File name: Pandora67s1_Cologne_20200717_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T092442.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20200717_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20200717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200717T071714.3Z 7503.303638 260 1 2.57 2 58.31 95.14 34.47 144.37 0.00 1 0.00 1 0 25 9.518e-03 6.047e-03 4.773e-03 2.169e-03 2.561039e-01 1.131514e-03 3.312324e-03 -6.000000e+00 5.601890e-03 233.75 -2.00 3.80 -2.00 316.40 0.00e+00 4.447434e-04 1.280638e-04 4.553155e-05 -6.000000e+00 2.425796e-04 283.52 -2.00 20.00 -2.00 315.68 0.00e+00 1.896 0.000 302.00 328.00 3 2.7466e+00 2.9805e-03 2.4030e-02 -6.0000e+00 1.4117e-02 1.8899e-02 3.3160e-03 1.4605e-02 -6.0000e+00 1.5249e-02 -1.4076e-03 1.9158e-03 7.0406e-03 -6.0000e+00 9.0443e-03 -2.7151e-03 8.8868e-04 1.9261e-03 -6.0000e+00 3.7939e-03 3.7622e-03 -6.7847e-04 6.2736e-05 2.3700e-05 -6.0000e+00 2.6420e-04 3.5634e-03 -1.2268e-04 12 1 1 12 1 1 -21.46 21.55 0.21 0.00356 -0.00153 10 52 1 5 0 217.950 25.68 20.00 21.55 24.02 25.8 1008.34 -2047 942 -3223 -2740 -3883 517 -1372 393 -835 -797 -2157 -1010 -295 36 -14 311 1653 -360 1308 767 1304 135 1742 -809 632 9 526 -716 1445 869 1512 806 1020 -1309 -2199 -856 -1878 -376 358 -443 -1421 -553 -607 -210 -762 -1098 -839 -413 -1140 648 509 801 994 1115 742 1087 616 363 783 138 1501 1202 2025 1373 -291 -479 -379 -448 891 442 356 226 -25 6 -652 -76 -594 -191 -305 -782 -1037 -1246 -2181 -1142 -1003 -798 -483 64 165 51 417 645 345 565 619 286 638 591 -62 -8 292 -767 -211 209 -809 -783 -603 -338 -25 304 10 298 116 136 186 362 225 323 142 -2 -595 233 -174 169 465 523 210 1309 295 370 -274 -3 -386 283 -363 -123 100 111 -187 -81 49 -337 -417 -345 167 -607 -492 -627 78 -227 71 -163 -163 -441 -212 -69 9 -4 96 510 -118 438 267 458 48 625 -305 245 4 211 -272 513 311 572 318 422 -567 -922 -352 -837 -186 199 -275 -923 -371 -411 -143 -519 -748 -572 -273 -764 429 348 571 728 842 581 862 488 288 620 110 1216 1004 1778 1263 -269 -418 -323 -373 758 409 347 226 -25 6 -611 -68 -494 -154 -256 -695 -993 -1271 -2354 -1256 -1139 -953 -584 79 206 62 485 712 365 584 659 318 758 742 -82 -10 366 -936 -245 247 -1001 -1006 -795 -460 -34 436 15 443 169 192 251 467 292 430 196 -4 -865 333 -249 235 627 682 266 1670 390 503 -389 -5 -561 421 -560 -193 159 182 -305 -130 76 -524 -642 SS 20200717T072711.9Z 7503.310554 263 1 35.71 2 56.75 97.18 33.60 148.13 0.00 1 0.00 1 0 25 7.891e-03 5.584e-03 7.391e-04 3.383e-04 2.452469e-01 1.763883e-04 3.162955e-03 -6.000000e+00 4.648513e-03 233.75 -2.00 3.80 -2.00 316.40 0.00e+00 2.170275e-04 1.995536e-05 5.386069e-05 -6.000000e+00 2.012260e-04 283.52 -2.00 20.00 -2.00 315.67 0.00e+00 1.818 0.000 302.00 328.00 3 1.8671e+00 4.6461e-04 2.3011e-02 -6.0000e+00 1.1714e-02 1.1347e-02 5.1694e-04 1.3951e-02 -6.0000e+00 1.2651e-02 -1.1759e-03 2.9885e-04 6.7289e-03 -6.0000e+00 7.5032e-03 -2.1608e-03 1.3835e-04 1.8300e-03 -6.0000e+00 3.1495e-03 1.0012e-02 1.4626e-04 9.8297e-06 2.2411e-05 -6.0000e+00 2.1900e-04 1.9560e-03 2.4843e-05 12 1 1 12 1 1 99.99 21.60 0.23 0.00196 0.00306 590 192 1 5 0 59.220 25.79 20.01 21.60 25.17 25.7 1015.15 -757 -547 -1518 -3188 -2738 -1249 -849 623 583 -976 -1420 -53 -158 7 525 -247 173 235 751 