File name: Pandora67s1_Cologne_20210711_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T113628.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210711_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210711T085252.0Z 7862.370046 249 1 47.74 2 43.04 116.54 53.07 99.26 0.00 1 0.00 1 0 17 1.061e-02 7.051e-03 4.570e-03 2.285e-03 2.190178e-01 1.194267e-03 2.806014e-03 -6.000000e+00 6.269505e-03 233.80 -2.00 3.80 -2.00 316.11 0.00e+00 6.021201e-04 1.265191e-04 5.529436e-05 -6.000000e+00 2.702766e-04 283.08 -2.00 20.00 -2.00 315.42 0.00e+00 1.366 0.000 302.00 328.00 3 6.2492e+00 3.1365e-03 1.8629e-02 -6.0000e+00 1.5804e-02 5.5316e-02 3.4827e-03 1.2382e-02 -6.0000e+00 1.7053e-02 -6.1040e-03 2.0026e-03 5.9779e-03 -6.0000e+00 1.0112e-02 -6.6330e-04 9.1725e-04 1.6608e-03 -6.0000e+00 4.2547e-03 1.9770e-04 -4.4354e-05 6.6120e-05 1.9771e-05 -6.0000e+00 2.9429e-04 -1.5066e-02 8.1825e-05 11 8 0 10 0 0 99.89 21.69 0.08 -0.01507 -0.01540 15 4 1 5 0 3182.080 25.79 20.00 21.69 25.71 32.5 1037.90 -4052 -1179 -805 -2801 -1980 -3181 -1560 -3291 80 -612 -1065 -1357 730 -874 -1269 -375 1154 1445 954 -563 1917 2737 1497 901 -108 84 -54 -430 103 1599 866 1073 2073 -2325 -741 -383 -1096 -219 2536 -359 -1015 -865 -550 -623 -195 -410 -663 -919 -1096 44 346 159 1251 838 1467 810 -217 312 312 179 842 928 1855 1135 -300 -343 -569 -367 329 489 229 916 788 498 -18 -410 -331 -1792 -784 -1351 -891 -1543 -1958 -1384 -994 -869 -174 808 862 694 304 40 -124 -287 -83 -12 203 673 133 -115 105 -782 -1305 -136 -678 -1108 -572 -160 39 579 792 1153 339 132 -174 344 -290 -149 -201 379 -432 408 526 335 673 637 -698 604 495 0 14 -389 -763 -70 162 291 -8 679 75 150 -213 -696 -836 -816 -251 -174 -588 -368 -572 -290 -683 17 -142 -244 -314 183 -246 -398 -125 394 507 348 -215 723 1013 571 357 -45 36 -23 -177 39 588 336 431 884 -1053 -313 -157 -484 -108 1397 -229 -702 -612 -400 -458 -142 -297 -478 -642 -757 30 244 116 947 661 1171 659 -181 258 254 147 693 803 1691 1078 -288 -312 -491 -309 281 455 227 933 808 503 -17 -371 -277 -1441 -636 -1188 -848 -1568 -2114 -1533 -1144 -1047 -217 1019 1100 868 362 45 -131 -291 -87 -13 240 845 175 -149 132 -947 -1523 -158 -834 -1433 -759 -217 55 828 1177 1714 497 187 -234 438 -364 -190 -269 529 -621 586 742 464 897 817 -872 743 632 0 19 -544 -1087 -101 241 448 -12 1076 121 237 -330 -1063 -1258 SS 20210711T090701.6Z 7862.379880 258 1 24.18 2 41.08 120.47 50.95 102.26 0.00 1 0.00 1 0 17 9.103e-03 6.540e-03 4.353e-03 2.497e-03 2.076616e-01 1.311897e-03 2.674480e-03 -6.000000e+00 5.375869e-03 233.80 -2.00 3.80 -2.00 315.64 0.00e+00 6.119457e-04 1.256303e-04 3.127954e-05 -6.000000e+00 2.318172e-04 283.09 -2.00 20.00 -2.00 314.98 0.00e+00 1.325 0.000 302.00 328.00 3 5.7971e+00 3.4279e-03 1.7878e-02 -6.0000e+00 1.3551e-02 4.2430e-02 3.7979e-03 1.1756e-02 -6.0000e+00 1.4623e-02 -6.7310e-03 2.1711e-03 5.6748e-03 -6.0000e+00 8.6708e-03 1.0192e-03 9.7302e-04 1.5868e-03 -6.0000e+00 3.6477e-03 3.3274e-04 -3.1778e-04 7.1960e-05 1.9834e-05 -6.0000e+00 2.5241e-04 -1.4688e-02 4.1523e-05 12 9 1 12 1 1 78.10 21.71 0.22 -0.01469 -0.01708 6 3 1 5 0 3427.490 25.79 20.00 21.71 26.85 32.6 1045.85 -2729 -2949 -1013 -1626 338 -363 354 -1060 1513 -667 -433 -125 -153 -789 315 -1354 -953 1521 258 1794 1506 2036 1409 793 -162 735 77 -1441 1641 223 1132 645 2210 -2049 -1833 -432 -1638 -1038 1837 -586 -1111 -1048 -967 -359 26 -120 -1096 -1023 -677 389 -17 -127 852 778 701 526 502 104 493 813 765 1039 1966 1189 -274 408 -388 -789 727 553 22 867 118 434 275 -364 -264 -974 -608 -1346 -1126 -1236 -1853 -1049 -870 -578 -479 437 524 445 561 446 -285 61 208 -45 503 1261 -138 -380 123 -576 -992 -239 -924 -947 -497 -550 -16 565 128 793 74 225 -364 286 -32 390 -135 -8 -195 132 566 447 532 271 244 565 292 -121 325 -132 -509 290 337 322 169 452 -188 -366 -328 -543 -681 -674 -776 -272 -410 75 -79 80 -261 400 -187 -118 -34 -46 -265 113 -530 -384 614 109 768 644 871 618 360 -76 350 37 -673 706 95 489 295 1043 -1023 -867 -199 -816 -567 1118 -402 -813 -796 -744 -277 20 -91 -836 -764 -497 280 -13 -99 675 640 586 446 432 90 416 688 656 933 1832 1153 -269 380 -341 -680 639 522 22 895 124 444 271 -335 -228 -815 -508 -1217 -1087 -1265 -1990 -1152 -994 -690 -595 551 660 549 663 500 -305 62 218 -49 586 1558 -180 -489 153 -689 -1145 -278 -1130 -1199 -646 -734 -21 791 186 1155 105 310 -479 359 -41 497 -178 -11 -273 185 789 606 695 345 303 688 369 -158 434 -181 -704 408 489 482 258 697 -294 -567 -495 -807 -998 SS 20210711T092007.5Z 7862.388975 267 1 21.92 2 39.34 124.32 49.01 105.14 0.00 1 0.00 1 0 17 7.752e-03 6.030e-03 2.818e-03 1.714e-03 2.004960e-01 9.010559e-04 2.599966e-03 -6.000000e+00 4.578965e-03 233.80 -2.00 3.80 -2.00 315.43 0.00e+00 5.124257e-04 8.253474e-05 2.770071e-05 -6.000000e+00 1.973794e-04 283.09 -2.00 20.00 -2.00 314.79 0.00e+00 1.292 0.000 302.00 328.00 3 5.1298e+00 2.3494e-03 1.7370e-02 -6.0000e+00 1.1543e-02 3.2705e-02 2.6003e-03 1.1383e-02 -6.0000e+00 1.2455e-02 -3.9448e-03 1.4847e-03 5.4985e-03 -6.0000e+00 7.3849e-03 -1.1390e-03 6.5968e-04 1.5360e-03 -6.0000e+00 3.1076e-03 6.8259e-04 1.2980e-04 4.9231e-05 1.9608e-05 -6.0000e+00 2.1492e-04 -1.5243e-02 9.6505e-05 12 1 1 12 1 1 99.84 21.74 0.16 -0.01524 -0.01427 13 7 1 5 0 1553.080 25.90 20.00 21.74 28.29 32.5 1053.71 -1036 -446 -1707 -2196 -2120 -817 184 -412 990 -225 -1329 60 828 -987 -136 59 889 524 1418 155 357 681 1595 336 569 302 -171 -209 308 1335 1227 1154 1168 -1220 -2141 -530 -1465 -333 510 -612 -1251 -666 -1249 -743 -82 -580 -562 -771 -529 65 543 28 1271 972 1008 829 568 273 304 436 1189 907 1572 886 -203 49 -347 -238 1000 506 336 515 -65 375 -540 -134 -557 -725 -155 -1083 -1277 -1468 -2003 -1356 -677 -505 -205 265 491 254 421 455 121 385 701 -22 611 657 19 -439 -161 -518 -474 -134 -769 -715 -872 -394 -73 463 296 244 261 121 -60 543 330 9 44 11 -581 147 291 425 608 347 95 1083 308 98 234 122 -314 86 29 -7 -210 630 -266 -284 -95 -459 -605 -278 -126 -499 -612 -528 -195 46 -111 284 -68 -397 18 267 -351 -53 25 372 226 625 70 164 312 726 162 279 153 -88 -102 139 590 566 550 585 -634 -1065 -256 -752 -187 322 -433 -948 -514 -985 -588 -64 -453 -434 -584 -393 48 411 22 1019 811 856 713 491 236 261 372 1035 822 1486 873 -201 46 -310 -207 887 480 340 534 -69 384 -535 -125 -488 -609 -131 -988 -1239 -1517 -2152 -1495 -775 -600 -251 330 619 314 496 510 129 393 734 -25 712 812 25 -563 -199 -620 -544 -155 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