File name: Pandora67s1_Cologne_20210813_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T115507.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210813_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210813T050432.5Z 7895.211488 75 1 47.67 2 83.71 74.55 128.98 33.82 0.00 1 0.00 1 0 17 7.298e-01 3.999e-02 3.939e-01 2.131e-02 8.979456e-01 1.239018e-02 1.112452e-02 -6.000000e+00 4.354787e-01 232.54 -2.00 3.80 -2.00 321.92 0.00e+00 1.473382e-02 6.208986e-03 8.561298e-04 -6.000000e+00 1.934075e-02 283.66 -2.00 20.00 -2.00 321.39 0.00e+00 8.212 0.012 302.00 328.00 3 1.7211e+00 4.4852e-02 9.8612e-02 -6.0000e+00 1.0981e+00 1.5001e+00 5.5419e-02 5.7552e-02 -6.0000e+00 1.1913e+00 -1.6414e+00 4.0789e-02 2.6899e-02 -6.0000e+00 7.0354e-01 6.3733e-01 1.9856e-02 1.3410e-02 -6.0000e+00 2.9465e-01 8.7798e-06 -4.0453e-03 5.7391e-04 1.9067e-04 -6.0000e+00 2.1254e-02 -1.8015e-03 -1.9785e-05 12 8 8 10 0 0 8.82 21.67 0.69 -0.00180 -0.03220 16 4 1 5 0 2978.570 25.79 20.00 21.67 25.86 33.1 977.70 -54646 80082 420344 111750 15948 9692 78669 -161049 101952 -17366 105292 900000 182332 -37626 425814 186003 55552 900000 31204 -12883 -26466 253414 73427 211679 61080 14879 -52403 22448 27166 900000 -4342 21786 64165 27183 900000 21978 900000 40128 900000 26859 14665 16997 44402 32532 76414 42161 -6925 10732 782 125910 -2837 50520 18410 18796 106483 -10871 21982 34397 21270 33459 8668 15046 31422 3741 5330 7338 -642 32671 35207 785 27837 5602 23122 20022 12139 8043 1664 -34183 -9696 -4452 17546 -14246 -3197 -6201 2773 -1876 -11487 -11945 8486 11149 1437 -9422 -1003 -4767 7092 -2637 -1465 3052 4294 -2647 -702 -491 -4744 -4782 -1969 334 -4909 -4917 2342 -1162 1125 -701 104 -2100 -3749 4132 2161 89 -2482 4332 1984 -4962 4697 4517 3999 2659 1689 2027 234 -874 1439 -370 -4229 -1317 4119 -856 1224 -854 1187 -432 840 -1281 -2007 -3355 1662 8724 2319 404 225 1633 -16996 2116 -425 2185 900000 3784 -1883 8838 3861 1834 900000 1402 -878 -1906 5260 1735 4393 1502 556 -3571 695 772 900000 -230 1064 2372 1502 900000 1081 900000 1874 900000 1818 1213 1417 2923 2389 3643 2844 -761 1018 86 4314 -369 4374 2316 2509 6315 -1990 2913 3938 2567 3472 1146 2023 4147 723 1091 1461 -139 5331 6037 212 6294 1631 5497 4597 2686 1631 333 -9857 -2530 -1316 4961 -6324 -1413 -2989 1292 -955 -6686 -7135 4201 5198 687 -4693 -448 -2308 3467 -1663 -1087 2519 3931 -2617 -658 -416 -3775 -3630 -1531 269 -4336 -4732 2334 -1353 1449 -1013 154 -3178 -5587 5499 2947 129 -3913 6622 3067 -7831 6541 6064 5173 3388 2157 2636 354 -1511 2749 -784 -9864 -3182 10117 -2310 3308 -2386 3252 -1147 2070 -3040 -4521 SS 20210813T051523.0Z 7895.219016 78 1 48.33 2 82.06 76.60 128.07 36.92 0.00 1 0.00 1 0 17 5.286e-01 1.734e-02 3.274e-01 7.740e-03 8.182894e-01 4.381389e-03 9.967687e-03 -6.000000e+00 3.102079e-01 232.54 -2.00 3.80 -2.00 321.81 0.00e+00 1.039340e-02 2.435099e-03 1.830965e-03 -6.000000e+00 1.349170e-02 283.66 -2.00 20.00 -2.00 321.29 0.00e+00 6.754 0.007 302.00 328.00 3 1.9980e+00 1.6534e-02 8.3411e-02 -6.0000e+00 7.7925e-01 5.8900e-01 2.3180e-02 5.0646e-02 -6.0000e+00 8.4211e-01 -7.4356e-01 2.2385e-02 2.7891e-02 -6.0000e+00 5.0014e-01 2.9403e-01 1.0262e-02 1.3498e-02 -6.0000e+00 2.1103e-01 