File name: Pandora67s1_Cologne_20200807_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T093039.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20200807_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20200807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200807T045600.4Z 7524.205560 188 1 48.76 2 83.81 71.70 67.11 222.95 0.00 1 0.00 1 0 25 5.241e-01 2.826e-02 3.675e-01 1.238e-02 9.168666e-01 7.280608e-03 1.078785e-02 -6.000000e+00 3.092743e-01 232.78 -2.00 3.80 -2.00 322.17 0.00e+00 9.900921e-03 4.274925e-03 3.392953e-03 -6.000000e+00 1.384469e-02 283.63 -2.00 20.00 -2.00 321.68 0.00e+00 8.317 0.012 302.00 328.00 3 8.7633e-01 2.8983e-02 1.0484e-01 -6.0000e+00 7.7851e-01 1.3008e+00 3.8547e-02 7.4036e-02 -6.0000e+00 8.4225e-01 -1.5386e+00 3.3059e-02 2.9713e-02 -6.0000e+00 4.9815e-01 5.8284e-01 1.5366e-02 1.4999e-02 -6.0000e+00 2.1069e-01 2.0992e-05 -1.6205e-03 3.4537e-04 1.7632e-04 -6.0000e+00 1.5121e-02 5.3517e-03 -3.0925e-05 12 8 8 10 0 0 23.60 21.92 0.48 0.00535 -0.00683 49 11 1 5 0 994.420 26.00 20.00 21.92 26.62 25.5 1013.64 -73407 900000 40295 82655 157 -1741 -64704 900000 -142922 -13902 -66768 -89075 900000 -7632 -64220 13095 185777 -16922 115831 19795 900000 900000 11633 183352 -5832 -41938 112353 149933 182701 130436 -21876 233242 107468 86398 65935 27759 68233 10055 900000 10694 25644 20344 25221 61594 -10134 -96902 38521 78098 58963 57617 36847 35117 26716 12110 46196 36585 34234 50003 38325 8750 41917 2936 14530 23077 20912 19200 7735 24249 9359 21451 15956 17958 20343 17221 9348 15083 8547 6342 -4328 8272 -380 -1400 4335 1579 514 7380 -3127 -849 -1136 3833 817 231 -612 -3738 548 -2457 -5092 -1903 2805 -1432 -3674 -139 -5857 -2437 -4499 -3641 -255 -1557 -2458 -125 -2632 -791 -1722 -734 -1348 849 523 -1579 -916 1249 362 2345 2616 2972 2070 1144 201 1584 973 1527 1789 628 -1576 191 686 -90 774 -503 -104 514 59 -737 -2421 -2486 900000 486 997 2 -21 -1407 900000 -6560 -178 -1425 -2677 900000 -167 -3027 338 2240 -684 1397 563 900000 900000 305 2211 -178 -1802 1355 1808 2203 1573 -951 2813 1756 1798 1539 902 1566 454 900000 641 1433 1242 1501 2588 -836 -18573 2060 2964 2810 2992 2623 2763 2465 1367 3917 3452 3303 4036 3272 950 3383 378 1908 3180 3077 2851 1310 3660 1802 4175 3526 3988 4331 3475 1814 2486 1420 1127 -978 2005 -117 -500 1616 641 221 3185 -1532 -415 -556 1741 356 96 -253 -1701 272 -1477 -3742 -1573 2450 -1296 -3261 -108 -4349 -1709 -3429 -2908 -210 -1403 -2472 -142 -3460 -1101 -2501 -1049 -1878 1143 718 -2292 -1396 1922 551 3377 3617 3949 2711 1478 258 2130 1506 2653 3458 1336 -3688 463 1767 -246 2152 -1419 -291 1374 148 -1777 -5659 SS 20200807T050539.2Z 7524.212260 191 1 48.47 2 82.36 73.52 68.11 225.24 0.00 1 0.00 1 0 17 6.769e-01 1.210e-02 2.518e-01 4.598e-03 8.290256e-01 2.599185e-03 9.985865e-03 -6.000000e+00 3.977056e-01 232.78 -2.00 3.80 -2.00 321.90 0.00e+00 8.702735e-03 1.530041e-03 2.958312e-03 -6.000000e+00 1.757231e-02 283.63 -2.00 20.00 -2.00 321.40 0.00e+00 6.983 0.007 302.00 328.00 3 9.2589e-01 1.0245e-02 8.6256e-02 -6.0000e+00 9.9893e-01 3.8566e-01 1.5244e-02 5.2431e-02 -6.0000e+00 1.0800e+00 -5.3321e-01 1.5863e-02 3.0318e-02 -6.0000e+00 6.4054e-01 2.0888e-01 7.1565e-03 1.2827e-02 -6.0000e+00 2.6927e-01 