File name: Pandora67s1_Cologne_20201009_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T100410.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20201009_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20201009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201009T141214.3Z 7587.591832 554 1 4.58 2 68.48 227.03 95.98 320.57 0.00 1 0.00 1 0 17 2.505e-02 7.340e-03 2.059e-02 5.012e-03 3.221716e-01 2.525737e-03 4.139403e-03 -6.000000e+00 1.433630e-02 225.24 -2.00 3.80 -2.00 317.67 0.00e+00 5.006757e-04 4.032353e-04 1.380358e-04 -6.000000e+00 6.229206e-04 277.42 -2.00 20.00 -2.00 317.05 0.00e+00 2.701 0.000 302.00 328.00 3 3.9027e+00 6.6783e-03 3.2027e-02 -6.0000e+00 3.5471e-02 2.7565e-02 7.5354e-03 1.7743e-02 -6.0000e+00 3.8555e-02 2.2947e-04 4.7394e-03 8.7654e-03 -6.0000e+00 2.2943e-02 -3.6135e-03 2.4114e-03 2.6326e-03 -6.0000e+00 9.7775e-03 5.0136e-04 1.7317e-03 1.4592e-04 2.8989e-05 -6.0000e+00 6.9290e-04 -1.2108e-02 2.4037e-04 12 9 1 12 1 1 -43.26 21.24 0.12 -0.01211 0.00090 3 10 1 5 0 1102.080 25.47 19.98 21.24 21.97 26.0 998.04 -12589 -6839 726 -9364 4324 1690 -4298 -4326 -769 -13050 1162 -5950 1881 -5605 6143 -7820 2361 260 2601 4778 3234 -104 -1408 -2015 -1039 -260 751 2685 781 3627 17 1697 -814 -747 26 1427 -2794 1381 1283 186 -413 -981 -452 -2098 1347 -2067 -591 -880 -1435 920 833 400 1420 -151 1088 250 1086 485 163 -300 1337 1858 914 1777 -530 55 769 -746 646 1032 13 290 170 926 -605 123 -1507 654 -175 -744 -927 -1717 -1584 -1836 -957 -953 -883 25 127 940 1442 638 854 932 383 425 309 885 -659 5 40 -999 -382 -105 -1315 -809 -205 -371 -425 361 -230 514 -20 312 0 -342 503 126 46 -71 -732 294 77 -48 514 208 388 1377 831 277 461 -215 -361 561 209 -84 140 482 -184 -309 -495 -734 -317 -1039 -590 60 -809 296 116 -336 -376 -72 -1449 114 -647 217 -797 900 -1427 420 49 501 936 655 -22 -308 -465 -249 -65 187 629 174 794 4 440 -233 -223 7 393 -870 469 507 84 -204 -503 -239 -1127 709 -1112 -314 -463 -753 479 457 234 861 -98 713 169 732 333 110 -202 913 1323 700 1434 -435 43 572 -562 501 867 12 270 158 833 -526 99 -1157 477 -133 -619 -841 -1687 -1635 -1949 -1055 -1102 -1049 30 154 1115 1626 681 874 936 399 475 370 1130 -884 7 52 -1237 -448 -125 -1658 -1051 -272 -510 -606 536 -356 801 -32 464 0 -466 679 175 66 -107 -1118 443 114 -70 720 285 519 1825 1161 402 696 -335 -571 901 349 -143 244 850 -328 -544 -854 -1238 -527 SS 20201009T142320.4Z 7587.599541 561 1 48.71 2 69.79 229.63 97.03 322.77 0.00 1 0.00 1 0 17 1.829e-02 5.789e-03 1.095e-02 1.899e-03 3.410556e-01 9.558392e-04 4.402783e-03 -6.000000e+00 1.045168e-02 225.24 -2.00 3.80 -2.00 318.30 0.00e+00 6.221181e-04 1.808897e-04 1.741895e-04 -6.000000e+00 4.550217e-04 277.42 -2.00 20.00 -2.00 317.67 0.00e+00 2.864 0.000 302.00 328.00 3 4.2635e+00 2.5635e-03 3.4011e-02 -6.0000e+00 2.5857e-02 3.6304e-02 2.9113e-03 1.8887e-02 -6.0000e+00 2.8123e-02 -1.3855e-04 1.9482e-03 9.3967e-03 -6.0000e+00 1.6736e-02 -6.7636e-03 1.0170e-03 2.7463e-03 -6.0000e+00 7.1186e-03 2.9018e-04 -8.5354e-05 5.5928e-05 3.1097e-05 -6.0000e+00 5.0642e-04 -4.8977e-03 6.8043e-06 11 1 0 11 8 0 99.96 21.25 0.17 -0.00490 -0.00554 56 13 1 5 0 869.720 25.47 20.03 21.25 22.54 26.2 1002.29 -1577 3789 -6360 2988 -8011 1088 -8338 -2321 -6485 2949 -5619 