3.7355e-05 -1.4959e-03 2.1414e-04 1.8710e-04 -6.0000e+00 1.5006e-02 -3.7298e-03 -4.4846e-05 12 8 8 10 0 0 0.05 21.68 0.46 -0.00373 -0.01497 45 11 1 5 0 1073.650 25.79 20.00 21.68 26.35 32.8 978.84 -254629 -144708 -55347 -75010 -99715 -162084 -61074 -244063 -149188 -161794 43100 -114043 -75127 -69360 -76319 -28214 -57166 -2512 -29380 -80287 -30441 175553 -24669 -44534 7218 20754 -41605 -3742 45904 80716 -12997 70769 101861 73925 106098 -26091 15302 12897 900000 -2369 -21175 18063 16402 40519 14058 17462 3414 27162 17962 68752 10119 38789 12143 24736 18299 14281 6085 8153 1734 4546 5176 12750 19116 7112 6972 17592 9051 8756 11878 5185 8984 5377 7426 1203 4262 -897 -3813 -3349 1048 278 899 -4152 -3808 -972 588 167 -1954 417 3152 2296 -816 -3219 -327 34 -1983 -1883 -2135 -23 191 -1467 -932 -1317 -2259 -1255 -3801 -2618 -2123 -1210 398 -1008 -319 -748 -248 -18 228 448 -562 983 -395 1204 -221 118 2159 1450 1655 1389 529 1896 281 266 353 896 -836 404 85 -28 -72 438 -425 -417 443 -821 -1064 -8469 -1932 -418 -566 -783 -2164 -461 -7792 -2027 -2588 325 -1343 -794 -921 -1405 -392 -1208 -34 -559 -2617 -597 1325 -447 -1022 100 268 -967 -60 447 635 -314 935 1153 1185 1168 -1008 443 420 900000 -127 -1521 932 906 1810 832 1028 239 1574 1215 3156 901 2904 1298 2539 2116 1695 797 1029 224 583 683 1724 2685 1294 1360 3069 1742 1771 2558 1371 2529 1572 2171 350 1085 -215 -884 -798 274 88 325 -1833 -1858 -490 312 95 -1142 245 1873 1331 -455 -1730 -167 18 -1225 -1324 -1779 -21 195 -1538 -921 -1231 -1911 -1027 -3401 -2449 -2097 -1245 448 -1306 -451 -1151 -388 -27 337 638 -816 1471 -633 1973 -364 185 3199 2083 2355 1926 723 2670 444 466 692 1852 -1876 952 210 -73 -193 1184 -1128 -1089 1071 -1945 -2413 SS 20210813T052615.1Z 7895.226564 81 1 48.59 2 80.39 78.66 127.09 39.96 0.00 1 0.00 1 0 17 5.395e-01 9.109e-03 1.768e-01 3.454e-03 7.273876e-01 1.912954e-03 8.820865e-03 -6.000000e+00 3.166492e-01 232.54 -2.00 3.80 -2.00 321.34 0.00e+00 4.546339e-03 9.520202e-04 1.597945e-03 -6.000000e+00 1.377087e-02 283.66 -2.00 20.00 -2.00 320.79 0.00e+00 5.707 0.004 302.00 328.00 3 1.9161e+00 6.6336e-03 7.1387e-02 -6.0000e+00 7.9547e-01 1.3182e-01 9.3686e-03 4.3967e-02 -6.0000e+00 8.5966e-01 -1.7925e-01 9.6413e-03 2.4158e-02 -6.0000e+00 5.1046e-01 6.4061e-02 4.5185e-03 9.0947e-03 -6.0000e+00 2.1501e-01 1.3098e-04 -8.1657e-04 9.6816e-05 1.1409e-04 -6.0000e+00 1.4967e-02 -4.2211e-03 -4.1432e-05 11 8 0 10 0 0 1.03 21.70 0.30 -0.00422 -0.01036 100 23 1 5 0 485.840 25.79 20.00 21.70 26.65 33.0 981.95 -252874 -209112 -176174 -146978 -190014 -20718 -180762 -128996 -216968 -89449 -141923 -105399 -94873 -115291 -98920 -4676 -82111 -33003 -66043 -64966 -6736 -14338 -27451 -32624 -20210 -49243 -45992 -29625 16766 -34851 3269 -19065 9236 -20925 -2256 -24836 -2681 -13356 54396 -3003 -9006 949 -6246 5608 -2982 310 2198 8878 1484 12948 2492 9535 4659 8210 1383 3547 2233 2334 1989 -320 2804 3472 6042 3066 2640 4034 2432 1285 5218 702 4186 3476 2154 1061 322 106 -911 -3434 -97 -61 636 -1459 -2216 -792 -633 -497 -1180 -320 834 1429 24 244 -107 -496 218 -314 -50 504 -38 -627 -755 -981 -413 -425 -1669 -1705 -1173 -1391 127 -361 286 -66 229 37 27 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