9.4591e-05 -9.5143e-04 1.2876e-04 2.0140e-04 -6.0000e+00 1.8908e-02 5.1810e-03 -6.0743e-05 12 8 8 10 0 0 11.87 21.94 0.35 0.00518 -0.00197 127 30 1 5 0 381.540 26.11 20.00 21.94 27.12 25.5 1015.58 -207772 -201285 -206806 -229717 900000 -195585 -152775 -241861 -185328 -224513 -216095 -184534 40021 -121213 -90682 -70014 131425 -87001 26087 -74508 -74174 -6286 -95833 -14378 -98903 -76021 -53527 -11421 -24613 18583 -62743 28191 -16237 28589 -44129 -8729 -37526 23054 205134 -5379 21494 -1987 28590 11622 2693 -46545 19938 4759 19566 12255 19993 13512 18174 8468 20540 9358 8295 7857 507 -60 7571 7150 8764 11395 7366 9531 1152 6593 3547 7110 6668 4560 3229 3777 456 334 -1226 749 889 734 -347 -1524 113 -1231 306 -582 887 -663 1405 1439 1145 -732 -17 -1308 -579 -1121 -151 554 -778 -163 -1472 -1287 -2587 -675 -3206 -1489 -1558 -1626 -592 136 -644 -328 -249 286 -163 238 242 643 275 56 390 906 760 993 1115 428 290 877 691 262 347 -11 -576 108 -222 -131 -119 856 -471 101 -84 -196 -732 -1694 -1805 -2107 -2809 900000 -1515 -809 -3352 -1586 -3020 -2818 -2106 179 -1334 -961 -742 589 -1418 164 -1215 -1209 -56 -1992 -155 -2338 -1487 -936 -128 -320 183 -1611 392 -377 500 -1385 -211 -1224 527 920 -215 736 -92 1037 516 134 -3927 902 266 1013 749 1288 1046 1481 835 1909 1007 923 868 58 -7 836 886 1239 1807 1297 1639 221 1266 781 1744 1816 1318 928 1008 114 75 -266 167 229 230 -120 -618 50 -587 154 -316 495 -386 805 795 592 -365 -8 -685 -345 -796 -126 494 -774 -162 -1400 -1107 -2202 -558 -2905 -1402 -1443 -1646 -661 172 -930 -511 -396 446 -245 346 356 989 449 88 601 1433 1161 1460 1572 591 394 1252 1134 460 681 -24 -1333 247 -549 -341 -318 2304 -1284 261 -203 -446 -1721 SS 20200807T051619.5Z 7524.219670 194 1 49.04 2 80.74 75.53 69.27 227.73 0.00 1 0.00 1 0 25 5.591e-01 7.857e-03 1.032e-01 2.115e-03 7.361360e-01 1.166250e-03 8.816509e-03 -6.000000e+00 3.279205e-01 232.78 -2.00 3.80 -2.00 321.44 0.00e+00 5.835229e-03 6.038978e-04 8.769646e-04 -6.000000e+00 1.425749e-02 283.63 -2.00 20.00 -2.00 320.89 0.00e+00 5.902 0.004 302.00 328.00 3 8.1030e-01 4.1472e-03 7.3353e-02 -6.0000e+00 8.2428e-01 1.0514e-01 5.9174e-03 4.4965e-02 -6.0000e+00 8.9106e-01 -1.8243e-01 6.1339e-03 2.4318e-02 -6.0000e+00 5.2898e-01 7.2422e-02 2.8558e-03 1.0436e-02 -6.0000e+00 2.2236e-01 3.3327e-04 -9.5344e-04 5.9301e-05 1.1901e-04 -6.0000e+00 1.5515e-02 5.1516e-03 -5.7187e-05 11 8 0 10 0 0 18.88 21.97 0.21 0.00515 -0.00201 266 62 1 5 0 182.260 26.11 20.01 21.97 27.73 25.5 1016.78 -236869 -172323 -218144 -172040 -190511 -148846 -217250 -144086 -196641 -144885 -138314 -103057 -64466 -58434 -91202 -73791 -22634 -58667 -33049 -47312 -33784 -50608 -41985 -40879 -31200 -62584 -14706 -36780 -25607 -35152 -24794 -16118 -1915 -4201 -13080 -15679 -12121 3036 12452 1385 859 -472 -2188 4531 -5853 -11635 927 4910 1517 8564 4133 7355 2814 4900 4742 4696 2606 598 1329 -1141 3720 1786 4650 3902 4498 3040 2455 3486 3638 2970 2216 1266 1369 1633 -578 342 -1201 -481 -1486 317 -722 -653 -1778 -932 -573 24 -176 344 432 764 643 557 -324 -622 -205 -443 -223 447 -91 -274 -574 -1069 -543 -542 -1624 -1748 -583 -664 -257 118 21 -6 82 340 -26 578 -12 233 -107 -40 -317 720 232 472 533 339 221 1181 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