File name: Pandora67s1_Cologne_20200825_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T094430.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20200825_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20200825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200825T051132.2Z 7542.216345 63 1 48.47 2 85.32 78.95 145.98 8.30 0.00 1 0.00 1 0 25 5.102e-01 4.990e-02 3.862e-01 2.767e-02 1.013753e+00 1.614313e-02 1.294896e-02 -6.000000e+00 2.988534e-01 231.20 -2.00 3.80 -2.00 322.06 0.00e+00 7.843211e-03 6.880574e-03 9.068047e-03 -6.000000e+00 1.341981e-02 282.70 -2.00 20.00 -2.00 321.51 0.00e+00 10.276 0.023 302.00 328.00 3 -3.6293e-01 5.5746e-02 1.2601e-01 -6.0000e+00 7.4731e-01 2.2719e+00 6.7448e-02 7.5973e-02 -6.0000e+00 8.0866e-01 -2.0766e+00 4.6978e-02 3.6845e-02 -6.0000e+00 4.8073e-01 6.8441e-01 2.4317e-02 1.0381e-02 -6.0000e+00 2.0334e-01 7.2562e-06 -8.7934e-04 7.1052e-04 2.4433e-04 -6.0000e+00 1.4484e-02 -4.1677e-03 -2.7541e-05 12 8 8 10 0 0 -14.20 21.37 0.89 -0.00417 -0.01078 25 6 1 5 0 1938.460 25.58 20.00 21.37 22.11 25.0 932.32 25414 140367 181248 42352 90981 27755 -6935 -39939 17956 51358 141287 -40 -12070 209749 103630 93813 154689 38949 69045 13991 -60843 900000 96144 50974 1105 900000 -81801 -63822 35516 -2221 -4925 38096 139791 76169 15806 -39176 53924 89530 900000 19555 87319 88064 -24529 63160 30779 -63177 50449 5736 35294 82413 992 55520 53073 63708 68292 31887 3232 113936 58113 26501 -56116 26638 63712 20924 37704 67150 -2783 32554 36596 40714 35677 34098 40524 14353 -10386 16333 -11363 -22521 9993 -11720 19071 -6724 22991 -13768 -2007 -3212 -2547 20599 14374 24497 -25522 -6172 936 7205 72 1063 -8289 7963 5755 -6094 -9317 1510 -16913 -5340 3212 476 1893 -370 2787 -2410 -3213 -2379 1757 2842 384 934 1487 -266 -1400 2494 300 2699 3970 2798 -606 1557 1868 857 2283 -1490 -1540 1851 -6297 -724 3517 -156 917 630 -102 -36 324 165 -2021 1516 3786 4889 1828 2454 976 -323 -2467 613 1385 3811 -2 -704 5657 2920 3323 4172 2595 3419 1121 -9228 900000 2711 2229 75 900000 -11259 -6706 1341 -133 -372 2229 3770 3445 1167 -4563 2596 3358 900000 1874 4600 4676 -3889 4179 2669 -13555 3572 640 3109 4904 142 5124 5346 6122 6447 4327 566 6439 5275 3038 -14173 3267 6219 3510 5657 7532 -618 5405 6370 7670 7623 7487 7941 3297 -2666 2839 -2399 -5552 2068 -3604 5192 -2698 7556 -6769 -923 -1565 -1264 8300 6084 9064 -13934 -2653 372 2885 36 619 -6217 5982 4898 -5873 -8713 1152 -13651 -3692 2149 343 1430 -314 2540 -2686 -4114 -3284 2455 3926 529 1245 2000 -382 -2101 3742 447 3702 5220 3584 -773 1903 2244 1110 3370 -2641 -3119 3971 -15661 -1833 9229 -443 2630 1835 -297 -100 834 401 -4766 SS 20200825T052318.6Z 7542.224521 66 1 49.19 2 83.49 81.21 145.69 13.05 0.00 1 0.00 1 0 17 4.880e-01 1.801e-02 2.532e-01 6.956e-03 8.856330e-01 3.985748e-03 1.056466e-02 -6.000000e+00 2.850964e-01 231.20 -2.00 3.80 -2.00 322.05 0.00e+00 9.227092e-03 2.282019e-03 1.577488e-03 -6.000000e+00 1.240876e-02 282.70 -2.00 20.00 -2.00 321.58 0.00e+00 7.988 0.011 302.00 328.00 3 4.4702e-01 1.5372e-02 9.5911e-02 -6.0000e+00 7.1401e-01 8.4557e-01 2.1575e-02 5.5572e-02 -6.0000e+00 7.7246e-01 -1.0089e+00 2.0673e-02 2.9650e-02 -6.0000e+00 4.5904e-01 3.9096e-01 9.4875e-03 1.3147e-02 -6.0000e+00 