File name: Pandora249s1_ChicagoIL_20250605_L2Fit_fout2c3d20230501p1-8.txt File generation date: 20250606T060054.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Randazzo Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 249 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora249_OF_v3d20221026.txt Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt Level 1 file used: Pandora249s1_ChicagoIL_20250605_L1_smca1c3d20230501p1-8.txt Full location name: North Park University Chicago Short location name: ChicagoIL Country of location: United States Location latitude [deg]: 41.9748 Location longitude [deg]: -87.7120 Location altitude [m]: 200 Local noon date: 20250605 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2"OoB session" for fieldcal First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1444 305.2853 305.4262 305.5671 305.7080 305.8489 305.9897 306.1306 306.2714 306.4122 306.5531 306.6939 306.8346 306.9754 307.1162 307.2569 307.3977 307.5384 307.6791 307.8198 307.9605 308.1012 308.2418 308.3825 308.5231 308.6637 308.8044 308.9450 309.0855 309.2261 309.3667 309.5072 309.6478 309.7883 309.9288 310.0693 310.2098 310.3503 310.4908 310.6312 310.7716 310.9121 311.0525 311.1929 311.3333 311.4737 311.6140 311.7544 311.8947 312.0351 312.1754 312.3157 312.4560 312.5962 312.7365 312.8768 313.0170 313.1572 313.2975 313.4377 313.5778 313.7180 313.8582 313.9984 314.1385 314.2786 314.4187 314.5589 314.6989 314.8390 314.9791 315.1192 315.2592 315.3992 315.5393 315.6793 315.8193 315.9592 316.0992 316.2392 316.3791 316.5190 316.6590 316.7989 316.9388 317.0787 317.2185 317.3584 317.4982 317.6381 317.7779 317.9177 318.0575 318.1973 318.3371 318.4768 318.6166 318.7563 318.8960 319.0358 319.1755 319.3151 319.4548 319.5945 319.7341 319.8738 320.0134 320.1530 320.2926 320.4322 320.5718 320.7113 320.8509 320.9904 321.1300 321.2695 321.4090 321.5485 321.6880 321.8274 321.9669 322.1063 322.2457 322.3852 322.5246 322.6640 322.8033 322.9427 323.0821 323.2214 323.3607 323.5001 323.6394 323.7787 323.9179 324.0572 324.1965 324.3357 324.4750 324.6142 324.7534 324.8926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250605T124006.1Z 9287.527848 162 1 55.42 2 65.95 80.52 142.59 338.02 0.00 1 0.00 1 0 17 5.064e-02 1.147e-02 2.434e-02 4.190e-03 3.543848e-01 2.247412e-03 4.274351e-03 -6.000000e+00 3.095543e-02 232.22 -2.00 3.53 -2.00 318.52 0.00e+00 7.296833e-04 4.476198e-04 1.717538e-04 -6.000000e+00 1.354126e-03 284.07 -2.00 20.00 -2.00 317.77 0.00e+00 2.436 0.000 302.00 328.00 3 6.0953e+00 6.1309e-03 3.0606e-02 -6.0000e+00 7.7646e-02 1.0431e-01 6.9373e-03 1.8936e-02 -6.0000e+00 8.3682e-02 -6.4680e-02 4.5578e-03 9.2503e-03 -6.0000e+00 4.9712e-02 2.6588e-02 2.3381e-03 2.6137e-03 -6.0000e+00 2.0997e-02 6.7646e-05 -8.7305e-04 1.3314e-04 3.2535e-05 -6.0000e+00 1.5545e-03 -9.6625e-03 0.0000e+00 12 8 8 10 0 0 99.99 25.54 -1.62 -0.00966 -0.01622 29 3 1 5 0 1910.910 32.50 20.01 25.54 21.98 9.7 944.07 900000 14087 -12297 3646 -11872 1576 -23801 -21345 -4733 -3542 -9773 -14331 -1924 14233 -3399 -1514 -12349 7565 12569 -10895 4010 -276 -4830 -519 3361 -15338 2878 -523 1853 2993 2566 9964 -5385 -6644 -4271 -7654 729 -4089 2137 2280 6699 -3471 -878 5774 -541 -1417 1239 -1936 1661 601 2100 6819 2670 -250 727 3421 415 493 1025 -203 -682 2228 3122 -33 68 2376 344 -725 -360 -777 -572 -18 1624 -1317 -241 1763 -1218 -1066 -6598 -2966 -1911 -2707 -1714 -635 366 -78 707 185 1091 424 -290 544 -1635 80 -92 -1242 -584 869 1576 17 126 -1056 -600 -803 -359 -748 -246 -351 -440 445 678 1929 570 -161 -403 -442 -430 806 -518 -371 -415 -249 268 61 454 818 655 503 -656 730 64 22 637 1451 -655 454 -257 -268 -609 -70 -734 -594 586 900000 639 -774 194 -684 74 -1449 -1378 -288 -230 -699 -1107 -144 1047 -347 -173 -1710 909 1510 -1723 562 -41 -754 -81 533 -3071 488 -89 294 457 409 1612 -1113 -1477 -921 -1657 150 -999 581 731 2324 -1435 -369 2319 -233 -615 521 -831 682 252 902 2995 1311 -134 405 1913 244 292 597 -118 -403 1346 2027 -22 47 1545 236 -487 -248 -537 -438 -15 1322 -1079 -184 1207 -856 -701 -4640 -2204 -1446 -2311 -1582 -616 373 -86 814 222 1320 507 -330 567 -1606 74 -87 -1293 -675 1102 1976 22 158 -1362 -716 -943 -440 -982 -338 -465 -615 659 1070 3129 935 -254 -595 -610 -576 1085 -745 -565 -655 -392 410 90 639 1192 913 690 -949 1029 97 34 1040 2431 -1177 851 -504 -496 -1142 -140 -1423 -1102 1038 SS 20250605T125058.5Z 9287.535400 170 1 40.04 2 63.95 82.19 143.30 342.17 0.00 1 0.00 1 0 17 4.826e-02 1.007e-02 2.070e-02 3.904e-03 3.428837e-01 2.078015e-03 4.096349e-03 -6.000000e+00 2.951417e-02 232.22 -2.00 3.53 -2.00 318.30 0.00e+00 -2.241841e-04 3.931296e-04 1.333166e-04 -6.000000e+00 1.290690e-03 284.07 -2.00 20.00 -2.00 317.56 0.00e+00 2.264 0.000 302.00 328.00 3 5.9315e+00 5.6202e-03 2.8858e-02 -6.0000e+00 7.4032e-02 7.8463e-02 6.3601e-03 1.8201e-02 -6.0000e+00 7.9779e-02 -3.0735e-02 4.1181e-03 8.8637e-03 -6.0000e+00 4.7393e-02 1.0113e-02 2.1028e-03 2.4446e-03 -6.0000e+00 2.0024e-02 9.5776e-05 -5.2928e-04 1.2294e-04 2.9590e-05 -6.0000e+00 1.4817e-03 -1.1733e-02 0.0000e+00 12 9 9 12 1 1 99.99 25.61 0.46 -0.01173 -0.01571 20 3 1 5 0 1906.320 32.75 20.01 25.61 22.97 9.7 949.66 900000 1114 -17212 1116 -23829 7185 -23798 -11896 -7323 8291 1834 -11283 -4699 10177 -2367 -818 -7686 7771 -1564 11448 2546 6846 -4013 -1277 3387 -14928 -1178 2878 -1803 8546 9289 11560 -3287 -2388 -4915 -3906 -3262 2977 648 -2445 2111 -3740 2979 3046 305 -2610 476 -2796 648 -1537 1676 5296 -152 457 537 4197 891 520 475 -191 -1182 1864 3139 -315 688 1283 -943 -138 466 -426 137 -37 1394 -1690 -479 -864 -241 -451 -5297 -1154 -1910 -2085 -691 -506 452 -354 -202 870 1054 136 299 603 596 388 1683 -446 -385 238 989 -241 -866 -713 -44 -876 -56 -518 -872 -473 -142 -159 -215 1004 134 -155 -355 -17 -37 464 -511 69 -620 51 124 71 52 1032 1042 1019 -358 455 294 -210 1304 1138 -552 62 6 -42 -521 -289 -580 -321 -115 900000 62 -1232 66 -1678 347 -1585 -770 -507 533 131 -945 -402 864 -264 -102 -1115 1021 -237 1586 397 1035 -686 -222 598 -3330 -233 533 -331 1376 1535 2033 -733 -560 -1175 -898 -774 750 199 -914 853 -1570 1219 1272 131 -1157 223 -1216 297 -724 796 2601 -77 244 300 2336 525 310 279 -111 -705 1134 2042 -229 513 925 -654 -92 316 -321 114 -33 1245 -1521 -402 -666 -167 -294 -3648 -834 -1572 -1921 -686 -488 458 -386 -234 1036 1269 163 336 624 621 385 1687 -455 -438 299 1337 -339 -1177 -901 -51 -1012 -68 -667 -1186 -674 -196 -234 -338 1619 217 -240 -515 -26 -52 666 -720 103 -961 79 186 103 77 1463 1410 1353 -503 681 435 -326 2059 1862 -965 114 11 -76 -956 -522 -1095 -579 -201 SS 20250605T125507.4Z 9287.538280 173 1 10.77 2 63.19 82.84 143.53 343.79 0.00 1 0.00 1 0 17 7.922e-02 9.540e-03 4.211e-02 5.997e-03 3.390928e-01 3.206585e-03 4.117817e-03 -6.000000e+00 4.839842e-02 232.22 -2.00 3.53 -2.00 318.10 0.00e+00 -6.553094e-04 5.859665e-04 3.332584e-04 -6.000000e+00 2.118610e-03 284.07 -2.00 20.00 -2.00 317.35 0.00e+00 2.205 0.000 302.00 328.00 3 5.5130e+00 8.6808e-03 2.8384e-02 -6.0000e+00 1.2139e-01 2.8918e-02 9.7938e-03 1.8160e-02 -6.0000e+00 1.3086e-01 4.4603e-02 6.4107e-03 8.8904e-03 -6.0000e+00 7.7739e-02 -2.9434e-02 3.3054e-03 2.5002e-03 -6.0000e+00 3.2807e-02 1.5512e-04 -1.6525e-03 1.8827e-04 3.0598e-05 -6.0000e+00 2.4324e-03 -4.9450e-03 0.0000e+00 12 9 9 12 9 1 99.40 25.64 2.37 -0.00495 -0.01736 3 2 1 5 0 2691.910 32.75 20.02 25.64 23.30 9.7 952.18 900000 19155 -1875 36381 5131 37395 29065 -5830 33550 18723 29771 -27 28849 22624 12258 -524 -1285 5158 161 4376 2176 -3005 2210 -8611 7203 -3798 -1160 6770 -1952 10001 9609 1209 -150 -1066 -997 1114 952 -974 500 -2318 -1538 -3071 -3358 -1935 -1512 -3586 -1984 -4999 -1703 250 -1057 1380 820 -876 729 767 -415 -81 1455 1013 -698 2258 3806 -1386 -286 1151 -1153 1310 113 1110 189 -752 1367 -498 1537 51 555 2781 -1434 521 -289 -872 -964 -658 1 -572 -397 862 110 -200 303 1777 -240 1480 1321 -500 -21 1923 294 -213 -488 -260 -482 403 -410 -480 -1350 -635 -23 -641 -685 202 -737 -227 -102 -184 814 1003 -446 -397 -356 -695 -149 -479 38 1169 333 854 137 986 181 118 544 1320 -30 -234 20 -450 -498 -495 -199 -156 529 900000 795 -103 1362 246 1225 1054 -331 1452 1029 1532 -2 1704 1641 1147 -63 -171 685 24 647 341 -504 359 -1642 1255 -782 -238 1255 -376 1661 1658 247 -34 -261 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