File name: Pandora67s1_Cologne_20220308_L2Fit_fwvt1c2d20200629p1-8.txt File generation date: 20250409T130021.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20220308_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20220308 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 1702 1852 Nominal wavelengths inside fitting window [nm]: 492.0797 492.2003 492.3208 492.4414 492.5619 492.6824 492.8029 492.9234 493.0438 493.1642 493.2847 493.4051 493.5255 493.6458 493.7662 493.8865 494.0068 494.1271 494.2474 494.3677 494.4879 494.6082 494.7284 494.8486 494.9688 495.0890 495.2091 495.3292 495.4494 495.5695 495.6895 495.8096 495.9297 496.0497 496.1697 496.2897 496.4097 496.5297 496.6496 496.7696 496.8895 497.0094 497.1293 497.2491 497.3690 497.4888 497.6086 497.7284 497.8482 497.9680 498.0877 498.2074 498.3272 498.4469 498.5665 498.6862 498.8058 498.9255 499.0451 499.1647 499.2843 499.4038 499.5234 499.6429 499.7624 499.8819 500.0014 500.1208 500.2403 500.3597 500.4791 500.5985 500.7179 500.8372 500.9566 501.0759 501.1952 501.3145 501.4338 501.5530 501.6723 501.7915 501.9107 502.0299 502.1490 502.2682 502.3873 502.5064 502.6255 502.7446 502.8637 502.9827 503.1018 503.2208 503.3398 503.4588 503.5777 503.6967 503.8156 503.9345 504.0534 504.1723 504.2911 504.4100 504.5288 504.6476 504.7664 504.8852 505.0039 505.1227 505.2414 505.3601 505.4788 505.5974 505.7161 505.8347 505.9533 506.0719 506.1905 506.3091 506.4276 506.5462 506.6647 506.7832 506.9017 507.0201 507.1386 507.2570 507.3754 507.4938 507.6121 507.7305 507.8488 507.9672 508.0855 508.2037 508.3220 508.4403 508.5585 508.6767 508.7949 508.9131 509.0312 509.1494 509.2675 509.3856 509.5037 509.6218 509.7398 509.8579 509.9759 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220308T060655.5Z 8102.254809 35 1 16.75 2 90.03 97.73 105.42 32.52 0.00 1 0.00 1 0 64 2.335e-02 2.327e-02 2.043e-03 2.029e-03 4.455567e+03 1.160005e+02 2.659072e+02 -6.000000e+00 1.212037e+03 269.24 -2.00 20.00 -2.00 505.39 0.00e+00 5.435537e-03 5.407803e-05 2.845259e-04 -6.000000e+00 6.308745e-04 269.24 -2.00 20.00 -2.00 501.22 0.00e+00 -2.117862e-01 3.869986e-02 6.541612e-02 -6.000000e+00 4.662143e-01 224.84 -2.00 3.80 -2.00 502.67 0.00e+00 20.791 0.195 489.00 513.00 1 5.5966e+00 2.9441e-03 4.1376e-02 -6.0000e+00 3.5458e-02 -5.5997e-03 7.5414e-04 2.4646e-03 -6.0000e+00 9.4321e-03 3.6543e-04 1.7450e-02 1.9556e-04 1.0738e-04 -6.0000e+00 2.2855e-03 1.5358e-01 -1.9575e-03 12 9 9 12 1 1 -102.05 20.13 18.74 0.15358 0.27463 4 4 1 4 0 3314.160 24.56 19.99 20.13 6.57 34.6 971.24 900000 -5328 -2675 -240 1099 2558 3809 3623 3008 2490 852 -34 -1535 -2657 -2792 -2166 -1318 -298 1135 1390 1188 1917 1580 2238 2473 2575 2109 1032 -943 -3052 -3558 -3173 -2487 -1782 1426 1907 1042 408 -103 -551 -496 413 1027 2161 3113 2994 2900 2229 970 -514 -2712 -3929 -4867 -4053 -2539 -446 963 2485 2530 2085 2911 2767 2913 3107 2374 1342 884 -711 -1395 -2107 -2856 -2506 -1982 -1351 -583 -782 -1597 -2841 -3792 -4003 -3571 -3098 -2164 -2793 -1459 -1491 -1566 -1575 -1385 -1311 -810 -69 1088 2215 2437 1623 1258 -228 -1444 -3903 -4806 -3812 -3146 -1522 153 379 -61 -757 -1818 -1671 -464 748 2107 3178 3963 4174 4598 4532 4058 3304 1806 1239 903 863 1641 1620 1491 1491 1324 1153 1012 -15 -935 -2359 -2639 -2890 -1712 -763 154 715 1032 859 1330 1511 1756 2540 -104 -1126 -2391 -3676 -3789 900000 -4708 -2389 -218 971 2278 3413 3282 2732 2245 771 -31 -1381 -2387 -2509 -1950 -1195 -273 1052 1304 1122 1803 1497 2120 2360 2372 1952 956 -868 -2900 -3357 -3002 -2286 -1684 1351 1822 1000 390 -98 -526 -476 399 1003 2125 3079 2875 2787 2141 931 -491 -2677 -3845 -4773 -3981 -2427 -432 946 2446 2506 2078 2886 2771 2937 3136 2405 1359 888 -717 -1402 -2107 -2856 -2509 -1997 -1369 -592 -798 -1625 -2885 -3845 -4046 -3604 -3144 -2196 -2764 -1441 -1490 -1572 -1578 -1383 -1313 -815 -70 1112 2267 2484 1647 1259 -226 -1411 -3825 -4711 -3732 -3132 -1544 158 396 -62 -791 -1835 -1691 -473 769 2181 3309 4146 4399 4871 4844 4359 3544 1940 1321 957 916 1748 1738 1610 1561 1390 1215 1066 -16 -978 -2478 -2765 -3045 -1816 -821 168 783 1138 956 1480 1691 1902 2820 -113 -1214 -2642 -4066 -4213 SQ 20220308T060959.3Z 8102.256936 39 1 46.31 2 89.55 98.32 105.16 33.19 0.00 1 0.00 1 0 22 1.664e-02 1.639e-02 4.880e-04 4.842e-04 6.425032e+03 2.855631e+01 3.998631e+02 -6.000000e+00 8.645630e+02 269.24 -2.00 20.00 -2.00 505.45 0.00e+00 5.057432e-03 1.295980e-05 2.727011e-04 -6.000000e+00 4.484311e-04 269.24 -2.00 20.00 -2.00 501.34 0.00e+00 4.106722e-01 9.212473e-03 8.241946e-02 -6.000000e+00 3.281352e-01 224.84 -2.00 3.80 -2.00 502.79 0.00e+00 20.086 0.176 489.00 513.00 1 4.1084e+00 7.0071e-04 3.9019e-02 -6.0000e+00 2.5033e-02 -4.6997e-02 1.7787e-04 2.6034e-03 -6.0000e+00 6.5220e-03 1.7106e-03 -6.0347e-04 4.6174e-05 1.1150e-04 -6.0000e+00 1.6259e-03 -5.9395e-03 -5.7898e-05 12 9 9 12 1 1 36.27 20.13 13.44 -0.00594 -0.01013 64 16 1 4 0 709.590 24.56 20.01 20.13 6.64 34.5 971.29 -4352 -3678 -2043 -214 1139 2043 2752 2869 2519 1929 977 225 -803 -1552 -1907 -1597 -835 -126 775 1231 1309 1384 1272 1354 1597 1753 1662 807 -422 -1986 -2791 -2549 -1877 -597 819 1270 998 280 -152 -464 -336 44 761 1503 1947 2142 2007 1585 683 -435 -1735 -2720 -3287 -2910 -1726 -362 822 1426 1439 1556 1440 1794 1977 2052 1589 1060 465 -280 -991 -1563 -1909 -1708 -1322 -907 -525 -672 -1233 -1947 -2440 -2619 -2587 -2232 -1786 -1656 -1286 -934 -930 -1131 -1191 -861 -588 218 1040 1545 1579 1434 714 -215 -1499 -2768 -3177 -2913 -1973 -814 181 311 -240 -804 -1321 -1060 -362 516 1502 2200 2678 3102 3347 3218 2677 1979 1338 818 597 716 1011 1193 1133 1153 1058 972 673 19 -740 -1392 -1879 -1702 -975 -387 331 693 707 711 759 944 1031 965 -92 -1082 -2098 -2614 -2418 -3761 -3208 -1755 -188 1019 1855 2532 2577 2267 1727 872 207 -735 -1412 -1738 -1463 -745 -114 714 1147 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