File name: Pandora249s1_ChicagoIL_20250806_L2Fit_fwvt1c3d20230501p1-8.txt
File generation date: 20250807T060508.8Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: John Randazzo
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 249
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora249_OF_v3d20221026.txt
Instrument calibration file used: Pandora249s1_CF_v3d20230501.txt
Level 1 file used: Pandora249s1_ChicagoIL_20250806_L1_smca1c3d20230501p1-8.txt
Full location name: North Park University Chicago
Short location name: ChicagoIL
Country of location: United States
Location latitude [deg]: 41.9748
Location longitude [deg]: -87.7120
Location altitude [m]: 200
Local noon date: 20250806
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: based on session 2"OoB session" for fieldcal
First and last pixel inside fitting window: 1615 1765
Nominal wavelengths inside fitting window [nm]: 492.0600 492.1808 492.3016 492.4224 492.5432 492.6639 492.7847 492.9054 493.0261 493.1468 493.2675 493.3881 493.5088 493.6294 493.7500 493.8706 493.9912 494.1118 494.2323 494.3528 494.4734 494.5939 494.7143 494.8348 494.9552 495.0757 495.1961 495.3165 495.4369 495.5572 495.6776 495.7979 495.9182 496.0385 496.1588 496.2790 496.3993 496.5195 496.6397 496.7599 496.8801 497.0002 497.1204 497.2405 497.3606 497.4807 497.6008 497.7209 497.8409 497.9609 498.0809 498.2009 498.3209 498.4409 498.5608 498.6807 498.8006 498.9205 499.0404 499.1602 499.2801 499.3999 499.5197 499.6395 499.7593 499.8790 499.9988 500.1185 500.2382 500.3579 500.4775 500.5972 500.7168 500.8365 500.9561 501.0756 501.1952 501.3148 501.4343 501.5538 501.6733 501.7928 501.9123 502.0317 502.1511 502.2705 502.3899 502.5093 502.6287 502.7480 502.8673 502.9867 503.1059 503.2252 503.3445 503.4637 503.5829 503.7022 503.8213 503.9405 504.0597 504.1788 504.2979 504.4170 504.5361 504.6552 504.7742 504.8933 505.0123 505.1313 505.2503 505.3692 505.4882 505.6071 505.7260 505.8449 505.9638 506.0826 506.2015 506.3203 506.4391 506.5579 506.6767 506.7954 506.9142 507.0329 507.1516 507.2703 507.3889 507.5076 507.6262 507.7448 507.8634 507.9820 508.1006 508.2191 508.3376 508.4561 508.5746 508.6931 508.8116 508.9300 509.0484 509.1668 509.2852 509.4036 509.5219 509.6402 509.7586 509.8769 509.9951
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250806T110928.2Z 9349.464910 105 1 28.50 2 87.45 69.91 126.39 262.50 0.00 1 0.00 1 0 36 1.602e-02 1.595e-02 1.500e-03 1.492e-03 1.089637e+04 1.045518e+02 6.959826e+02 -6.000000e+00 9.396919e+02 288.38 -2.00 20.00 -2.00 505.42 0.00e+00 4.271816e-03 4.236291e-05 2.299013e-04 -6.000000e+00 4.612929e-04 288.38 -2.00 20.00 -2.00 501.12 0.00e+00 -2.878070e-02 2.894968e-02 8.537815e-02 -6.000000e+00 3.227800e-01 232.09 -2.00 3.53 -2.00 502.59 0.00e+00 14.557 0.058 489.00 513.00 1 6.4406e+00 2.2280e-03 2.3732e-02 -6.0000e+00 2.4848e-02 -3.8234e-02 5.4869e-04 2.2290e-03 -6.0000e+00 6.3589e-03 3.8199e-04 9.9821e-03 1.5936e-04 1.1299e-04 -6.0000e+00 1.8107e-03 6.8713e-02 -8.3982e-04 12 9 9 12 1 1 -1.05 26.50 15.70 0.06871 0.13795 8 2 1 4 0 3166.280 33.25 20.00 26.50 26.80 10.0 973.04 -3580 -2716 -1226 103 1073 2154 2618 2620 2047 1451 639 -307 -362 -1652 -1367 -1198 -877 20 980 762 985 914 1543 1520 2691 1686 1171 482 -609 -2070 -2632 -2513 -1264 -12 952 1484 486 55 -473 -332 -543 200 1417 1782 1392 1877 1476 976 -99 -835 -1832 -2767 -3264 -2288 -1380 -224 772 1151 1424 1421 1355 1661 2298 1753 