File name: Pandora67s1_Cologne_20210522_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T112420.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210522_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210522 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210522T055919.0Z 7812.249525 222 1 48.33 2 69.54 82.43 121.61 327.62 0.00 1 0.00 1 0 17 5.812e-02 4.983e-03 2.625e-02 1.729e-03 4.619406e-01 9.026875e-04 5.770829e-03 -6.000000e+00 3.402307e-02 231.57 -2.00 3.80 -2.00 319.61 0.00e+00 1.069430e-03 2.505516e-04 2.365762e-04 -6.000000e+00 1.449014e-03 277.96 -2.00 20.00 -2.00 319.01 0.00e+00 2.832 0.000 302.00 328.00 3 3.5525e+00 2.5480e-03 3.8930e-02 -6.0000e+00 8.5430e-02 1.9104e-02 3.0035e-03 2.6442e-02 -6.0000e+00 9.2446e-02 9.7178e-03 2.4687e-03 1.3164e-02 -6.0000e+00 5.4753e-02 -9.1935e-03 1.2900e-03 3.9654e-03 -6.0000e+00 2.3020e-02 4.9706e-04 -3.5644e-04 5.0649e-05 4.2743e-05 -6.0000e+00 1.6107e-03 -1.2623e-02 -8.1287e-06 10 0 0 10 0 0 99.99 20.94 0.17 -0.01262 -0.01530 295 69 1 5 0 163.800 25.17 20.00 20.94 18.07 31.8 1012.26 -20393 -23776 -9859 -19710 -14929 -31200 -20018 -26479 -6893 -17304 -1163 -13875 -6670 -3793 -3806 -2739 -3223 10 -3215 2357 -3063 884 -2232 654 -5282 -1913 -894 -3791 -1262 2050 -1016 113 1680 -1832 -4333 -3301 -1916 -1578 4128 -1966 -1486 -1051 -602 -472 45 -1187 63 -516 -63 835 2277 733 968 1199 705 1143 36 170 -337 468 949 1601 1628 1899 -118 632 508 315 1006 946 140 285 65 -157 -266 -23 -37 -482 304 -732 -663 -1214 -1973 -1439 -759 -824 -168 -100 312 269 403 662 501 683 1005 219 556 718 -123 -308 -289 -418 -299 585 -845 -813 -683 -725 -229 203 88 72 -74 288 35 437 405 322 32 -24 -715 170 125 369 455 181 79 979 286 -55 -4 -115 -228 108 -279 -50 -82 599 -260 -118 -28 -221 -142 -359 -496 -190 -405 -265 -646 -402 -637 -154 -467 -27 -404 -217 -145 -176 -145 -173 1 -199 145 -205 57 -156 48 -437 -162 -77 -320 -99 162 -93 12 191 -230 -533 -397 -252 -241 723 -438 -369 -255 -152 -122 12 -314 17 -137 -17 231 675 242 343 457 285 474 15 73 -142 194 404 732 825 1056 -69 349 271 169 572 612 94 201 46 -107 -180 -14 -21 -261 175 -489 -470 -977 -1742 -1333 -747 -812 -172 -106 332 277 411 623 444 594 935 231 618 902 -168 -420 -374 -498 -327 634 -1000 -1018 -895 -1010 -318 305 143 123 -123 459 52 611 598 462 50 -39 -1180 272 194 552 688 262 110 1362 435 -86 -8 -205 -420 194 -536 -100 -170 1263 -559 -244 -56 -418 -260 SS 20210522T061712.3Z 7812.261948 235 1 48.01 2 66.74 85.79 123.03 332.40 0.00 1 0.00 1 0 17 2.264e-02 5.196e-03 2.211e-03 3.212e-04 4.069007e-01 1.656575e-04 5.171325e-03 -6.000000e+00 1.325108e-02 231.57 -2.00 3.80 -2.00 318.37 0.00e+00 6.736672e-04 3.169860e-05 1.523375e-04 -6.000000e+00 5.644463e-04 277.96 -2.00 20.00 -2.00 317.73 0.00e+00 2.513 0.000 302.00 328.00 3 1.1378e+00 4.4968e-04 3.4325e-02 -6.0000e+00 3.3273e-02 1.4835e-02 5.0824e-04 2.3042e-02 -6.0000e+00 3.6007e-02 -9.7465e-03 3.4359e-04 1.1272e-02 -6.0000e+00 2.1326e-02 -1.4260e-03 1.7924e-04 3.1919e-03 -6.0000e+00 8.9648e-03 8.2198e-03 -3.5480e-04 9.2390e-06 3.5009e-05 -6.0000e+00 6.2747e-04 -1.2476e-02 -4.2237e-05 10 0 0 10 0 0 99.59 20.97 0.21 -0.01248 -0.01514 948 222 1 5 0 50.520 25.28 20.00 20.97 18.27 32.0 1013.96 -7925 -5092 -6050 -8753 -9553 -9011 -7889 -6468 -5461 -5520 -6289 -5676 -3299 -2878 -953 -1086 -193 -356 582 193 167 309 1135 -153 -264 -383 -1097 -1607 -1387 154 243 932 1147 -1097 -2683 -1524 -2117 -512 -231 -471 -1186 -636 -488 -544 112 -342 -290 -352 -426 385 1036 655 1272 1118 766 1108 705 285 561 419 1201 1345 1762 1286 -21 257 162 -95 912 677 133 227 -108 39 -365 -175 -168 -326 57 -550 -796 -1030 -2035 -1358 -995 -871 -527 3 142 117 437 527 365 714 649 152 611 638 -248 -380 -140 -632 -160 408 -840 -903 -573 -578 -272 324 79 61 -2 183 78 575 484 467 95 -65 -551 114 68 218 475 382 276 1166 310 18 85 -95 -178 205 -203 -158 -103 410 -299 -168 -56 -334 -226 -321 -226 -285 -405 -401 -370 -346 -313 -294 -320 -374 -358 -239 -247 -95 -124 -24 -47 80 28 25 46 173 -25 -43 -65 -191 -268 -237 27 43 181 247 -255 -601 -333 -514 -142 -71 -174 -490 -256 -204 -232 48 -147 -124 -151 -183 169 487 337 696 613 442 655 429 174 334 247 725 874 1177 941 -16 183 110 -65 653 551 114 203 -97 34 -292 -134 -117 -235 41 -449 -699 -960 -2079 -1374 -1073 -956 -606 4 169 134 489 543 371 707 685 171 732 820 -330 -502 -183 -768 -187 478 -1025 -1167 -774 -790 -393 481 121 98 -2 284 112 808 675 674 140 -102 -846 177 104 320 688 530 384 1615 445 27 131 -154 -298 341 -358 -283 -191 769 -549 -310 -99 -590 -386 SS 20210522T063415.4Z 7812.273790 240 1 48.25 2 64.05 89.04 124.20 337.09 0.00 1 0.00 1 0 17 1.713e-02 5.511e-03 2.170e-03 4.314e-04 3.690089e-01 2.224053e-04 4.720483e-03 -6.000000e+00 1.002807e-02 231.57 -2.00 3.80 -2.00 317.92 0.00e+00 6.047739e-04 3.711846e-05 1.507984e-04 -6.000000e+00 4.271201e-04 277.96 -2.00 20.00 -2.00 317.27 0.00e+00 2.272 0.000 302.00 328.00 3 2.0293e+00 5.9736e-04 3.1072e-02 -6.0000e+00 2.5180e-02 1.2741e-02 6.7137e-04 2.0870e-02 -6.0000e+00 2.7248e-02 -5.3191e-03 4.3147e-04 1.0213e-02 -6.0000e+00 1.6138e-02 -1.7029e-03 2.2114e-04 2.8737e-03 -6.0000e+00 6.7848e-03 4.4712e-03 -3.2901e-04 1.2454e-05 3.1699e-05 -6.0000e+00 4.7479e-04 -1.2904e-02 -3.4313e-05 10 0 0 10 0 0 97.78 21.02 0.24 -0.01290 -0.01538 442 104 1 5 0 109.140 25.28 20.00 21.02 19.21 32.2 1019.55 -4742 -4070 -4432 -7915 -6056 -7425 -4215 -5315 -3024 -5047 -4013 -4057 -2040 -1834 -42 -1116 -653 -475 38 526 -143 320 734 286 -435 -524 -1096 -1274 -1057 898 367 1087 1350 -1244 -2237 -1250 -1814 -525 -82 -602 -1072 -669 -369 -588 272 -365 -172 -331 -395 363 1265 765 1248 1291 859 1054 733 490 491 710 1149 1369 1660 1385 -22 308 14 -14 1026 662 114 111 -175 71 -357 -239 -148 -508 132 -656 -860 -1148 -2082 -1357 -979 -935 -503 -109 -51 -11 359 529 261 674 591 216 501 617 -334 -480 -170 -662 -235 363 -823 -854 -628 -596 -182 273 120 122 100 209 122 557 487 499 170 -54 -515 189 154 272 627 443 392 1219 327 130 77 -99 -168 220 -198 -97 -150 392 -357 -178 -137 -436 -326 -275 -262 -300 -527 -355 -432 -255 -363 -226 -413 -328 -351 -201 -212 -6 -170 -106 -75 6 91 -25 56 134 56 -90 -114 -244 -269 -209 177 80 258 353 -351 -603 -329 -528 -161 -30 -265 -488 -319 -183 -297 136 -185 -87 -165 -197 183 678 417 722 798 557 699 499 334 328 468 777 932 1236 1056 -17 241 11 -10 791 546 99 101 -159 62 -308 -186 -111 -367 100 -533 -795 -1125 -2110 -1435 -1049 -1074 -605 -128 -61 -13 399 570 261 691 607 235 611 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