File name: Pandora67s1_Cologne_20220723_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T140927.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20220723_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20220723 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220723T044643.9Z 8239.199119 210 1 48.79 2 82.32 67.45 42.66 121.21 0.00 1 0.00 1 0 17 3.674e-01 3.025e-02 3.086e-01 1.638e-02 8.503745e-01 9.286181e-03 1.084719e-02 -6.000000e+00 2.164318e-01 233.53 -2.00 3.80 -2.00 321.71 0.00e+00 1.639842e-02 4.352439e-03 2.893625e-03 -6.000000e+00 9.530934e-03 283.55 -2.00 20.00 -2.00 321.16 0.00e+00 6.953 0.007 302.00 328.00 3 2.7054e+00 3.2313e-02 8.5666e-02 -6.0000e+00 5.4486e-01 1.2760e+00 3.9016e-02 5.0545e-02 -6.0000e+00 5.8836e-01 -1.4540e+00 2.9287e-02 2.6427e-02 -6.0000e+00 3.4923e-01 5.6988e-01 1.4652e-02 1.4844e-02 -6.0000e+00 1.4731e-01 1.1730e-05 -1.8954e-03 4.4221e-04 2.4382e-04 -6.0000e+00 1.0457e-02 3.2302e-04 1.6672e-06 12 8 8 10 0 0 96.83 21.49 0.91 0.00032 -0.01392 14 3 1 5 0 3484.090 25.68 20.00 21.49 23.51 34.5 946.29 47020 68483 -50286 -46260 7503 -37648 2405 -117329 -25002 -70592 23233 -8079 900000 40161 -24717 39726 53123 151141 -111 -58179 21642 900000 45189 -20641 -49247 14433 -8199 -13384 81315 57703 -19514 36132 -20653 -13345 188520 -9259 115847 149108 900000 -2618 60771 53837 26117 12036 13033 11665 10125 16646 16374 52451 7246 22574 23133 22366 8011 3694 -14863 52773 4152 55682 14653 6815 25314 22775 10137 42799 3348 -5325 8512 4485 16198 16106 6847 -6926 -6168 -332 10919 -14413 -12744 -4155 6204 -3513 -5355 927 -2493 -7447 -1285 12965 9069 -998 -2039 -2268 -2261 1630 -1102 -3359 -1275 1625 2320 -878 -2871 -642 -8265 -4193 -1942 1050 -9595 -924 -1543 -516 -4792 3327 -1731 14 -772 2062 1406 216 -258 883 1341 3096 763 3011 1010 2482 -256 2179 3716 934 -500 1361 -3302 288 1297 635 -981 522 -1994 761 2342 -2119 -1502 941 1234 -2899 -2309 183 -1262 51 -7492 -630 -2656 371 -178 900000 924 -1330 1362 1746 2413 -7 -6050 981 900000 1421 -1192 -3532 543 -373 -603 1416 1437 -1264 1618 -1828 -1137 3009 -657 2532 2563 900000 -257 3454 3386 2197 1179 1264 1162 1042 1658 1709 4110 967 2829 3081 3192 1337 642 -3074 5501 655 5237 2098 1140 4017 4222 2227 6884 777 -1396 2106 1309 4586 4681 2115 -2261 -1783 -81 2266 -3911 -3841 -1389 2212 -1568 -2682 460 -1355 -4437 -747 6776 4929 -578 -1107 -1156 -1125 816 -646 -2352 -1021 1486 2302 -907 -2862 -575 -7112 -3411 -1640 908 -9645 -928 -1710 -636 -6925 4819 -2706 22 -1135 2885 2000 321 -406 1426 2124 4658 1130 4191 1393 3276 -340 2950 5594 1640 -986 2845 -7622 683 3217 1651 -2645 1405 -5485 1960 5591 -4936 -3344 SS 20220723T045808.2Z 8239.207040 213 1 48.45 2 80.65 69.57 41.16 124.40 0.00 1 0.00 1 0 17 5.381e-01 1.380e-02 2.675e-01 5.937e-03 8.002805e-01 3.348030e-03 9.621669e-03 -6.000000e+00 3.168284e-01 233.53 -2.00 3.80 -2.00 321.60 0.00e+00 4.333879e-03 1.754525e-03 2.250272e-03 -6.000000e+00 1.378972e-02 283.55 -2.00 20.00 -2.00 321.06 0.00e+00 5.851 0.004 302.00 328.00 3 2.5544e+00 1.2036e-02 7.5797e-02 -6.0000e+00 7.9765e-01 3.6882e-01 1.6875e-02 4.8993e-02 -6.0000e+00 8.6142e-01 -4.8914e-01 1.6869e-02 2.6356e-02 -6.0000e+00 5.1121e-01 1.9159e-01 7.8377e-03 9.0168e-03 -6.0000e+00 2.1540e-01 