File name: Pandora67s1_Cologne_20210912_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T120824.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210912_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210912T070358.2Z 7925.294424 115 1 48.85 2 71.97 106.45 132.09 67.71 0.00 1 0.00 1 0 25 8.515e-02 8.573e-03 5.772e-02 5.672e-03 3.932969e-01 2.916555e-03 4.956257e-03 -6.000000e+00 4.938442e-02 229.18 -2.00 3.80 -2.00 319.47 0.00e+00 7.505742e-04 7.698278e-04 2.549027e-04 -6.000000e+00 2.150382e-03 281.08 -2.00 20.00 -2.00 318.79 0.00e+00 3.187 0.001 302.00 328.00 3 5.2021e+00 8.2311e-03 3.8677e-02 -6.0000e+00 1.2315e-01 4.1084e-02 9.6119e-03 2.2265e-02 -6.0000e+00 1.3347e-01 7.8257e-03 7.2738e-03 1.1038e-02 -6.0000e+00 7.9350e-02 -1.1508e-02 3.7880e-03 3.2688e-03 -6.0000e+00 3.3592e-02 7.6381e-05 3.1094e-04 1.7157e-04 3.7182e-05 -6.0000e+00 2.3593e-03 -4.8534e-03 7.5814e-05 11 9 0 11 8 0 99.98 21.51 0.12 -0.00485 -0.00252 85 20 1 5 0 574.540 25.68 20.00 21.51 25.59 33.1 1000.48 -45410 -751 -18433 -12099 -26587 -20135 -19976 -55822 -28311 -8874 10371 -10199 -6524 5735 16270 -9207 2580 7768 7501 -2224 2874 2291 -6548 128 2345 -6941 -683 -9875 -4523 13505 -719 752 7016 1947 -5601 -5036 -2894 9000 17160 -843 -2412 -1539 -4592 785 -885 1205 -3433 -662 197 2938 247 1388 1632 616 1631 -1198 1013 609 1901 -31 2171 1423 1819 249 -605 563 -1696 -481 502 922 1182 1763 1918 1078 364 758 -724 -465 -289 -216 -1486 -1729 -2975 -907 -1211 -1183 -654 53 252 698 1224 -356 590 -139 1574 -351 -70 589 700 331 -293 -781 -1103 -108 -1625 -1277 -959 -710 540 174 767 77 199 46 -788 387 284 -93 309 88 -532 158 387 -94 1019 514 290 1285 379 348 276 -221 -872 434 28 -131 -52 303 -28 -229 221 -151 -787 -1620 -20 -603 -360 -826 -581 -623 -2678 -1184 -328 328 -417 -303 280 828 -675 181 553 568 -194 244 196 -626 12 234 -796 -75 -1126 -471 1212 -81 93 902 276 -810 -720 -450 1447 3014 -207 -653 -436 -1398 230 -265 363 -1060 -202 60 895 84 495 621 254 696 -530 457 276 832 -14 972 694 956 144 -359 311 -919 -257 283 588 815 1264 1371 744 239 445 -403 -250 -165 -139 -1077 -1407 -2604 -818 -1175 -1209 -698 58 277 737 1209 -330 515 -120 1427 -357 -79 726 923 432 -364 -918 -1227 -121 -1954 -1617 -1249 -978 781 268 1239 129 326 73 -1187 544 397 -135 469 142 -877 254 607 -145 1471 726 395 1742 550 548 457 -387 -1556 794 54 -267 -108 633 -59 -478 439 -295 -1504 SS 20210912T080654.1Z 7925.338126 157 1 30.70 2 62.89 120.34 123.14 81.54 0.00 1 0.00 1 0 17 1.297e-02 5.965e-03 5.833e-03 1.962e-03 2.738868e-01 1.002858e-03 3.543489e-03 -6.000000e+00 7.519482e-03 229.17 -2.00 3.80 -2.00 317.11 0.00e+00 4.750824e-04 1.364306e-04 6.679790e-05 -6.000000e+00 3.274251e-04 281.07 -2.00 20.00 -2.00 316.41 0.00e+00 2.183 0.000 302.00 328.00 3 4.7063e+00 2.6441e-03 2.6584e-02 -6.0000e+00 1.8751e-02 2.7464e-02 2.9637e-03 1.5348e-02 -6.0000e+00 2.0322e-02 2.5642e-03 1.7699e-03 7.4977e-03 -6.0000e+00 1.2082e-02 -4.8395e-03 8.6332e-04 2.1302e-03 -6.0000e+00 5.1151e-03 3.9331e-04 2.1678e-04 5.7264e-05 2.4742e-05 -6.0000e+00 3.5925e-04 -5.5268e-03 5.4302e-05 12 1 1 12 1 1 99.96 21.61 0.09 -0.00553 -0.00390 21 8 1 5 0 1386.970 25.79 20.00 21.61 27.59 33.2 1012.17 358 -3048 -420 -8376 -1253 -1272 2383 -5084 1296 -4804 1255 -2504 919 662 -77 -123 299 -462 -608 1029 -379 3129 -45 563 -1401 719 -550 460 -842 2021 367 1875 1276 -736 -1217 571 -1807 -1035 1911 -1130 -1177 -822 -390 -879 -253 -657 -751 -592 -684 468 1693 281 488 1065 789 779 638 149 72 999 722 1599 1214 1287 -739 166 -881 -21 750 898 229 215 -22 394 -227 56 142 -765 339 -1057 -689 -1408 -1856 -1586 -716 -1055 32 105 609 117 536 359 419 795 592 18 260 709 -233 -117 -367 -590 -644 548 -962 -701 -886 -421 -259 364 201 118 147 148 -215 562 382 167 55 -270 -488 87 255 336 613 355 520 671 481 282 234 128 -492 353 63 120 47 256 -390 68 -278 -470 -599 40 -383 -53 -1065 -136 -135 260 -651 173 -710 176 -378 149 123 -16 -28 72 -115 -158 272 -103 818 -13 165 -431 225 -175 138 -238 564 110 592 433 -259 -409 189 -654 -422 879 -604 -671 -487 -235 -538 -154 -400 -455 -351 -404 276 1029 181 326 740 569 565 472 110 53 726 536 1246 1006 1112 -650 137 -700 -16 603 784 217 207 -21 375 -207 47 112 -587 265 -904 -636 -1401 -1946 -1720 -807 -1241 39 130 757 142 619 393 436 802 614 20 311 903 -309 -154 -467 -722 -753 646 -1211 -911 -1184 -579 -367 533 307 182 221 214 -299 740 505 225 78 -397 -730 130 375 479 847 479 675 875 648 399 342 191 -748 544 100 198 80 436 -671 116 -461 -769 -965 SS 20210912T082000.1Z 7925.347223 166 1 5.72 2 61.14 123.47 121.22 84.17 0.00 1 0.00 1 0 17 1.057e-02 6.089e-03 5.520e-03 2.329e-03 2.560981e-01 1.193979e-03 3.352258e-03 -6.000000e+00 6.126859e-03 229.17 -2.00 3.80 -2.00 316.60 0.00e+00 3.429287e-04 1.429442e-04 5.537644e-05 -6.000000e+00 2.668409e-04 281.07 -2.00 20.00 -2.00 315.92 0.00e+00 2.062 0.000 302.00 328.00 3 3.5652e+00 3.1223e-03 2.5043e-02 -6.0000e+00 1.5278e-02 8.0149e-03 3.4875e-03 1.4371e-02 -6.0000e+00 1.6559e-02 3.8975e-04 2.0391e-03 7.0290e-03 -6.0000e+00 9.8452e-03 -1.8115e-03 9.6663e-04 1.9691e-03 -6.0000e+00 4.1672e-03 1.4393e-03 -5.3183e-05 6.7619e-05 2.3939e-05 -6.0000e+00 2.9283e-04 -5.0629e-03 3.1052e-06 12 1 1 12 1 1 97.86 21.64 0.23 -0.00506 -0.00546 10 23 1 5 0 503.520 25.79 20.00 21.64 27.48 33.1 1010.79 -3555 -634 -3430 -4252 -4948 -610 -1820 1858 -490 -328 -923 158 559 331 327 -105 1320 797 1143 37 500 684 1674 288 168 -536 -655 -1040 392 1358 1912 1683 663 -1069 -2449 -59 -1626 161 319 -796 -1641 -277 -978 -912 -641 -790 -908 -551 -553 815 793 512 1565 933 675 1060 975 268 691 693 914 1152 2018 1085 -261 -225 -65 -214 907 657 62 218 70 -12 -95 105 -267 -242 -1003 -1180 -800 -1389 -1880 -1059 -1070 -740 -263 192 78 152 -22 483 239 563 1115 247 655 451 -504 -286 -234 -660 -622 360 -748 -847 -605 -763 -35 412 304 541 310 181 123 486 255 192 -97 -169 -654 123 47 119 808 627 541 1047 447 187 245 34 -113 222 -96 -185 -5 166 -294 -257 -182 -324 -483 -564 -102 -583 -705 -733 -84 -271 295 -88 -62 -175 30 116 79 85 -30 391 237 353 12 163 221 553 102 60 -200 -246 -380 131 447 665 627 261 -440 -956 -23 -683 74 164 -471 -1039 -180 -643 -606 -423 -521 -606 -358 -352 514 528 355 1133 698 510 812 761 210 529 528 718 941 1728 974 -236 -193 -53 -177 758 590 60 215 70 -12 -89 93 -222 -195 -824 -1032 -762 -1403 -1997 -1142 -1211 -876 -319 234 97 185 -26 530 253 570 1174 276 774 570 -669 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