00 1 0.00 1 0 25 3.997e-01 7.650e-03 1.701e-02 5.964e-04 7.366506e-01 3.248365e-04 8.398627e-03 -6.000000e+00 2.410076e-01 228.43 -2.00 3.53 -2.00 320.20 0.00e+00 2.664150e-03 1.170119e-04 5.271881e-04 -6.000000e+00 1.045014e-02 278.64 -2.00 20.00 -2.00 319.66 0.00e+00 4.613 0.002 302.00 328.00 3 4.4260e-01 9.5530e-04 5.9821e-02 -6.0000e+00 6.0009e-01 1.2897e-01 1.2000e-03 3.9377e-02 -6.0000e+00 6.4907e-01 -1.2803e-01 1.1597e-03 2.0274e-02 -6.0000e+00 3.8554e-01 4.3230e-02 5.8832e-04 7.4972e-03 -6.0000e+00 1.6338e-01 1.5953e-03 -4.8243e-04 1.6199e-05 7.9293e-05 -6.0000e+00 1.2253e-02 -1.2976e-02 0.0000e+00 11 8 0 10 0 0 20.62 24.27 0.32 -0.01298 -0.01660 806 82 1 5 0 67.590 31.75 20.01 24.27 9.69 9.3 862.71 900000 -143527 -133554 -140118 -120486 -140888 -152055 -144500 -113607 -106700 -110860 -107768 -87494 -71793 -67204 -41320 -40201 -30239 -31153 -36314 -26203 -28293 -27653 -29716 -26311 -30366 -19509 -19440 -22247 -24415 -9709 -7050 -9560 -6637 -5228 -5188 -5819 -3832 -501 -960 1916 1025 2880 2389 2538 2133 3055 2057 2736 2539 2462 3766 3215 3639 3214 2212 2098 1209 651 762 662 1149 2499 2286 2078 1621 953 615 1038 975 771 751 618 -41 -214 -816 -1406 -1390 -1566 -1101 -1259 -1150 -1507 -1581 -1147 -943 -302 12 179 372 476 698 391 550 482 258 369 220 -38 -142 -231 -490 -153 24 -803 -997 -911 -653 -407 -46 -66 -192 -34 5 166 526 584 448 199 -191 -198 48 60 91 359 338 677 1070 611 251 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