File name: Pandora67s1_Cologne_20220519_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T132936.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20220519_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20220519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220519T045830.2Z 8174.207294 206 1 49.66 2 79.34 71.69 85.34 212.36 0.00 1 0.00 1 0 17 3.934e-01 2.649e-02 2.140e-01 6.510e-03 6.914924e-01 3.555736e-03 9.153384e-03 -6.000000e+00 2.298260e-01 231.33 -2.00 3.80 -2.00 321.14 0.00e+00 2.254040e-02 1.526057e-03 2.527241e-03 -6.000000e+00 1.021750e-02 277.61 -2.00 20.00 -2.00 320.63 0.00e+00 5.202 0.003 302.00 328.00 3 3.4743e+00 1.1378e-02 6.5972e-02 -6.0000e+00 5.7761e-01 5.4746e-01 1.4100e-02 4.3809e-02 -6.0000e+00 6.2583e-01 -7.1179e-01 1.2791e-02 2.7546e-02 -6.0000e+00 3.7017e-01 3.0706e-01 6.3335e-03 2.3232e-02 -6.0000e+00 1.5662e-01 3.8981e-05 -1.0933e-03 1.8196e-04 2.9704e-04 -6.0000e+00 1.1176e-02 -1.6606e-03 -2.2759e-05 12 8 8 10 0 0 32.09 21.92 0.22 -0.00166 -0.00988 21 5 1 5 0 2364.620 26.00 20.00 21.92 26.56 35.0 1010.88 -111960 900000 57509 -56260 35583 76075 -105400 -106396 -86846 900000 26349 -75570 -35264 2415 51995 19850 69297 12404 -139318 41697 21506 241335 83301 -7564 9346 8705 -22282 4022 55652 119646 47183 25244 44344 32650 58036 62688 42481 53880 900000 8613 36067 9934 14350 17660 26718 26316 13593 29924 25536 33361 28084 29845 28251 23864 16795 376 8681 10364 7512 5906 12259 4672 18178 12175 11309 9577 7714 4882 6019 6331 4091 5811 3327 283 -3622 -1281 415 -5916 -3074 -4396 2761 -1562 -3816 -2065 -2995 -3070 -3048 1144 -250 1015 430 -2674 -3941 -4768 -2505 -3234 -1841 -796 795 739 542 -481 -1758 -2459 -3665 -1719 -4191 -1227 -574 -354 269 742 -566 -350 -1362 73 686 505 -353 1073 414 1831 1529 1707 1887 1835 1507 2332 1527 843 736 741 -225 -146 317 255 -182 -129 -777 -864 637 -1381 -1352 -3664 900000 468 -1279 293 483 -2832 -2801 -1879 900000 189 -1620 -695 45 784 489 1216 405 -19997 1140 693 1531 1367 -282 284 262 -898 124 1093 1493 1455 1131 1897 1657 2164 2181 1899 2383 900000 749 2627 973 1426 1780 2550 2635 1584 3138 2933 3760 3618 4144 4276 3965 3077 80 1707 1954 1411 1127 2320 1065 4155 3309 3269 2758 2247 1499 1944 2316 1653 2384 1371 114 -1373 -431 129 -1999 -1130 -1938 1330 -886 -2388 -1338 -2056 -2245 -2299 852 -190 747 296 -1794 -2575 -3224 -1832 -2754 -1770 -871 929 867 602 -503 -1701 -2356 -3747 -1821 -4754 -1444 -728 -491 409 1183 -921 -552 -2087 106 1007 769 -567 1774 685 2909 2356 2551 2720 2592 2077 3305 2396 1451 1386 1471 -469 -318 717 601 -439 -312 -1898 -2043 1422 -2998 -2839 SS 20220519T050422.5Z 8174.211372 209 1 48.40 2 78.46 72.78 85.82 213.52 0.00 1 0.00 1 0 17 3.726e-01 1.587e-02 1.500e-01 4.501e-03 6.694036e-01 2.431065e-03 8.356078e-03 -6.000000e+00 2.174894e-01 231.33 -2.00 3.80 -2.00 321.04 0.00e+00 1.033160e-02 1.044918e-03 1.981297e-03 -6.000000e+00 9.269375e-03 277.61 -2.00 20.00 -2.00 320.53 0.00e+00 4.836 0.002 302.00 328.00 3 3.2429e+00 7.7724e-03 6.2097e-02 -6.0000e+00 5.4584e-01 2.2442e-01 1.0068e-02 3.9306e-02 -6.0000e+00 5.9118e-01 -3.2346e-01 9.8457e-03 2.3870e-02 -6.0000e+00 3.5013e-01 1.3971e-01 4.8130e-03 1.3081e-02 -6.0000e+00 1.4694e-01 7.9066e-05 -1.1041e-03 1.2681e-04 1.5946e-04 -6.0000e+00 1.0332e-02 -9.3484e-04 -6.9406e-05 12 8 8 10 0 0 99.37 21.92 0.19 -0.00093 -0.00923 49 11 1 5 0 987.570 26.00 20.00 21.92 26.61 34.9 1010.88 -145372 -15528 -109000 -65926 -111046 -32168 -171924 -139759 -139713 -54352 -98773 -86744 -37076 -66870 -10599 -17469 -26170 -10425 -143894 -9500 7326 42262 6310 -32877 -3595 -13253 -7903 -18258 19918 -15639 19120 -10416 28502 -3518 4822 16264 10198 13093 111673 7805 1883 7648 9514 15389 7055 9520 2847 14220 12460 23534 12118 12225 12485 11444 7214 602 1703 -417 5932 -1270 7297 4965 9893 5803 5152 5940 3078 2801 6202 2448 1128 2230 2727 -774 -868 1543 -941 -419 -1644 -683 -774 -1413 -2297 -735 -515 -1070 -2141 524 700 -590 -863 -124 -1477 -2130 -2125 -1495 -707 289 -67 -867 625 -1226 34 -1382 -1505 -1570 -1900 -801 -134 324 50 125 -539 -7 -462 726 53 247 -33 887 111 1274 790 932 1079 966 632 739 961 149 324 237 -528 284 -153 -116 208 87 123 -601 149 -892 -686 -2380 -88 -1564 -613 -1462 -194 -4005 -2501 -2689 -507 -1422 -1279 -436 -1397 -162 -347 -618 -243 -12316 -249 163 653 143 -1104 -96 -403 -232 -580 434 -549 581 -487 1049 -191 229 681 499 718 2843 615 175 717 928 1468 750 1021 337 1563 1464 2651 1704 1908 2039 2049 1417 129 368 -91 1185 -271 1493 1151 2492 1723 1564 1815 931 877 2046 961 495 1009 1212 -336 -343 536 -325 -146 -630 -309 -397 -834 -1502 -501 -363 -809 -1713 421 564 -466 -634 -87 -1017 -1514 -1631 -1324 -701 319 -81 -1056 709 -1332 33 -1350 -1577 -1740 -2165 -974 -177 462 77 205 -897 -11 -706 1081 80 377 -54 1484 186 2039 1230 1435 1583 1370 874 1056 1534 262 608 466 -1103 603 -339 -272 498 212 299 -1416 335 -1926 -1458 SS 20220519T050906.6Z 8174.214660 212 1 48.40 2 77.75 73.65 86.22 214.45 0.00 1 0.00 1 0 17 3.652e-01 7.672e-03 6.241e-02 1.988e-03 6.492579e-01 1.061487e-03 7.866032e-03 -6.000000e+00 2.132341e-01 231.33 -2.00 3.80 -2.00 320.72 0.00e+00 3.485709e-03 4.265134e-04 7.081164e-04 -6.000000e+00 9.087542e-03 277.61 -2.00 20.00 -2.00 320.19 0.00e+00 4.575 0.002 302.00 328.00 3 2.2194e+00 3.2886e-03 5.9191e-02 -6.0000e+00 5.3516e-01 5.6937e-02 4.2828e-03 3.7894e-02 -6.0000e+00 5.7959e-01 -1.0229e-01 4.2872e-03 2.0052e-02 -6.0000e+00 3.4327e-01 3.7674e-02 2.1173e-03 7.4490e-03 -6.0000e+00 1.4407e-01 3.0311e-04 -7.1285e-04 5.5899e-05 8.1390e-05 -6.0000e+00 1.0127e-02 -1.4416e-03 -5.1988e-05 11 8 0 10 0 0 96.04 21.93 0.26 -0.00144 -0.00680 123 29 1 5 0 393.410 26.00 20.00 21.93 26.63 34.9 1011.17 -155715 -124556 -96384 -119382 -95711 -126844 -112481 -130677 -121223 -94232 -101302 -82326 -64789 -61243 -45459 -32891 -20192 -17860 -86122 -21099 -7976 -13115 -10371 -18821 -16209 -7718 -22659 -17553 -10857 -5541 -8598 -10403 743 -545 -7267 -6083 -4400 -2097 17328 -2828 -975 667 1390 -118 1805 1448 223 4113 1932 3646 4267 5639 4504 3395 3845 2007 901 1 -616 883 1480 3257 3424 2771 1992 2605 533 2021 2306 1594 972 1190 413 353 -430 11 -578 -1935 -803 -1029 -1109 -1311 -1889 -1675 -1096 -926 -508 153 500 235 650 389 69 -176 -55 -125 316 782 -420 -401 -147 -770 -357 363 -1358 -993 -967 -689 -55 290 100 -35 47 96 -130 571 598 497 -99 70 -345 346 406 205 705 88 341 1024 238 97 -1 -24 -354 98 -170 -145 15 344 -369 -151 210 -139 -329 -1933 -1328 -841 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