File name: Pandora67s1_Cologne_20201128_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T102325.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20201128_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20201128 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201128T080325.3Z 7637.335709 263 1 48.52 2 84.26 134.91 112.63 331.58 0.00 1 0.00 1 0 25 9.100e-01 4.965e-02 3.712e-01 1.779e-02 8.777928e-01 1.025642e-02 1.059416e-02 -6.000000e+00 5.283580e-01 220.84 -2.00 3.80 -2.00 321.95 0.00e+00 1.869109e-02 4.937993e-03 4.294037e-03 -6.000000e+00 2.531975e-02 270.99 -2.00 20.00 -2.00 321.52 0.00e+00 8.857 0.015 302.00 328.00 3 1.0082e+00 3.4771e-02 1.1061e-01 -6.0000e+00 1.3044e+00 1.6602e+00 4.2815e-02 8.5345e-02 -6.0000e+00 1.4321e+00 -1.8404e+00 3.7330e-02 2.7188e-02 -6.0000e+00 8.3887e-01 6.9819e-01 1.9019e-02 2.3107e-02 -6.0000e+00 3.5707e-01 1.0489e-05 -2.2897e-03 5.0372e-04 2.5703e-04 -6.0000e+00 2.7226e-02 -8.6423e-03 -4.4752e-05 12 8 8 10 0 0 98.32 20.25 0.47 -0.00864 -0.02585 22 5 1 5 0 2204.800 24.65 20.00 20.25 10.16 29.0 939.54 900000 207228 329518 22665 900000 126832 900000 -91156 900000 135468 289109 900000 900000 475321 64002 257870 119019 900000 155940 258918 133211 900000 87452 130178 3746 126914 900000 -1108 -8898 900000 -12608 151825 281473 46456 900000 12904 130024 233798 900000 51091 90226 86539 49176 31889 20118 -105239 53389 23130 39202 92769 29983 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-6006 -514 -5875 2349 -1251 -3058 -927 3281 -8368 606 5294 2120 1335 -4621 79 -5644 -3447 -2304 -1686 -636 -5698 -5265 1836 2309 365 3059 5850 2643 3971 4740 1182 1361 499 314 2739 -123 -1603 1260 -7607 2048 5158 -220 3207 4536 -4489 2495 -4902 -1106 -2995 SS 20201128T081333.5Z 7637.342749 266 1 48.97 2 83.15 137.01 113.31 334.06 0.00 1 0.00 1 0 17 5.373e-01 2.267e-02 3.133e-01 9.460e-03 8.169692e-01 5.247708e-03 9.864998e-03 -6.000000e+00 3.025468e-01 220.83 -2.00 3.80 -2.00 321.86 0.00e+00 7.553367e-03 2.574831e-03 2.003990e-03 -6.000000e+00 1.412622e-02 270.99 -2.00 20.00 -2.00 321.44 0.00e+00 7.675 0.010 302.00 328.00 3 1.4015e+00 1.7931e-02 8.9030e-02 -6.0000e+00 7.4312e-01 7.9646e-01 2.4498e-02 4.7938e-02 -6.0000e+00 8.1247e-01 -9.9567e-01 2.5159e-02 2.7665e-02 -6.0000e+00 4.8275e-01 3.9768e-01 1.2118e-02 1.1380e-02 -6.0000e+00 2.0980e-01 2.9819e-05 -1.8045e-03 2.7008e-04 1.6784e-04 -6.0000e+00 1.5409e-02 -8.2223e-03 -6.8519e-05 12 8 8 10 0 0 98.26 20.26 0.38 -0.00822 -0.02178 61 14 1 5 0 802.510 24.65 20.00 20.26 10.33 29.0 940.59 900000 900000 -151595 -41924 -131870 73589 -138609 -82845 -172062 900000 -127480 -48961 -74189 227574 8863 74181 35472 25743 131446 -43623 209031 166866 140017 -62260 40808 -79172 900000 -83901 33121 19502 32104 -8113 59999 16770 36486 -2460 -22744 78749 900000 68837 -3580 122577 967 89775 -13615 -51309 5571 22158 -674 61350 13824 36079 39936 26675 29539 40154 10496 12342 31372 2035 27512 -5184 39156 428 26068 8851 30480 12639 13299 5484 11953 13711 9896 10605 -6201 1811 -6718 649 -5987 4059 -5133 581 -4026 3089 -3179 1523 -5282 1301 -1850 1867 1298 934 -2132 -1989 70 -3591 1350 -757 -557 -3367 -108 -2425 -791 -3900 354 -4611 -414 -3799 -700 -1419 -960 173 -1192 321 -618 435 -1019 2642 -1178 2618 233 1754 883 3058 837 1363 1311 