5.2824e-05 -7.6391e-04 1.6395e-04 1.2719e-04 -6.0000e+00 1.5278e-02 7.0146e-04 -6.2770e-05 12 8 8 10 0 0 66.50 21.50 0.39 0.00070 -0.00504 45 11 1 5 0 1076.530 25.68 20.01 21.50 23.81 34.5 947.99 -72307 -195987 -189405 -207703 -65663 -208648 -59723 -216971 -159264 -58232 -89780 -111626 -142903 -127210 -130117 -14132 -67737 125066 -68800 -98182 -52122 900000 -81634 -42593 -75387 -32683 31146 -9906 -4157 35128 -16944 -27155 -17503 -51246 17383 -26757 -3539 2531 900000 -18808 21142 -3275 11710 5612 13691 1641 -4994 12266 15886 9988 10246 14939 8017 16121 12467 12003 1465 10532 -7382 6253 8596 10103 15857 12905 6382 6898 8995 3632 9152 4449 5338 3341 4645 2141 2997 -5072 3555 -6386 -224 761 1338 -1083 -2051 -2071 -1304 -1095 -1328 -151 1753 1617 354 -573 -1823 -1125 -1697 -1446 -1400 -119 -111 -677 -1439 -410 -1303 -432 -1949 -1820 -3097 12 -367 -322 85 165 -71 413 43 79 648 464 423 -188 -26 339 480 629 1494 451 856 1613 662 461 -265 560 -832 67 -340 583 -55 675 -982 -171 626 -501 -895 -418 -2647 -2558 -3205 -380 -2918 -346 -3872 -1767 -337 -563 -1023 -2343 -2331 -3138 -141 -1209 724 -1493 -2983 -1005 900000 -2205 -842 -2181 -705 361 -167 -66 425 -428 -838 -574 -2521 448 -981 -125 90 900000 -1215 1030 -218 706 368 839 116 -390 846 1126 819 949 1484 940 1913 1635 1644 229 1488 -1203 872 1211 1549 2638 2527 1416 1510 1961 879 2322 1260 1656 1101 1485 657 893 -1468 892 -1829 -69 258 534 -512 -1083 -1164 -779 -696 -883 -102 1162 1034 214 -329 -1039 -668 -1152 -1150 -1215 -119 -121 -747 -1511 -387 -1118 -363 -1778 -1750 -3199 13 -444 -442 123 255 -113 638 64 113 929 698 672 -311 -42 526 718 903 2183 646 1194 2342 1032 821 -529 1132 -1816 153 -843 1425 -139 1713 -2528 -442 1502 -1141 -1964 SS 20220723T050812.4Z 8239.214033 219 1 48.42 2 79.16 71.43 39.87 127.35 0.00 1 0.00 1 0 17 4.920e-01 8.821e-03 1.385e-01 3.004e-03 7.159096e-01 1.647558e-03 8.698907e-03 -6.000000e+00 2.895123e-01 233.52 -2.00 3.80 -2.00 321.19 0.00e+00 4.635472e-03 7.862498e-04 1.802987e-03 -6.000000e+00 1.254447e-02 283.55 -2.00 20.00 -2.00 320.62 0.00e+00 5.117 0.003 302.00 328.00 3 2.2702e+00 5.5592e-03 6.6589e-02 -6.0000e+00 7.2913e-01 1.0342e-01 7.6638e-03 4.3188e-02 -6.0000e+00 7.8759e-01 -1.5267e-01 7.7973e-03 2.3644e-02 -6.0000e+00 4.6723e-01 5.4009e-02 3.7022e-03 8.6695e-03 -6.0000e+00 1.9622e-01 1.5934e-04 -7.4684e-04 8.3971e-05 1.0929e-04 -6.0000e+00 1.3653e-02 5.6274e-04 -5.7312e-05 11 8 0 10 0 0 73.54 21.52 0.29 0.00056 -0.00505 94 22 1 5 0 515.030 25.68 20.01 21.52 24.13 34.6 949.27 -159718 -178885 -181564 -178580 -152660 -118698 -109962 -188044 -184617 -125334 -65603 -150861 -56485 -104579 -41747 -57367 -30674 -27413 -47049 -82557 11135 -2421 -19869 -39837 -46918 -38612 -44579 -33024 -31744 -5973 -28501 -5373 -9442 -9434 -14557 -15157 -18125 -1344 54280 863 -4350 4960 -3882 -3300 4204 -6310 474 -1883 2019 5645 7324 2747 6995 3929 5008 4487 2889 3901 1230 2045 4712 3835 4625 5096 3288 3554 2175 1183 2492 2399 2255 1914 -405 350 184 -282 369 -1409 -57 -1081 -309 -1043 -1850 -1609 -1205 -439 -686 -12 1156 708 309 67 -185 -511 -75 -205 243 645 -283 -416 -628 -934 -704 -232 -1719 -1471 -1682 -610 -459 632 -103 189 194 297 238 208 724 332 163 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