File name: Pandora67s1_Cologne_20220419_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T131302.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20220419_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20220419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220419T050537.7Z 8144.212242 208 1 50.08 2 85.34 78.00 86.14 226.80 0.00 1 0.00 1 0 25 7.728e-01 7.236e-02 4.471e-01 4.497e-02 1.193884e+00 2.734065e-02 1.536956e-02 -6.000000e+00 4.595364e-01 228.16 -2.00 3.80 -2.00 321.98 0.00e+00 1.706377e-02 9.573438e-03 2.747257e-03 -6.000000e+00 2.013152e-02 274.01 -2.00 20.00 -2.00 321.50 0.00e+00 10.346 0.024 302.00 328.00 3 -1.9712e-01 8.7002e-02 1.2517e-01 -6.0000e+00 1.1489e+00 3.0566e+00 9.9802e-02 7.1943e-02 -6.0000e+00 1.2545e+00 -2.7227e+00 5.9775e-02 3.3470e-02 -6.0000e+00 7.3991e-01 8.7912e-01 3.3096e-02 1.9661e-02 -6.0000e+00 3.1179e-01 3.5097e-06 8.9221e-04 1.0834e-03 3.2493e-04 -6.0000e+00 2.2899e-02 -8.3915e-03 -9.8959e-06 12 8 8 10 0 0 10.65 20.66 1.30 -0.00839 -0.00169 16 4 1 5 0 3128.970 24.96 20.00 20.66 14.99 33.8 994.64 900000 277093 18456 165293 162735 52146 -50780 -47041 167677 195300 5122 19043 900000 56406 -18821 213169 120073 900000 54254 71722 900000 900000 97917 -40981 900000 -2078 317133 -52634 83814 181011 122750 -59802 900000 9494 900000 -1899 38441 900000 900000 93958 -10356 37681 17703 93339 55433 900000 -58918 -4561 57010 208678 -49397 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-7354 3497 4706 3884 870 6230 -7476 -6051 -2651 -537 -5740 9580 10578 1823 -239 -1134 -7260 -3936 16395 5055 1044 -1033 6196 -10100 20561 5911 -2689 2931 1847 -1174 -475 4878 -7783 8456 -7059 2391 -6497 4690 -11983 -84 -397 4489 8364 -3139 -8097 -4197 -13952 -2255 22294 -5620 879 -9 -5944 -7123 22298 -3440 1669 SS 20220419T051750.0Z 8144.220717 211 1 48.58 2 83.45 80.33 87.54 229.15 0.00 1 0.00 1 0 25 5.426e-01 1.852e-02 3.882e-01 9.104e-03 1.150315e+00 5.432514e-03 1.319943e-02 -6.000000e+00 3.142027e-01 228.16 -2.00 3.80 -2.00 322.47 0.00e+00 4.470293e-03 3.136134e-03 7.348504e-03 -6.000000e+00 1.373424e-02 274.01 -2.00 20.00 -2.00 322.08 0.00e+00 7.961 0.011 302.00 328.00 3 5.4532e-01 2.1249e-02 1.1619e-01 -6.0000e+00 7.8261e-01 1.3946e+00 3.0963e-02 9.6991e-02 -6.0000e+00 8.4995e-01 -1.7477e+00 3.1789e-02 4.4842e-02 -6.0000e+00 5.0336e-01 6.8069e-01 1.4608e-02 1.3982e-02 -6.0000e+00 2.1473e-01 3.2737e-05 -1.5635e-03 2.3294e-04 2.0214e-04 -6.0000e+00 1.5616e-02 -9.5238e-03 -2.9708e-05 12 8 8 10 0 0 5.95 20.66 0.44 -0.00952 -0.02127 78 18 1 5 0 622.800 24.96 20.00 20.66 15.36 33.9 997.73 900000 -34806 -157126 -125606 900000 -122444 -168820 -179586 -224575 18967 -61112 -126735 -56162 7941 -65972 39870 -13181 127972 -38113 -60511 52409 900000 66128 -90636 140538 -67912 