441 1234 546 508 -431 545 -576 762 -993 415 80 81 -23 -408 -1395 -255 900000 900000 -5450 -480 -3185 678 -3304 -1159 -5921 900000 -2998 -612 -1486 2098 131 684 537 466 1212 -1608 1927 1538 1291 -2632 645 -4051 900000 -4240 543 392 698 -315 1363 624 1045 -100 -1164 1774 900000 2289 -263 2887 74 2985 -1229 -6621 430 1561 -61 3312 1292 3004 3478 2874 3258 4071 1448 1636 3271 275 2938 -812 4667 83 4358 1689 4892 2450 2795 1424 3210 3753 2758 2731 -1699 407 -1540 142 -1599 1184 -1886 234 -1886 1431 -1669 811 -3041 742 -1059 1027 669 454 -1049 -1024 40 -2445 1034 -673 -549 -3459 -102 -2194 -629 -3101 287 -4154 -379 -3805 -756 -1760 -1312 254 -1833 481 -900 605 -1442 3765 -1841 4086 368 2609 1277 4306 1158 1827 1723 609 1879 963 980 -920 1196 -1360 1905 -2596 1096 216 217 -62 -1009 -3262 -578 SS 20201128T082454.5Z 7637.350631 269 1 49.03 2 81.96 139.38 113.99 336.88 0.00 1 0.00 1 0 17 5.609e-01 1.024e-02 1.744e-01 3.451e-03 7.450250e-01 1.853457e-03 8.940824e-03 -6.000000e+00 3.150966e-01 220.83 -2.00 3.80 -2.00 321.46 0.00e+00 4.546562e-03 8.710256e-04 1.040599e-03 -6.000000e+00 1.365716e-02 270.99 -2.00 20.00 -2.00 321.04 0.00e+00 6.694 0.006 302.00 328.00 3 1.0514e+00 6.0662e-03 7.8529e-02 -6.0000e+00 7.7370e-01 2.0508e-01 8.8959e-03 4.4600e-02 -6.0000e+00 8.4517e-01 -2.5977e-01 1.0172e-02 2.4511e-02 -6.0000e+00 5.0276e-01 1.0105e-01 4.8500e-03 9.4341e-03 -6.0000e+00 2.1636e-01 1.2788e-04 -1.2750e-03 9.6992e-05 1.1308e-04 -6.0000e+00 1.5591e-02 -8.4189e-03 -7.7445e-05 12 8 8 10 0 0 99.05 20.27 0.26 -0.00842 -0.01800 115 27 1 5 0 422.620 24.65 19.99 20.27 10.57 29.0 942.64 900000 -172266 -224187 -237426 -134369 -187458 -176226 -203947 -221884 -128920 -166421 -127592 -79428 96911 -82572 260 -14201 13091 -41100 -10663 -46450 20629 -47216 -48978 -28272 -55068 -9260 -67179 -18248 -4427 -15860 -20078 18594 -36073 7795 -28763 4716 -2601 83268 2537 -1967 -2627 4353 1664 -439 -26712 -6340 1749 6705 15063 6701 8650 6460 11422 6085 12571 1400 5339 772 -91 314 2549 7783 6109 2808 5364 5616 2695 4840 3235 5515 1763 4835 510 -546 -1694 -95 -1790 881 -2167 -619 -1790 -1591 -589 -1321 -976 -1173 111 -296 1222 1367 963 -509 -67 -729 -87 -547 427 -354 -972 49 -353 -955 -414 -981 -2124 -1024 -1470 -160 -309 -113 129 -12 250 -175 171 395 692 57 207 -194 602 368 538 424 567 593 1143 376 49 453 186 -470 589 -178 -440 -202 500 -542 -137 106 -198 -167 900000 -1265 -3017 -3558 -723 -1703 -1542 -2370 -3461 -954 -1904 -1159 -588 326 -1083 2 -134 106 -622 -126 -797 180 -858 -989 -495 -1334 -146 -1853 -307 -73 -363 -581 432 -1434 212 -1123 146 -102 1681 126 -117 -170 278 113 -31 -2533 -508 136 529 1189 650 929 782 1450 873 1761 226 826 121 -14 50 441 1469 1347 686 1271 1343 696 1344 964 1787 621 1636 170 -167 -513 -27 -523 260 -793 -264 -895 -882 -345 -833 -655 -825 79 -213 841 876 583 -305 -41 -514 -66 -488 439 -404 -1126 53 -351 -859 -362 -922 -2138 -1079 -1688 -200 -405 -167 205 -19 398 -268 250 578 1052 92 347 -323 957 566 798 604 783 798 1589 596 88 851 382 -1031 1270 -415 -1088 -511 1277 -1403 -338 246 -462 -372 SS 20201128T083611.5Z 7637.358467 273 1 49.04 2 80.83 141.78 114.59 339.71 0.00 1 0.00 1 0 25 4.235e-01 6.918e-03 1.267e-01 2.178e-03 6.821060e-01 1.139243e-03 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