1.9412e-01 5.0398e-05 -1.8553e-03 1.9013e-04 1.8426e-04 -6.0000e+00 1.3851e-02 -4.9108e-03 -1.9557e-05 12 9 8 11 8 0 22.08 21.37 0.33 -0.00491 -0.01885 88 21 1 5 0 552.580 25.58 20.00 21.37 22.64 24.9 935.78 -148223 -117974 -165325 -151441 -125035 -80835 -157772 -77804 -188648 17107 -138125 -149944 -137372 -7371 -69097 99143 -37191 -30698 -59037 -57319 -59556 -33321 -35805 -50896 -52114 -76026 -62412 -78898 -29715 -53335 9042 -15042 69846 -15082 9980 -66348 -10415 -26580 900000 24369 16290 45712 -1959 39638 9025 -52619 11998 36544 26519 42645 28731 32359 25795 38788 27174 16706 8092 9222 15449 17118 2339 5487 21141 17421 17907 11734 23242 11040 19912 15070 16879 7881 16715 6774 5023 1147 -6996 -4144 413 -1500 2321 -1619 -923 -833 -2784 1486 32 1915 2091 3738 -4264 -260 -3783 -1440 -2510 -970 -1748 772 -851 -2411 -1271 -1207 -2753 -1963 -3178 -3619 -1773 -1895 -36 -1623 717 -1336 -261 385 -313 -486 -232 981 -421 509 444 2123 1481 1350 1531 1854 585 1239 893 304 -268 932 -973 380 -71 75 -86 305 391 -245 192 -1163 -1170 -2178 -1467 -3458 -2568 -1413 -548 -2319 -576 -4052 116 -1874 -2627 -2795 -59 -1211 672 -711 -606 -1502 -1458 -1515 -678 -751 -1287 -1350 -2531 -1809 -2578 -586 -1513 173 -445 1034 -558 271 -3413 -360 -1229 900000 947 763 1691 -122 1662 518 -5235 703 1758 1504 2235 1949 2374 2211 3181 2427 1700 910 1006 1511 1596 259 648 2462 2432 2682 1870 3363 1903 3455 3152 3835 2036 3874 1612 1093 231 -1435 -857 94 -424 754 -638 -403 -387 -1297 706 16 969 1060 1804 -2080 -125 -1848 -725 -1351 -612 -1322 671 -839 -2449 -1212 -1044 -2159 -1480 -2576 -3120 -1593 -1862 -39 -2038 936 -1952 -390 568 -450 -677 -325 1425 -655 814 700 3139 2120 1865 2029 2571 806 1777 1373 544 -546 1929 -2204 908 -184 206 -241 864 1109 -667 484 -2780 -2662 SS 20200825T053256.1Z 7542.231205 69 1 48.20 2 81.99 83.05 145.34 16.87 0.00 1 0.00 1 0 17 5.397e-01 1.393e-02 2.689e-01 5.921e-03 7.774205e-01 3.314633e-03 9.549191e-03 -6.000000e+00 3.152755e-01 231.20 -2.00 3.80 -2.00 321.60 0.00e+00 7.087722e-03 1.741864e-03 2.707496e-03 -6.000000e+00 1.372192e-02 282.70 -2.00 20.00 -2.00 321.08 0.00e+00 6.706 0.006 302.00 328.00 3 1.6720e+00 1.1940e-02 8.1446e-02 -6.0000e+00 7.8959e-01 4.1692e-01 1.6963e-02 4.7961e-02 -6.0000e+00 8.5422e-01 -4.2659e-01 1.7190e-02 2.7614e-02 -6.0000e+00 5.0763e-01 1.5459e-01 7.9755e-03 1.1017e-02 -6.0000e+00 2.1467e-01 5.7396e-05 -1.4178e-03 1.6447e-04 1.5578e-04 -6.0000e+00 1.5317e-02 -4.6780e-03 -2.3504e-07 12 8 8 10 0 0 98.61 21.38 0.19 -0.00468 -0.01533 62 15 1 5 0 777.260 25.58 20.00 21.38 23.32 24.9 939.41 -152206 -60095 -83739 -213494 -200383 100271 -221356 -212118 -191946 -136144 -133709 -140747 -109194 -89753 -33846 -66055 921 -69815 71207 -78526 -35113 52183 31861 -6470 -60033 -6292 -73983 -69365 -32388 -28234 -43822 46971 -7371 17082 3029 -26082 -31190 31195 900000 24258 -3176 23607 -16808 17383 5747 -46778 1164 1002 18723 19171 13249 10452 17314 15905 22265 6725 3986 7608 8473 -523 -825 4167 10723 9553 10608 8653 6621 6393 5283 4778 7072 3460 4569 5003 -1296 3967 -7028 1534 -1736 -38 543 -2703 182 -4424 -2027 -1338 -273 106 2553 1624 -325 -947 946 -2775 495 -1668 -790 878 365 -1791 -1889 -484 -3017 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