File name: Pandora67s1_Cologne_20210629_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T113306.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210629_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210629T041312.8Z 7850.175843 187 1 46.86 2 84.13 59.87 66.45 188.73 0.00 1 0.00 1 0 25 4.717e-01 4.268e-02 3.940e-01 2.798e-02 9.427616e-01 1.676708e-02 1.341495e-02 -6.000000e+00 2.830711e-01 233.63 -2.00 3.80 -2.00 321.92 0.00e+00 3.593684e-02 7.647566e-03 2.567757e-03 -6.000000e+00 1.378016e-02 281.97 -2.00 20.00 -2.00 321.40 0.00e+00 8.673 0.014 302.00 328.00 3 1.3414e+00 5.7868e-02 1.0591e-01 -6.0000e+00 7.1766e-01 1.9940e+00 6.7931e-02 7.5679e-02 -6.0000e+00 7.7854e-01 -1.8673e+00 4.7002e-02 2.9074e-02 -6.0000e+00 4.5596e-01 6.5198e-01 2.4250e-02 3.1092e-02 -6.0000e+00 1.9166e-01 6.0481e-06 -2.8378e-03 7.4329e-04 4.7716e-04 -6.0000e+00 1.4334e-02 -3.7266e-05 6.0467e-05 12 9 8 11 8 0 98.06 21.86 0.85 -0.00004 -0.02136 12 3 1 5 0 3904.220 26.00 20.00 21.86 26.60 32.4 1046.37 -26729 117188 64343 -21846 100211 40929 -38961 67579 900000 -82250 900000 -76285 900000 -47197 76718 155712 108431 -34558 114476 14509 27284 900000 -27061 86487 -56211 31399 900000 105936 900000 900000 89451 -21015 23648 -25723 900000 900000 206114 900000 900000 -38486 57426 19385 -23331 31251 35979 67070 -14573 48614 46456 189287 1937 43935 900000 41622 79528 -12905 8840 19811 58512 69475 58820 -13256 90010 -4992 -13866 8891 14729 -2018 -2895 34557 21771 31113 30539 7794 -7299 -187 15654 -34163 -3575 290 6727 -2034 -2016 -13761 7404 1933 -3602 7398 26598 6633 532 -17387 5630 -5318 -3770 -10988 -8476 4785 2135 -937 1743 -1151 -8233 -6140 1330 1541 -4926 -3256 -220 1444 450 4236 -4105 -2569 731 1223 4750 -1238 -481 -1209 -384 4024 2052 4732 3460 -358 -552 -2447 3782 -604 -165 1459 -6064 -1511 5959 664 2421 -2837 1503 -1958 788 -1623 80 -1951 3190 2252 -1592 2728 1114 -1845 1840 900000 -3732 900000 -3390 900000 -3128 2089 4239 2952 -4072 3256 1069 1641 900000 -2102 2354 -4385 933 900000 2884 900000 900000 2435 -1955 1648 -3000 900000 900000 5611 900000 900000 -5035 3103 1559 -2935 2395 2697 3880 -1924 3645 3755 5153 278 4563 900000 4864 6461 -2459 1314 2481 4729 4984 4804 -2400 7040 -1114 -3638 1845 2936 -483 -746 6962 5298 7089 6690 1942 -1831 -39 2630 -9540 -872 83 2139 -802 -873 -7006 3192 923 -1875 3508 10543 3045 244 -8746 2225 -2461 -1946 -7223 -6542 3849 1949 -897 1557 -950 -6385 -4488 945 1149 -4087 -2905 -213 1564 567 5561 -6059 -3705 988 1595 6142 -1759 -717 -1872 -578 5562 2763 5951 4224 -448 -681 -3184 5361 -1031 -313 3023 -14388 -3658 14378 1758 6429 -7932 4078 -5234 1925 -3769 176 SS 20210629T055006.8Z 7850.243134 237 1 14.34 2 69.96 77.51 71.39 212.70 0.00 1 0.00 1 0 17 6.991e-02 9.704e-03 5.274e-02 6.312e-03 4.035708e-01 3.271998e-03 4.979424e-03 -6.000000e+00 4.126442e-02 233.63 -2.00 3.80 -2.00 318.80 0.00e+00 1.852006e-03 7.188801e-04 1.791542e-04 -6.000000e+00 1.771584e-03 281.98 -2.00 20.00 -2.00 318.09 0.00e+00 2.887 0.000 302.00 328.00 3 4.9726e+00 9.0501e-03 3.7036e-02 -6.0000e+00 1.0401e-01 6.2667e-02 1.0337e-02 2.3095e-02 -6.0000e+00 1.1228e-01 -2.0537e-02 7.2744e-03 1.1280e-02 -6.0000e+00 6.6541e-02 6.9931e-04 3.7950e-03 