1142 1241 30 -658 -964 -1719 -1760 -1952 -1228 -692 -514 -968 -1666 -2094 -2616 -2659 -2624 -1626 -2287 -1577 -1073 -964 -1362 -900 -656 -859 -129 593 1826 1747 1686 796 913 -809 -2015 -2718 -3378 -3076 -1803 -939 -25 118 -492 -1170 -1144 -615 -135 383 1310 2183 2562 2906 3416 2922 2573 1742 1085 659 641 1502 1341 1247 1533 1296 784 933 924 -419 -810 -1003 -1130 -858 -38 414 698 962 1032 847 946 1315 418 219 -239 -1169 -2660 -2929 -2486 -3174 -2431 -1116 96 963 1956 2406 2427 1905 1344 589 -282 -328 -1505 -1239 -1091 -809 19 927 732 950 886 1492 1479 2607 1654 1151 472 -590 -1987 -2510 -2409 -1223 -11 905 1417 468 53 -454 -318 -523 193 1374 1747 1387 1871 1474 970 -98 -815 -1766 -2645 -3120 -2190 -1343 -222 775 1167 1448 1450 1390 1709 2361 1812 1182 1270 31 -670 -973 -1733 -1768 -1970 -1243 -704 -526 -991 -1698 -2115 -2632 -2667 -2637 -1628 -2326 -1533 -1049 -949 -1350 -887 -645 -848 -128 588 1809 1732 1651 768 900 -790 -1952 -2617 -3274 -3024 -1723 -924 -25 121 -506 -1207 -1178 -634 -140 404 1384 2310 2723 3107 3504 3034 2681 1815 1122 675 653 1589 1365 1279 1574 1337 813 964 949 -432 -829 -1023 -1157 -888 -40 438 749 1045 1133 940 1055 1466 449 235 -265 -1289 -2939 -3236 -2758
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SQ 20250806T112404.3Z 9349.475049 113 1 54.53 2 84.89 72.30 128.96 264.64 0.00 1 0.00 1 0 22 5.535e-03 5.495e-03 1.661e-04 1.657e-04 1.260834e+04 1.195956e+01 8.122867e+02 -6.000000e+00 3.247580e+02 288.38 -2.00 20.00 -2.00 505.40 0.00e+00 3.689721e-03 4.721885e-06 2.135348e-04 -6.000000e+00 1.592704e-04 288.38 -2.00 20.00 -2.00 500.96 0.00e+00 6.014165e-01 3.249875e-03 9.072887e-02 -6.000000e+00 1.110606e-01 232.09 -2.00 3.53 -2.00 502.48 0.00e+00 9.637 0.017 489.00 513.00 1 3.7051e+00 2.4981e-04 1.6474e-02 -6.0000e+00 8.5568e-03 -6.6665e-02 6.1815e-05 2.2033e-03 -6.0000e+00 2.1770e-03 1.1200e-02 1.3972e-03 1.7361e-05 1.1156e-04 -6.0000e+00 6.2584e-04 9.1975e-04 -6.9499e-05 12 8 8 10 0 0 56.06 26.51 3.84 0.00092 0.01061 383 39 1 4 0 142.370 33.25 20.01 26.51 27.76 9.8 978.17 -970 -753 -242 190 468 889 1055 995 885 644 395 100 -201 -345 -454 -465 -363 -9 325 275 329 400 361 444 604 504 356 227 -166 -612 -835 -776 -591 2 245 207 115 72 -79 -195 -147 4 194 405 532 585 492 303 55 -345 -736 -983 -1209 -1091 -621 -198 76 240 321 407 457 604 598 539 482 291 -11 -167 -350 -504 -552 -559 -509 -285 -82 -265 -581 -741 -849 -923 -897 -768 -790 -580 -408 -384 -440 -374 -295 -207 -71 205 506 634 580 356 82 -328 -595 -980 -1210 -1162 -757 -257 -62 -168 -292 -397 -467 -308 -50 95 368 699 864 972 1132 1141 909 605 431 280 294 487 568 490 573 482 392 451 307 -61 -220 -351 -484 -253 69 91 224 463 461 380 409 410 282 147 -151 -569 -865 -920 -809 -874 -687 -222 179 444 861 1018 970 863 624 379 95 -193 -328 -431 -443 -344 -9 313 269 324 395 358 443 593 497 351 225 -163 -587 -807 -752 -572 2 243 208 116 72 -79 -193 -146 4 193 408 543 588 494 308 55 -340 -725 -951 -1164 -1058 -614 -197 76 242 325 413 466 618 615 555 494 295 -11 -166 -351 -501 -546 -554 -508 -282 -82 -264 -573 -734 -833 -902 -877 -753 -782 -579 -403 -383 -440 -373 -293 -206 -71 206 504 641 579 347 79 -315 -562 -917 -1133 -1106 -729 -252 -61 -170 -297 -403 -473 -313 -50 97 381 713 886 1005 1181 1201 944 625 447 287 298 494 578 503 590 497 405 465 316 -62 -222 -360 -489 -259 72 95 237 487 491 408 435 438 301 156 -162 -603 -907 -962 -852
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