714 185 596 1347 502 352 318 -347 -645 -20 1125 1186 1393 1403 -1439 -1766 -659 -1515 -478 -173 -666 -1202 -610 -789 -740 -231 -636 -662 -642 -742 289 898 579 1041 891 625 990 609 420 556 631 1207 1131 1483 1037 -344 -3 -152 -89 1017 514 142 171 15 142 -227 -145 -181 -340 74 -664 -927 -1253 -2024 -1185 -911 -778 -418 95 68 106 385 487 309 772 657 266 554 535 -313 -374 -149 -719 -104 296 -927 -861 -484 -612 -149 322 185 92 81 188 99 509 401 448 154 -90 -530 154 68 274 616 407 454 1183 309 185 64 -90 -188 322 -157 -135 -18 322 -318 -186 -136 -476 -344 -127 -99 -282 -557 -461 -203 -147 118 112 -200 -287 -11 -37 2 155 -74 54 76 250 246 65 206 478 190 138 130 -142 -248 -7 392 438 546 593 -640 -734 -269 -689 -230 -93 -419 -776 -407 -544 -514 -159 -438 -446 -421 -477 185 603 415 783 667 484 777 488 336 435 492 968 973 1299 969 -322 -3 -130 -74 882 476 137 172 16 138 -218 -125 -150 -268 60 -577 -904 -1282 -2118 -1289 -1061 -924 -520 116 84 132 438 532 327 782 698 296 652 667 -415 -488 -183 -867 -123 340 -1176 -1100 -644 -820 -208 454 276 139 117 265 135 645 506 587 208 -130 -756 225 98 376 833 526 586 1512 403 257 90 -130 -278 468 -243 -212 -28 530 -531 -302 -214 -757 -534 SS 20200717T073254.2Z 7503.314516 267 1 2.38 2 55.86 98.37 33.14 150.35 0.00 1 0.00 1 0 17 1.192e-02 7.962e-03 1.305e-02 6.308e-03 2.433005e-01 3.297171e-03 3.159399e-03 -6.000000e+00 7.021152e-03 233.75 -2.00 3.80 -2.00 316.20 0.00e+00 4.906842e-04 3.573653e-04 4.113891e-05 -6.000000e+00 3.039614e-04 283.52 -2.00 20.00 -2.00 315.49 0.00e+00 1.776 0.000 302.00 328.00 3 4.3009e+00 8.6663e-03 2.2652e-02 -6.0000e+00 1.7693e-02 3.6729e-02 9.6329e-03 1.3896e-02 -6.0000e+00 1.9109e-02 -7.0547e-04 5.5449e-03 6.7029e-03 -6.0000e+00 1.1334e-02 -4.2094e-03 2.5478e-03 1.8476e-03 -6.0000e+00 4.7566e-03 9.0482e-04 -2.2484e-04 1.8274e-04 2.2868e-05 -6.0000e+00 3.3090e-04 1.8754e-03 -3.6603e-05 12 9 1 12 1 1 999.00 21.63 0.25 0.00188 0.00019 1 10 1 5 0 1100.420 25.79 20.00 21.63 25.56 25.7 1015.60 -1676 -859 -83 -5607 -2283 1905 -792 630 1431 -695 172 4085 2050 1093 2306 -139 1047 -724 421 1802 -2322 1376 207 634 -496 59 1311 -2609 1522 -173 -321 1031 690 -1478 -1697 -1533 1468 450 1754 -517 -2079 -1969 -1177 202 -1800 -2621 -1786 1277 -132 630 408 877 1663 1 918 2748 415 708 69 -918 544 518 1232 1292 234 440 -73 -1144 1162 117 430 774 111 319 475 522 -296 -1011 -1503 -798 -970 -844 -1751 -576 -707 -855 -287 559 11 697 564 1694 88 1122 15 258 64 -262 -239 -125 -421 -735 -847 -336 -538 -1167 -481 -1215 631 592 533 -207 -465 -161 342 880 701 713 598 -418 -633 390 -444 -156 415 396 -490 1509 541 1153 380 715 -960 314 -39 -680 -413 465 -500 -300 493 -517 -232 -316 -171 -17 -1118 -396 314 -143 122 300 -154 38 889 497 299 687 -46 349 -255 150 655 -879 504 78 251 -204 25 547 -1056 569 -66 -127 424 299 -670 -727 -649 657 226 991 -330 -1419 -1381 -836 143 -1290 -1887 -1261 868 -89 423 287 641 1255 1 730 2199 339 579 56 -747 447 447 1110 1211 219 392 -62 -972 1006 109 426 784 113 319 452 463 -249 -830 -1263 -717 -941 -863 -1879 -630 -809 -1018 -352 695 14 853 657 1860 92 1149 16 289 77 -333 -314 -161 -527 -887 -985 -396 -668 -1494 -630 -1646 873 843 782 -307 -678 -226 454 1121 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