File name: Pandora67s1_Cologne_20210831_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T120416.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210831_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210831 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210831T054937.6Z 7913.242796 239 1 36.56 2 80.68 87.90 27.50 173.68 0.00 1 0.00 1 0 25 5.358e-01 1.904e-02 2.758e-01 6.084e-03 7.708204e-01 3.380683e-03 9.458086e-03 -6.000000e+00 3.141960e-01 230.61 -2.00 3.80 -2.00 321.42 0.00e+00 4.847511e-03 1.689654e-03 2.811376e-03 -6.000000e+00 1.449683e-02 282.22 -2.00 20.00 -2.00 320.89 0.00e+00 5.866 0.004 302.00 328.00 3 2.4378e+00 1.1752e-02 7.4575e-02 -6.0000e+00 7.8645e-01 3.9566e-01 1.6205e-02 4.7650e-02 -6.0000e+00 8.5205e-01 -5.0907e-01 1.5864e-02 2.5878e-02 -6.0000e+00 5.0433e-01 2.0721e-01 7.4417e-03 8.6182e-03 -6.0000e+00 2.1298e-01 6.0114e-05 -1.4276e-03 1.6813e-04 1.2812e-04 -6.0000e+00 1.5118e-02 -2.6462e-03 -5.7937e-05 12 9 9 12 1 1 98.20 21.22 0.26 -0.00265 -0.01337 29 9 1 5 0 1212.980 25.47 20.00 21.22 22.21 32.8 958.98 47473 37093 84063 -206088 -116241 -228514 900000 -264740 -20746 -210223 900000 -158786 900000 -60509 -1765 -34817 -17781 58910 11001 705 -50553 63080 -58269 74157 -54037 -2880 -35840 65405 -5543 165437 -43122 27877 6504 22434 825 -4336 4094 12738 229955 2359 14394 5770 21472 5148 30149 -6997 31278 -4820 22947 20635 26794 15204 16525 6913 17894 10384 5899 11786 5600 4194 2948 11025 8450 13643 5028 15172 730 9040 666 7763 4758 6929 4035 4099 -1170 779 -1590 -5122 660 -2037 1143 -1585 2077 -1853 -1324 -4073 171 -2211 2551 -958 3145 -2065 -128 -3608 -1049 -149 -185 -54 -1552 -1156 -3109 97 -2711 -248 -2763 -1815 -2730 124 -619 -286 -610 507 -341 693 -483 -7 998 -297 9 613 910 927 1130 683 2020 622 2226 976 462 363 248 89 -490 212 390 -392 253 570 -478 -204 -190 -151 -1682 282 220 498 -4888 -1048 -5942 900000 -10931 -123 -6137 900000 -3465 900000 -832 -18 -570 -278 495 154 11 -1367 561 -1741 660 -1743 -58 -1020 679 -115 981 -1718 655 221 697 30 -166 158 526 1423 151 916 428 1430 413 1981 -656 2137 -474 1811 1803 2475 1769 2081 1010 2587 1615 983 1835 894 664 487 1847 1663 2909 1244 3355 188 2243 198 2377 1664 2473 1461 1392 -380 230 -451 -1541 213 -779 500 -796 1113 -1098 -835 -2816 118 -1556 1778 -667 1959 -1274 -75 -2291 -732 -116 -170 -56 -1736 -1296 -3470 96 -2552 -224 -2727 -1815 -2916 140 -750 -390 -911 784 -542 1101 -743 -10 1461 -459 14 1000 1465 1473 1730 1010 2910 881 3023 1394 728 633 469 184 -1046 477 914 -952 625 1425 -1208 -490 -439 -338 -3646 SS 20210831T055850.9Z 7913.249200 245 1 25.36 2 79.23 89.69 27.38 178.16 0.00 1 0.00 1 0 25 3.693e-01 8.724e-03 2.366e-01 5.157e-03 6.925171e-01 2.783789e-03 8.417525e-03 -6.000000e+00 2.150732e-01 230.60 -2.00 3.80 -2.00 320.98 0.00e+00 3.125661e-03 1.243515e-03 5.529678e-04 -6.000000e+00 9.365376e-03 282.22 -2.00 20.00 -2.00 320.42 0.00e+00 5.147 0.003 302.00 328.00 3 2.6960e+00 9.0768e-03 6.5200e-02 -6.0000e+00 5.3798e-01 1.7278e-01 1.2122e-02 4.0888e-02 -6.0000e+00 5.8248e-01 -1.9272e-01 1.2018e-02 2.1065e-02 -6.0000e+00 3.4613e-01 7.1237e-02 5.8173e-03 7.6943e-03 -6.0000e+00 1.4613e-01 1.0205e-04 -1.0474e-03 1.4290e-04 8.5086e-05 -6.0000e+00 1.0239e-02 -2.7638e-03 -9.5119e-05 12 9 1 12 1 1 98.55 21.24 0.39 -0.00276 -0.01063 22 10 1 5 0 1094.970 25.47 19.99 21.24 22.33 33.0 959.76 -29055 -192359 -100859 -98823 59088 -167907 -103744 -92416 -121694 -124150 -17435 -89227 51352 -82875 -93853 -52718 -57892 -22708 -24351 -49787 -26684 4721 -38611 -8957 -36561 -13660 -27469 -9465 -10126 -1882 -31946 -21810 -8153 -17999 -8047 -23642 -18102 -3373 42714 -9870 -560 4401 -121 4866 -1415 -1665 17 2281 11089 8529 8233 2133 8052 3668 2566 5679 -283 3379 605 1596 733 1369 3237 4370 885 2214 1266 4455 2832 2928 2547 2395 828 925 -2983 -2370 -1810 -2113 -528 -1577 865 -2704 -264 -132 -666 -824 -443 -654 758 348 1192 931 -1327 -1137 116 -575 -291 414 -475 -288 -332 -599 -1026 146 -1044 -947 -465 -521 -64 -294 -239 460 135 692 -379 587 -54 -222 -200 -86 -342 729 388 452 194 568 585 910 397 316 162 -124 -487 205 -67 202 -28 480 -574 -139 110 -101 -610 -146 -3225 -761 -707 297 -2209 -783 -697 -1389 -1585 -88 -984 258 -1427 -2287 -1030 -1355 -417 -495 -1377 -599 78 -1038 -196 -1124 -354 -840 -234 -249 -47 -1316 -966 -367 -964 -375 -1290 -1043 -198 1933 -879 -51 412 -13 493 -155 -188 2 264 1239 1055 1147 341 1333 696 525 1172 -64 733 131 337 162 330 873 1275 282 684 396 1402 994 1182 1106 1089 379 413 -1261 -894 -636 -756 -209 -748 454 -1636 -172 -91 -495 -636 -356 -541 622 277 901 662 -933 -821 93 -518 -294 467 -573 -346 -389 -661 -1032 143 -1113 -1034 -533 -645 -83 -420 -371 755 225 1111 -585 882 -82 -342 -326 -146 -577 1172 605 697 286 831 831 1332 637 542 300 -247 -1003 432 -147 471 -64 1136 -1374 -326 248 -216 -1286 SS 20210831T060809.8Z 7913.255668 251 1 19.50 2 77.76 91.50 27.38 182.70 0.00 1 0.00 1 0 25 3.213e-01 1.347e-02 2.244e-01 8.446e-03 6.225641e-01 4.526790e-03 7.693710e-03 -6.000000e+00 1.882959e-01 230.60 -2.00 3.80 -2.00 320.57 0.00e+00 1.006226e-03 1.748121e-03 5.588424e-04 -6.000000e+00 8.252466e-03 282.22 -2.00 20.00 -2.00 319.96 0.00e+00 4.577 0.002 302.00 328.00 3 3.8662e+00 1.3933e-02 5.8023e-02 -6.0000e+00 4.7117e-01 1.8580e-01 1.7782e-02 3.6091e-02 -6.0000e+00 5.1042e-01 -1.5288e-01 1.6584e-02 1.8181e-02 -6.0000e+00 3.0229e-01 5.1485e-02 8.2520e-03 5.3259e-03 -6.0000e+00 1.2725e-01 5.6727e-05 -1.3307e-03 2.4032e-04 6.4158e-05 -6.0000e+00 9.0115e-03 -2.0571e-03 -1.4551e-04 12 9 9 12 1 1 99.85 21.26 0.42 -0.00206 -0.01206 6 4 1 5 0 2759.890 25.47 20.00 21.26 22.13 32.8 958.41 -185344 7634 -79900 -125749 -72878 -117687 900000 -117388 62046 -105506 -41484 -97611 900000 -55913 -5758 -38702 28869 -4200 344 -34921 52313 63406 -20011 -9975 -28876 4367 -3287 -4945 6119 17439 -6685 -20228 8715 4613 -2494 13449 -7009 3056 71360 -17455 -7727 -250 -11213 3802 4482 -8512 7947 -1908 -4746 12329 -1282 9252 13860 -202 5508 991 -1147 1875 336 -866 542 1683 4779 5068 -33 113 2154 3465 -918 5804 4344 3632 4345 2405 -1384 -4452 -1724 -5492 -1691 -592 -1281 -2586 -961 -738 -4 -2505 -842 1740 3216 -575 1849 -1162 589 -764 -272 -1848 469 33 22 -972 -925 -1942 -1356 423 -1021 -786 -1632 -709 -293 -589 -260 789 479 271 -3 1790 -92 -467 -562 22 -352 98 833 730 1172 399 741 1218 1177 323 548 319 -1398 104 207 245 548 266 -1082 -219 182 3 -1071 -4967 63 -956 -2243 -727 -1810 900000 -2225 511 -2196 -486 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