File name: Pandora67s1_Cologne_20200716_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T092316.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20200716_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20200716 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200716T130752.3Z 7502.547133 492 1 2.60 2 34.50 218.85 67.83 271.75 0.00 1 0.00 1 0 17 1.024e-02 7.894e-03 7.852e-03 5.330e-03 1.814722e-01 2.812902e-03 2.375160e-03 -6.000000e+00 6.030940e-03 233.79 -2.00 3.80 -2.00 314.97 0.00e+00 5.720593e-04 2.356726e-04 5.327806e-05 -6.000000e+00 2.610386e-04 283.52 -2.00 20.00 -2.00 314.36 0.00e+00 1.213 0.000 302.00 328.00 3 4.7484e+00 7.3027e-03 1.6048e-02 -6.0000e+00 1.5199e-02 3.1036e-02 8.0690e-03 1.0326e-02 -6.0000e+00 1.6415e-02 -5.3319e-04 4.6022e-03 4.9840e-03 -6.0000e+00 9.7353e-03 -2.7959e-03 2.0074e-03 1.3747e-03 -6.0000e+00 4.0860e-03 1.1244e-03 -1.7495e-04 1.5319e-04 1.8484e-05 -6.0000e+00 2.8417e-04 6.0279e-04 -6.1628e-05 12 9 1 12 1 1 999.00 21.62 0.14 0.00060 -0.00071 1 9 1 5 0 1205.920 25.79 19.99 21.62 24.14 25.8 1020.89 -2301 -10 -892 -1854 -1399 1441 -2281 3293 907 723 -493 1216 -403 895 784 -253 -35 -170 377 2638 1393 -225 1147 582 183 -1022 1051 -577 248 922 369 -228 1589 -2702 -2211 -2236 -2865 403 -403 -1337 -1969 -403 -1182 366 -558 -339 -1572 -395 -916 1288 73 704 1205 1660 476 487 1191 827 446 13 1164 1097 2456 407 840 431 206 -192 1576 230 368 307 226 241 -1011 112 -363 -1730 -599 -1308 -1152 -911 -2074 -863 -636 -536 -152 22 725 -401 -145 488 -57 1091 37 344 1082 -44 -69 608 -1160 -1468 123 326 -1156 -970 -740 -751 -284 658 -98 145 1033 609 -196 99 134 346 -168 415 -211 945 551 533 232 -45 300 923 337 77 365 -718 -653 485 37 -45 251 225 -484 -716 294 -582 -190 -759 -4 -308 -609 -413 406 -696 1029 310 257 -173 431 -154 366 349 -120 -17 -83 189 1329 709 -115 591 311 100 -576 584 -310 124 455 188 -121 871 -1531 -1195 -1192 -1632 246 -276 -1022 -1573 -328 -976 302 -461 -277 -1278 -311 -716 987 58 576 1007 1434 419 432 1055 738 392 11 1048 1027 2371 411 835 406 187 -170 1420 223 378 324 239 250 -1015 105 -321 -1484 -517 -1214 -1135 -949 -2249 -950 -732 -640 -186 27 903 -493 -170 543 -60 1115 39 378 1251 -54 -88 761 -1417 -1731 139 375 -1404 -1214 -951 -989 -383 902 -138 206 1419 806 -248 121 162 427 -216 556 -289 1282 743 703 295 -56 361 1102 416 98 473 -953 -871 658 52 -65 367 333 -725 -1057 425 -832 -268 SS 20200716T132328.3Z 7502.557966 502 1 48.60 2 36.13 224.47 70.20 274.66 0.00 1 0.00 1 0 17 1.077e-02 7.555e-03 3.469e-03 1.984e-03 1.923905e-01 1.039399e-03 2.449524e-03 -6.000000e+00 6.347545e-03 233.79 -2.00 3.80 -2.00 315.67 0.00e+00 6.750149e-04 1.003819e-04 3.030421e-05 -6.000000e+00 2.746923e-04 283.52 -2.00 20.00 -2.00 315.00 0.00e+00 1.237 0.000 302.00 328.00 3 6.1635e+00 2.7174e-03 1.6595e-02 -6.0000e+00 1.5997e-02 5.4937e-02 3.0139e-03 1.0839e-02 -6.0000e+00 1.7273e-02 -6.2805e-04 1.7224e-03 5.2176e-03 -6.0000e+00 1.0245e-02 -3.9636e-03 7.6992e-04 1.4782e-03 -6.0000e+00 4.3015e-03 2.5790e-04 2.5016e-04 5.7525e-05 1.7835e-05 -6.0000e+00 2.9886e-04 2.2558e-04 5.1456e-05 11 8 0 10 0 0 99.96 21.62 0.16 0.00023 0.00211 23 5 1 5 0 2112.410 25.79 20.00 21.62 24.35 25.8 1024.84 1563 335 923 -4025 -1084 -2632 -1895 -1752 