1699 51 981 -3855 580 -1149 246 709 -1150 2014 2411 330 -604 -87 -1289 1178 -2973 2572 863 1468 -129 2586 -3022 -2074 -3347 -2853 190 3367 -893 -1824 73 -1470 -193 -36 -3253 -1052 -603 -629 1247 556 868 632 1466 728 388 541 158 258 293 1591 1290 2869 1378 -36 -100 -2 -412 1422 688 68 234 589 -2 -287 -184 -404 -398 -689 -601 -1055 -991 -2162 -797 -964 -224 -566 307 304 464 507 257 -83 128 471 228 277 768 259 -593 20 -655 -358 -213 -733 -1059 -720 -498 66 292 367 245 105 335 -105 625 -23 171 -12 17 -661 200 38 620 358 604 129 965 -75 106 42 -222 -344 267 -66 -17 -45 395 -121 -297 18 -471 -93 -81 205 -388 160 -428 53 -472 -138 -449 198 -413 123 4 95 -447 72 -155 35 105 -180 311 369 54 -106 -16 -245 225 -560 430 149 276 -27 567 -730 -467 -756 -709 52 1054 -339 -756 31 -662 -87 -16 -1520 -477 -269 -279 555 266 440 342 823 430 231 328 96 153 176 957 838 1977 1023 -27 -71 -2 -280 1008 538 58 205 514 -2 -232 -136 -282 -268 -482 -469 -905 -918 -2150 -809 -1034 -252 -661 362 362 539 561 266 -83 124 474 248 329 985 348 -791 26 -797 -416 -251 -913 -1381 -967 -695 94 441 577 391 165 511 -153 859 -31 243 -18 27 -1039 311 58 915 516 842 176 1304 -107 158 66 -361 -567 447 -115 -32 -83 732 -227 -551 33 -830 -161 SS 20201009T143302.4Z 7587.606277 567 1 48.73 2 70.97 231.86 97.89 324.73 0.00 1 0.00 1 0 17 1.631e-02 5.107e-03 2.913e-03 4.304e-04 3.584686e-01 2.171214e-04 4.633900e-03 -6.000000e+00 9.314944e-03 225.24 -2.00 3.80 -2.00 318.54 0.00e+00 5.675773e-04 4.372238e-05 1.265945e-04 -6.000000e+00 4.055774e-04 277.42 -2.00 20.00 -2.00 317.90 0.00e+00 3.031 0.001 302.00 328.00 3 1.1888e+00 5.8561e-04 3.5942e-02 -6.0000e+00 2.3045e-02 -3.1436e-03 6.6736e-04 1.9922e-02 -6.0000e+00 2.5066e-02 3.6887e-03 4.6045e-04 9.9166e-03 -6.0000e+00 1.4917e-02 -6.5825e-03 2.4194e-04 2.9038e-03 -6.0000e+00 6.3438e-03 5.3456e-03 -2.7773e-04 1.2672e-05 3.2184e-05 -6.0000e+00 4.5145e-04 -4.4164e-03 -2.1461e-05 10 0 0 10 0 0 99.94 21.25 0.21 -0.00442 -0.00650 1310 307 1 5 0 36.910 25.47 20.00 21.25 23.20 26.2 1006.00 -4393 -3316 -2683 -7389 -4920 -7801 -3229 -5399 -2507 -5364 -3818 -4818 -1712 -1799 499 -581 431 167 1051 701 75 553 553 201 -529 -48 -1640 -1363 -1598 698 381 1036 844 -1445 -2327 -1327 -1799 -603 148 -794 -1211 -940 -652 -842 131 -855 -349 -560 -416 124 944 579 1079 910 779 906 605 314 313 548 1013 1309 1580 1343 -190 343 -20 103 1044 690 135 168 -81 200 -269 -37 35 -343 121 -632 -732 -1122 -2073 -1275 -841 -867 -376 122 294 199 586 584 497 865 723 293 577 615 -313 -354 -220 -635 -337 370 -999 -881 -639 -602 -220 397 132 150 101 178 94 481 392 354 -31 -215 -640 10 -41 163 525 291 375 1137 329 154 99 -41 -128 303 -180 -139 -122 406 -325 -145 -86 -310 -157 -187 -155 -130 -355 -207 -333 -142 -272 -137 -324 -229 -311 -125 -154 49 -65 51 21 139 97 11 78 81 32 -89 -8 -297 -233 -257 112 68 201 166 -304 -466 -261 -394 -152 44 -286 -447 -364 -262 -345 53 -353 -142 -227 -169 51 415 277 548 495 443 528 361 188 183 318 605 782 1034 955 -139 234 -13 66 711 534 108 141 -68 161 -216 -27 23 -219 81 -489 -600 -1032 -2078 -1251 -882 -974 -442 139 337 234 634 583 494 837 746 317 701 788 -410 -485 -285 -764 -399 441 -1231 -1148 -871 -821 -317 611 206 241 159 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