3.9762e-03 -6.0000e+00 2.7966e-02 1.2260e-04 2.0479e-03 1.8415e-04 3.8761e-05 -6.0000e+00 1.9380e-03 -5.3873e-03 4.1866e-04 12 9 9 12 1 1 94.93 21.95 0.44 -0.00539 0.01000 3 3 1 5 0 3540.280 26.11 20.00 21.95 27.76 32.5 1053.11 -44532 -28985 -23424 -17554 4317 -18602 187 -15675 7206 -153 -786 -25693 19261 -15352 4319 -7851 -2506 4909 9001 -13006 -329 4404 11554 5390 3555 4507 718 8560 925 11216 734 3646 736 -2548 1637 6256 493 -2871 -8311 -566 -1742 263 -1919 -1084 -1378 -270 513 936 -1707 484 1476 890 2797 865 682 -1354 383 -156 -416 748 2494 790 3761 2128 -196 1461 -239 -376 -92 1754 438 1292 953 -662 -700 178 -1097 -1217 -418 -1188 -1758 -2227 -1901 -2469 -1792 -1186 -49 297 2621 722 -253 127 785 1302 1208 -1158 640 556 -147 -760 -9 -368 -849 911 -976 20 -1100 -302 -551 651 683 1064 -186 302 -1133 983 897 -427 -335 223 -950 1115 -320 -317 486 38 -30 217 697 -606 220 278 -1055 207 422 -84 521 543 227 111 -422 -634 -530 -2029 -1302 -1045 -702 128 -682 6 -666 272 -7 -35 -1535 888 -1168 320 -735 -240 467 892 -1642 -37 476 1237 641 453 595 100 1072 119 1342 106 570 132 -484 288 1043 96 -660 -2379 -174 -600 94 -713 -407 -521 -102 196 355 -668 187 610 402 1298 438 355 -737 209 -86 -224 395 1340 458 2334 1432 -134 946 -154 -241 -61 1287 353 1058 782 -538 -535 124 -721 -777 -282 -890 -1454 -2036 -1839 -2485 -1888 -1308 -56 344 2987 807 -273 128 747 1233 1204 -1280 758 708 -199 -1020 -12 -449 -982 1065 -1218 26 -1476 -420 -792 983 1076 1721 -298 462 -1684 1390 1263 -625 -507 349 -1507 1750 -497 -480 701 53 -41 300 1006 -933 353 463 -1808 359 757 -158 984 1049 437 209 -786 -1155 -949 SS 20210629T060434.4Z 7850.253176 246 1 48.39 2 67.73 80.14 72.60 216.06 0.00 1 0.00 1 0 17 2.525e-02 5.526e-03 1.453e-02 2.059e-03 3.703310e-01 1.068641e-03 4.690976e-03 -6.000000e+00 1.487137e-02 233.63 -2.00 3.80 -2.00 318.60 0.00e+00 7.918967e-04 2.185291e-04 1.457567e-04 -6.000000e+00 6.398452e-04 281.98 -2.00 20.00 -2.00 317.89 0.00e+00 2.616 0.000 302.00 328.00 3 4.5148e+00 2.9341e-03 3.3851e-02 -6.0000e+00 3.7483e-02 2.6582e-02 3.3323e-03 2.1284e-02 -6.0000e+00 4.0489e-02 1.1611e-03 2.2657e-03 1.0320e-02 -6.0000e+00 2.3995e-02 -6.1888e-03 1.1756e-03 2.9223e-03 -6.0000e+00 1.0064e-02 2.6694e-04 -1.6010e-04 6.0788e-05 3.1787e-05 -6.0000e+00 7.0058e-04 -9.4537e-04 1.0059e-05 10 0 0 10 0 0 99.96 21.97 0.20 -0.00095 -0.00215 56 13 1 5 0 863.950 26.11 20.00 21.97 28.01 32.4 1054.63 -10881 -13894 -1509 -7460 -9921 -4949 740 -2147 -7559 -8377 333 -5963 7820 -3867 -1437 -1786 231 -4153 -47 783 -1402 1807 1216 -1342 383 -14 1158 -1002 -1020 2557 -1413 539 439 -2253 -1733 -752 -4374 -120 3502 -946 -930 -883 -1587 -376 766 -676 441 -613 -505 232 1268 355 1647 741 909 375 87 -199 14 954 1051 587 1900 1078 -236 952 42 562 914 1152 -250 343 466 440 -172 -541 -589 -713 99 -684 -633 -1408 -1929 -1628 -922 -595 -114 261 550 345 846 55 410 443 628 81 187 829 -171 -385 -169 -814 -93 92 -1230 -626 -743 -327 -476 442 238 351 78 101 -100 385 385 248 -116 -77 -583 166 225 247 621 233 104 1158 201 74 315 -203 -385 158 83 60 165 311 -215 -345 -109 -281 -337 -470 -667 -69 -341 -419 -197 30 -100 -417 -498 18 -373 498 -315 -134 -189 26 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