206272 -54159 44215 37373 38561 -40343 5648 11151 42153 -58722 22024 168371 900000 75848 -22179 39675 -1540 7143 64400 15511 2986 4772 22746 93884 54377 35584 35444 52292 58320 41786 23133 37825 31618 7695 17976 15664 13086 17768 23103 15993 13397 15128 23272 24088 28257 26425 21730 7778 4183 11161 1187 -3908 4442 2770 6593 -701 819 5122 683 2219 1363 3505 6839 1828 2539 5787 -5324 -4204 -4177 -2331 -2622 -976 -799 -3362 -1303 -1752 -2514 -3732 -2796 -2582 -1633 -2279 -142 -1896 -2771 -1082 -984 -500 -881 -535 -531 914 353 1437 366 2002 1689 1403 1223 1597 1396 1209 1072 815 111 885 -784 124 323 27 255 436 -327 -206 556 -996 -1773 900000 -309 -3950 -2043 900000 -1448 -3120 -3718 -7472 168 -542 -1874 -589 70 -1171 354 -202 1135 -830 -1611 465 900000 587 -2924 1247 -1753 1830 -1092 392 332 435 -1237 128 252 646 -2321 409 1494 900000 1285 -1109 1120 -67 282 1402 550 123 204 881 1969 1930 1722 1887 2573 2869 2494 1679 2288 1887 546 1145 1112 1108 1691 2292 1741 1567 1879 2966 3497 4330 4241 3523 1317 644 1404 156 -577 717 565 1443 -196 254 1621 239 807 516 1316 2468 666 856 1797 -1870 -1601 -1884 -1258 -1719 -754 -642 -2836 -1021 -1340 -1688 -2398 -1865 -1810 -1206 -1874 -120 -1934 -3370 -1459 -1406 -723 -1258 -746 -749 1328 540 2219 551 2768 2224 1782 1502 1918 1662 1542 1626 1481 218 1944 -1914 326 912 80 725 1244 -932 -592 1445 -2405 -4041 SS 20220419T052837.8Z 8144.228216 214 1 48.50 2 81.76 82.40 88.83 231.20 0.00 1 0.00 1 0 17 8.248e-01 1.292e-02 1.894e-01 3.334e-03 9.962142e-01 1.882730e-03 1.146700e-02 -6.000000e+00 4.764657e-01 228.16 -2.00 3.80 -2.00 322.02 0.00e+00 6.725841e-03 1.029101e-03 2.505699e-03 -6.000000e+00 2.023228e-02 274.01 -2.00 20.00 -2.00 321.61 0.00e+00 6.554 0.006 302.00 328.00 3 5.9286e-01 6.8737e-03 9.0721e-02 -6.0000e+00 1.1881e+00 5.4370e-01 1.1015e-02 6.8401e-02 -6.0000e+00 1.2901e+00 -7.2855e-01 1.2627e-02 3.5386e-02 -6.0000e+00 7.6445e-01 2.9274e-01 5.7182e-03 1.4064e-02 -6.0000e+00 3.2237e-01 1.5772e-04 -9.9031e-04 8.5289e-05 1.7005e-04 -6.0000e+00 2.2842e-02 -9.4670e-03 -4.3230e-05 12 8 8 10 0 0 32.38 20.66 0.31 -0.00947 -0.01691 192 45 1 5 0 252.560 24.96 20.00 20.66 16.29 33.7 1002.67 -246406 -210064 -306512 -241227 -265682 -258186 -286529 -242727 -287216 -240423 -216390 -208195 -79058 -124891 -139130 -128714 -38515 -75712 -86692 -126695 -13816 -34328 -105610 -115885 374 -122197 -11821 -81665 -42193 -34757 -56620 -46773 1906 4681 -28154 -32810 -46477 45167 50958 15372 -11977 32107 -2802 22102 -3187 15640 360 3295 6960 22457 11191 14931 19597 13165 21185 12532 16146 9057 14336 -2469 10325 6748 13268 11595 11732 10757 12580 9337 10836 8805 9222 7066 4014 4346 1547 3309 -2589 1320 -600 1385 1501 1787 244 525 -898 -93 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