File name: Pandora67s1_Cologne_20220820_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T142448.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20220820_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20220820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220820T072726.6Z 8267.310725 294 1 3.47 2 62.90 104.32 31.56 216.80 0.00 1 0.00 1 0 17 2.145e-02 8.515e-03 2.394e-02 7.544e-03 3.036782e-01 3.898085e-03 3.893396e-03 -6.000000e+00 1.255468e-02 231.90 -2.00 3.80 -2.00 317.20 0.00e+00 5.724426e-04 5.430418e-04 1.415468e-04 -6.000000e+00 5.464091e-04 283.27 -2.00 20.00 -2.00 316.46 0.00e+00 2.183 0.000 302.00 328.00 3 4.5068e+00 1.0342e-02 2.7824e-02 -6.0000e+00 3.1493e-02 5.4914e-02 1.1583e-02 1.7141e-02 -6.0000e+00 3.4056e-02 -1.1015e-02 6.9391e-03 8.3192e-03 -6.0000e+00 2.0228e-02 -1.3074e-03 3.3918e-03 2.3013e-03 -6.0000e+00 8.5271e-03 4.4832e-04 -3.1929e-04 2.1886e-04 2.6132e-05 -6.0000e+00 5.9484e-04 -3.7260e-03 -6.4895e-05 12 9 1 12 1 1 999.00 21.87 0.07 -0.00373 -0.00613 1 7 1 5 0 1643.950 26.00 20.00 21.87 26.39 34.7 967.05 1641 555 -4483 -1595 -1704 -5940 -6242 -2563 128 -181 -7610 1646 -9148 -2657 -1789 4133 4293 9710 -499 -3973 -1349 4524 -5218 -2598 -2119 -4540 199 -572 2791 2222 2990 -109 3072 -1335 711 -2933 665 -1579 2994 1527 -761 -902 -257 -1607 -204 216 -387 1366 -2574 -203 -794 17 327 1136 465 2570 1459 2535 253 476 798 22 1715 1017 194 5 -604 -223 2344 959 453 -762 -24 -592 -135 -1091 5 -663 -268 462 -1940 -1370 -2322 -26 -242 -690 -430 1136 -437 -104 1107 1265 -871 -635 -282 -715 -442 109 604 -313 -559 -542 -1137 443 -917 -266 -566 63 -294 -295 774 537 52 -451 -160 450 866 153 447 265 -428 97 -115 801 729 1416 371 1009 159 216 -362 -310 -272 995 -625 -83 183 686 -582 -447 192 -494 -846 164 62 -538 -174 -168 -598 -675 -296 16 -24 -1068 220 -1532 -475 -359 869 936 2130 -123 -1055 -354 1129 -1445 -745 -631 -1422 61 -165 745 601 853 -34 1004 -465 233 -975 232 -635 1345 780 -426 -522 -151 -969 -121 128 -229 788 -1510 -119 -487 11 218 789 333 1839 1065 1843 184 344 587 17 1402 871 168 4 -478 -174 1872 842 427 -739 -23 -561 -121 -929 4 -508 -212 396 -1828 -1372 -2450 -28 -271 -811 -520 1389 -542 -126 1264 1370 -915 -650 -297 -807 -533 140 800 -416 -719 -663 -1340 524 -1150 -345 -752 86 -415 -434 1171 825 78 -661 -222 601 1151 209 630 390 -639 143 -168 1138 1002 1890 485 1312 217 306 -533 -468 -415 1541 -1006 -139 307 1168 -1006 -761 316 -805 -1365 SS 20220820T073102.8Z 8267.313226 297 1 2.13 2 62.35 105.10 31.89 218.20 0.00 1 0.00 1 0 17 1.049e-02 5.709e-03 4.652e-03 1.688e-03 2.918157e-01 8.737022e-04 3.785025e-03 -6.000000e+00 6.138525e-03 231.90 -2.00 3.80 -2.00 316.96 0.00e+00 3.305563e-04 1.137776e-04 7.430079e-05 -6.000000e+00 2.671780e-04 283.26 -2.00 20.00 -2.00 316.22 0.00e+00 2.144 0.000 302.00 328.00 3 1.8031e+00 2.3088e-03 2.7131e-02 -6.0000e+00 1.5398e-02 1.7158e-02 2.5789e-03 1.6554e-02 -6.0000e+00 1.6652e-02 -2.7449e-03 1.5225e-03 8.0394e-03 -6.0000e+00 9.8907e-03 -3.0810e-03 7.3232e-04 2.2142e-03 -6.0000e+00 4.1689e-03 7.2208e-03 -4.2609e-04 4.8789e-05 2.6120e-05 -6.0000e+00 2.9088e-04 -2.6313e-03 -5.0901e-05 12 1 1 12 1 1 36.17 21.88 0.25 -0.00263 -0.00583 20 121 1 5 0 93.570 26.00 20.01 21.88 26.52 34.8 967.72 -1479 -891 -2780 -6084 -3237 -631 -2257 -1436 -32 805 -3059 78 -1506 -37 528 -490 -795 885 794 706 625 951 1873 75 81 259 -194 -1687 361 214 1568 773 2085 -1885 -1573 -1402 -2251 -329 -307 -500 -803 -678 -98 -274 106 -259 -582 -610 -1170 546 906 763 1365 1084 437 708 639 255 579 509 1102 1447 1684 1156 53 67 28 29 673 667 -126 -152 -137 -31 -130 -290 6 -380 212 -744 -1157 -1267 -2170 -1187 -875 -814 -625 -87 117 216 437 457 192 918 453 108 518 920 -142 -456 -410 -527 -206 166 -886 -758 -546 -662 -133 479 200 115 215 101 184 361 410 387 -167 38 -388 154 18 167 640 357 310 1181 320 302 101 94 -38 156 -184 54 -146 243 -199 -243 -94 -463 -535 -185 -121 -396 -837 -386 -72 -279 -196 -5 126 -497 13 -262 -7 119 -123 -211 242 209 193 174 262 530 23 26 86 -65 -540 105 63 488 261 757 -736 -574 -505 -903 -139 -155 -278 -461 -406 -60 -171 66 -161 -358 -367 -699 324 570 515 913 771 325 535 493 197 437 382 849 1127 1423 996 46 57 23 23 556 589 -117 -148 -134 -29 -119 -253 5 -305 167 -665 -1107 -1279 -2260 -1284 -966 -964 -742 -106 143 255 498 501 204 936 489 123 625 1179 -187 -595 -527 -631 -240 196 -1100 -994 -716 -916 -186 706 301 177 321 147 257 471 530 520 -231 56 -566 230 26 234 880 471 407 1535 429 432 147 143 -57 240 -290 90 -240 409 -339 -404 -156 -745 -839 SS 20220820T073518.6Z 8267.316188 300 1 48.06 2 61.71 106.02 32.30 219.83 0.00 1 0.00 1 0 17 8.994e-03 5.439e-03 8.833e-04 3.041e-04 2.853751e-01 1.571150e-04 3.678394e-03 -6.000000e+00 5.267588e-03 231.90 -2.00 3.80 -2.00 317.10 0.00e+00 3.890904e-04 2.124955e-05 7.544138e-05 -6.000000e+00 2.292031e-04 283.26 -2.00 20.00 -2.00 316.36 0.00e+00 2.099 0.000 302.00 328.00 3 1.6089e+00 4.1587e-04 2.6531e-02 -6.0000e+00 1.3214e-02 1.1345e-02 4.6522e-04 1.6156e-02 -6.0000e+00 1.4287e-02 -1.4797e-03 2.7592e-04 7.8317e-03 -6.0000e+00 8.4858e-03 -2.9236e-03 1.3345e-04 2.1627e-03 -6.0000e+00 3.5785e-03 9.2665e-03 1.3135e-04 8.8646e-06 2.5405e-05 -6.0000e+00 2.4941e-04 -3.9511e-03 4.3281e-05 10 0 0 10 0 0 99.99 21.89 0.22 -0.00395 -0.00296 967 227 1 5 0 49.580 26.00 20.00 21.89 26.65 34.8 968.59 -1004 -1669 -1385 -4421 -3223 -2587 -1357 -442 110 -1690 -1792 -940 -752 -92 425 -328 -312 446 492 1015 114 731 1138 408 110 323 -497 -760 -461 1160 829 1402 1277 -1377 -1879 -1042 -1616 -587 -5 -629 -1027 -687 -631 -689 -127 -474 -478 -442 -634 358 871 598 1064 978 703 1075 651 487 499 559 1107 1239 1503 1142 -277 38 -119 -200 945 515 65 132 -59 100 -243 -206 -193 -370 123 -666 -866 -1202 -2064 -1253 -864 -771 -440 48 147 103 430 520 309 792 700 208 573 622 -299 -368 -208 -721 -202 338 -929 -842 -622 -600 -209 304 193 92 60 159 98 499 465 468 164 -73 -486 129 105 275 586 371 386 1187 314 168 73 -101 -195 301 -194 -111 -84 377 -349 -177 -113 -431 -335 -117 -215 -183 -562 -360 -281 -156 -56 15 -254 -268 -145 -131 -17 89 -76 -76 113 130 277 32 202 324 124 35 99 -154 -240 -135 335 258 467 427 -489 -628 -369 -587 -244 -2 -342 -573 -399 -379 -419 -77 -287 -285 -257 -365 206 529 391 732 669 500 776 481 360 361 403 819 982 1216 991 -243 31 -97 -159 786 457 60 128 -57 93 -224 -171 -155 -283 97 -564 -827 -1206 -2124 -1341 -988 -898 -537 60 186 125 483 563 327 804 747 233 678 781 -402 -489 -261 -886 -231 392 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