1334 -1605 -2187 -465 680 402 -2221 1548 706 -123 -418 1584 52 2372 2031 376 -205 545 268 -699 581 1954 374 1375 1473 -1472 -851 -1688 -1661 -1509 2999 -1231 -593 -571 -971 -574 -139 -2977 -818 -1247 -615 250 512 627 1569 880 555 1238 178 912 295 725 1007 510 1851 1528 -267 180 -711 -910 641 95 778 698 922 384 151 -787 -913 -1750 -966 -1436 -1202 -1300 -2078 -1060 -674 -388 -16 611 946 648 646 151 -360 -496 -460 -204 144 932 200 -37 43 -663 -697 -223 -1376 -561 -387 -451 284 792 857 844 317 -122 -284 -484 -195 -375 -185 206 -263 578 628 559 333 284 -342 430 -4 151 -315 56 -786 305 137 197 204 515 117 -72 19 -473 -952 380 87 240 -1028 -240 -573 -433 -439 350 -452 -604 -128 204 133 -818 594 280 -51 -175 668 23 1003 881 171 -97 258 129 -316 245 800 162 610 696 -717 -388 -763 -812 -832 1819 -867 -437 -435 -752 -446 -108 -2331 -619 -926 -446 178 381 486 1243 726 465 1041 153 775 251 612 864 463 1758 1494 -261 166 -621 -780 558 91 788 729 963 394 146 -720 -776 -1427 -803 -1296 -1156 -1339 -2238 -1180 -782 -469 -21 778 1208 806 757 168 -377 -507 -482 -227 169 1161 261 -47 53 -789 -801 -258 -1695 -716 -508 -607 390 1127 1261 1234 457 -167 -370 -602 -242 -473 -244 284 -371 812 874 754 434 357 -421 520 -6 196 -423 76 -1083 426 198 294 310 799 183 -111 29 -703 -1403 SS 20200716T132846.4Z 7502.561648 505 1 12.83 2 36.73 226.30 71.00 275.63 0.00 1 0.00 1 0 17 1.008e-02 7.237e-03 5.612e-03 3.485e-03 1.942694e-01 1.833484e-03 2.532426e-03 -6.000000e+00 5.929161e-03 233.79 -2.00 3.80 -2.00 315.36 0.00e+00 3.637922e-04 1.654997e-04 2.760634e-05 -6.000000e+00 2.567524e-04 283.52 -2.00 20.00 -2.00 314.71 0.00e+00 1.247 0.000 302.00 328.00 3 5.8034e+00 4.7758e-03 1.6810e-02 -6.0000e+00 1.4943e-02 5.2378e-02 5.2873e-03 1.1045e-02 -6.0000e+00 1.6143e-02 -4.4705e-03 3.0185e-03 5.3428e-03 -6.0000e+00 9.5740e-03 -1.9071e-03 1.3348e-03 1.4631e-03 -6.0000e+00 4.0147e-03 3.6621e-04 -1.5334e-03 1.0052e-04 1.9342e-05 -6.0000e+00 2.7976e-04 2.4740e-03 -2.5828e-04 12 9 1 12 1 1 98.76 21.63 -0.00 0.00247 -0.00905 3 4 1 5 0 3163.240 25.79 20.00 21.63 24.79 25.7 1027.41 -1424 -159 -1660 -2098 -2240 -2047 -1099 1365 3062 -1149 -2790 -998 -461 831 -288 1861 831 -217 1244 2092 -78 1722 1408 659 -486 38 477 129 -637 2434 -1227 1418 844 -1496 -1581 -1297 -777 -1210 1876 -1931 -173 -225 -791 -940 159 -709 -696 -1674 -329 -622 886 -3 1594 1372 473 1599 92 -175 -54 322 616 617 1676 1411 223 -222 -1156 -503 821 189 579 -73 658 819 -431 -227 -518 -1582 -730 -1895 -1591 -1259 -1984 -1119 -346 -412 313 970 805 519 841 112 -435 467 429 -26 530 1028 -193 -131 60 -255 -1076 34 -1054 -795 -717 -87 -154 301 450 703 337 105 -100 -17 -173 -14 -323 73 -668 281 329 1 807 211 243 638 578 159 -158 -199 -1008 343 204 112 413 410 60 -105 -395 -280 -674 -400 -47 -497 -587 -570 -504 -284 373 890 -363 -873 -312 -156 305 -116 781 361 -96 561 962 -37 792 665 324 -246 20 245 62 -294 1087 -585 680 428 -778 -784 -632 -408 -705 1210 -1416 -132 -175 -636 -760 126 -564 -544 -1289 -245 -467 678 -2 1294 1158 409 1381 81 -154 -47 278 541 565 1598 1391 220 -208 -1034 -442 736 183 593 -77 689 845 -428 -211 -451 -1337 -621 -1731 -1560 -1309 -2145 -1240 -400 -496 385 1218 1011 640 988 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