File name: Pandora67s1_Cologne_20210817_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T115404.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210817_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210817T052751.6Z 7899.227681 86 1 10.64 2 80.98 79.92 149.08 324.15 0.00 1 0.00 1 0 17 5.103e-01 2.313e-02 3.407e-01 1.226e-02 7.900480e-01 7.017286e-03 9.670881e-03 -6.000000e+00 3.036070e-01 232.27 -2.00 3.80 -2.00 321.44 0.00e+00 1.020191e-03 3.532694e-03 4.126755e-03 -6.000000e+00 1.504663e-02 283.56 -2.00 20.00 -2.00 320.89 0.00e+00 6.041 0.005 302.00 328.00 3 2.3406e+00 2.4618e-02 7.8586e-02 -6.0000e+00 7.6160e-01 4.5588e-01 3.4574e-02 5.4319e-02 -6.0000e+00 8.2567e-01 -5.8241e-01 3.3996e-02 2.7851e-02 -6.0000e+00 4.8817e-01 2.3819e-01 1.5843e-02 7.7224e-03 -6.0000e+00 2.0670e-01 5.4491e-05 -9.2618e-04 3.4281e-04 1.2002e-04 -6.0000e+00 1.4641e-02 -2.4678e-03 5.6809e-06 12 9 9 12 1 1 67.61 21.23 0.20 -0.00247 -0.00943 6 8 1 5 0 1494.370 25.47 19.99 21.23 20.30 32.3 948.07 20029 900000 -159376 900000 900000 900000 -161242 -205650 -172857 900000 -140764 22080 -157357 900000 -61042 900000 -56250 -33165 -3999 900000 -36347 -2929 225397 -1516 900000 93190 76492 -30491 114170 29246 59222 9356 42091 -43440 84035 -60122 50203 63553 140575 36276 22074 48448 -77655 30439 24200 49238 7962 47303 41064 64726 9467 44155 18768 8833 9864 8413 6023 12522 23750 19451 11377 17188 24110 13083 5515 -2694 10812 -5945 4216 596 11485 3709 7481 737 3862 -2728 -1528 -6593 -224 -1926 -1435 2553 -2830 2616 305 1147 -918 5541 -1180 1119 -1130 -306 -3585 -2170 -1085 1320 -1454 309 -641 -1791 -2329 -3272 -913 -790 -445 -2464 1099 -3966 -2090 -1768 -683 193 -1057 973 -822 2101 1521 414 605 741 -1000 1956 1089 2418 1743 796 549 2082 -341 270 237 765 -1851 462 -192 437 84 248 119 -720 -166 -1389 98 239 900000 -2712 900000 900000 900000 -2533 -5382 -3685 900000 -2491 263 -4709 900000 -1148 900000 -1331 -698 -68 900000 -875 -51 2689 -30 900000 1112 913 -839 1362 490 893 267 1022 -2523 1414 -3818 1250 1621 2097 1724 1338 2447 -13342 1917 1624 2653 651 2756 2695 3630 1006 3783 2239 1256 1483 1337 993 1947 3222 2676 1709 2666 3981 2705 1286 -675 2429 -1631 1152 191 3669 1336 2556 252 1179 -795 -419 -1919 -69 -716 -618 1222 -1561 1454 183 728 -612 3605 -811 736 -708 -182 -2148 -1318 -737 1010 -1303 308 -700 -1988 -2492 -3260 -812 -689 -414 -2435 1110 -4446 -2506 -2359 -991 297 -1676 1484 -1237 2993 2192 621 945 1197 -1624 2994 1622 3462 2436 1089 744 2856 -530 463 443 1509 -3892 1007 -444 1044 203 610 293 -1722 -377 -3037 206 SS 20210817T061431.2Z 7899.260083 111 1 12.98 2 73.68 88.84 152.22 343.89 0.00 1 0.00 1 0 17 9.517e-02 8.090e-03 9.413e-02 5.315e-03 4.907267e-01 2.774160e-03 6.140362e-03 -6.000000e+00 5.579864e-02 232.26 -2.00 3.80 -2.00 319.53 0.00e+00 3.331630e-03 7.809800e-04 4.268762e-04 -6.000000e+00 2.428073e-03 283.56 -2.00 20.00 -2.00 318.84 0.00e+00 3.499 0.001 302.00 328.00 3 3.9773e+00 7.8942e-03 4.4968e-02 -6.0000e+00 1.4008e-01 7.4491e-02 9.3198e-03 2.8245e-02 -6.0000e+00 1.5142e-01 -2.5981e-02 7.5082e-03 1.4292e-02 -6.0000e+00 8.9928e-02 8.6789e-04 3.9227e-03 5.3087e-03 -6.0000e+00 3.7896e-02 1.6474e-04 -5.1332e-04 1.5226e-04 5.3014e-05 -6.0000e+00 2.6400e-03 -4.2347e-03 -4.7741e-05 12 9 1 12 1 1 97.72 21.28 0.31 -0.00423 -0.00809 6 6 1 5 0 1827.980 25.47 20.00 21.28 21.12 32.6 953.51 -2358 -43039 -38740 -26501 -16424 29407 -5650 -39555 -37617 -2337 -27502 16242 -27707 -22803 -19437 -5704 -7375 -7373 -27 3822 -1386 8772 -4896 5293 -2558 6592 -6938 -3632 10863 638 13465 -572 7039 -5528 11812 -10458 2398 715 14071 -6750 -3772 -843 2391 -4337 -1807 -446 -530 813 -1323 2140 -400 1186 -1861 1713 424 3515 -730 1526 -1663 1091 40 844 2715 2122 63 779 983 -80 1976 -69 1570 883 1346 -626 -917 -59 -909 -2267 -1038 -2691 196 -1987 -1892 -403 -740 -76 -119 80 406 1137 1178 696 -932 168 781 -171 -14 1079 -625 -352 -118 -926 -639 -102 -879 -1109 -856 -462 679 -184 1200 227 83 0 288 622 -276 132 -209 -486 -537 162 181 840 865 -432 -95 1294 7 253 -62 -483 -727 157 427 523 -532 596 -88 -4 -117 -275 -480 -32 -967 -888 -516 -271 305 -90 -951 -993 -48 -726 316 -992 -960 -936 -280 -406 -442 -2 231 -90 518 -346 363 -200 494 -608 -296 763 51 1094 -61 788 -722 1271 -1362 305 108 2249 -1540 -930 -214 618 -1197 -492 -122 -146 224 -381 623 -131 418 -711 681 179 1484 -321 655 -720 468 18 400 1408 1190 36 435 532 -44 1149 -45 1099 637 984 -445 -616 -36 -520 -1293 -633 -1840 150 -1670 -1689 -373 -722 -77 -127 86 437 1196 1173 660 -847 154 751 -180 -16 1363 -833 -473 -153 -1131 -731 -116 -1067 -1397 -1108 -622 970 -278 1910 373 136 -1 433 899 -400 198 -323 -792 -868 258 287 1268 1262 -625 -135 1832 11 402 -105 -853 -1314 289 819 1041 -1081 1221 -180 -7 -227 -521 -894 SS 20210817T061941.2Z 7899.263671 114 1 48.37 2 72.87 89.84 152.43 346.27 0.00 1 0.00 1 0 25 5.898e-02 5.401e-03 6.873e-03 5.526e-04 4.689473e-01 2.869057e-04 5.902624e-03 -6.000000e+00 3.457859e-02 232.26 -2.00 3.80 -2.00 319.19 0.00e+00 1.002686e-03 7.196477e-05 2.630934e-04 -6.000000e+00 1.504716e-03 283.56 -2.00 20.00 -2.00 318.47 0.00e+00 3.343 0.001 302.00 328.00 3 1.3075e+00 8.0376e-04 4.2955e-02 -6.0000e+00 8.6809e-02 1.0423e-02 9.3454e-04 2.6897e-02 -6.0000e+00 9.3839e-02 -5.5847e-03 7.1382e-04 1.3189e-02 -6.0000e+00 5.5730e-02 -2.7397e-03 3.7501e-04 3.7906e-03 -6.0000e+00 2.3484e-02 2.9451e-03 -5.0964e-04 1.5824e-05 4.1146e-05 -6.0000e+00 1.6361e-03 -4.1120e-03 -5.5999e-05 10 0 0 10 0 0 99.60 21.30 0.23 -0.00411 -0.00794 491 115 1 5 0 98.500 25.47 20.00 21.30 21.36 32.6 955.04 -20111 -17925 -16950 -22191 -20475 -26446 -17511 -21865 -14067 -18750 -11392 -18544 -8032 -9248 -1778 -4728 -1722 -2153 -244 -402 -280 -106 -2155 -823 -1878 -919 -3044 -2781 -4254 -379 -939 518 332 -1159 -3289 -1614 -2630 -903 279 -644 -934 -543 -1437 -458 502 -126 185 -445 -67 354 1216 618 1537 1065 940 1052 685 329 369 460 1094 1506 1982 1765 133 856 322 229 1068 749 177 400 -242 173 -357 -210 -334 -451 -111 -519 -674 -1163 -2055 -1290 -841 -809 -417 7 347 182 597 548 424 747 622 184 588 554 -293 -407 -334 -763 -258 289 -1150 -1009 -667 -583 -221 328 128 169 83 221 176 647 503 432 -3 -180 -613 82 60 255 578 270 382 1242 257 103 73 -63 -182 191 -254 -192 -37 359 -354 -114 -28 -267 -204 -428 -425 -422 -557 -460 -630 -416 -612 -412 -622 -362 -694 -326 -420 -90 -286 -111 -151 -18 -31 -22 -8 -184 -75 -185 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