File name: Pandora67s1_Cologne_20220829_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T143404.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20220829_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20220829 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220829T053803.1Z 8276.234758 70 1 48.72 2 81.98 85.02 100.28 71.11 0.00 1 0.00 1 0 25 6.232e-01 1.632e-02 2.508e-01 5.301e-03 7.579956e-01 2.960130e-03 9.277284e-03 -6.000000e+00 3.647371e-01 230.84 -2.00 3.80 -2.00 321.65 0.00e+00 8.155537e-03 1.555390e-03 1.915243e-03 -6.000000e+00 1.583359e-02 282.42 -2.00 20.00 -2.00 321.14 0.00e+00 6.701 0.006 302.00 328.00 3 1.5364e+00 1.0693e-02 8.0379e-02 -6.0000e+00 9.1324e-01 3.9640e-01 1.4887e-02 4.5989e-02 -6.0000e+00 9.8887e-01 -5.5290e-01 1.4553e-02 2.5690e-02 -6.0000e+00 5.8768e-01 2.3031e-01 6.7515e-03 1.0880e-02 -6.0000e+00 2.4773e-01 7.1327e-05 -1.3463e-03 1.5015e-04 1.4965e-04 -6.0000e+00 1.7278e-02 -8.5836e-03 -1.2533e-05 12 8 8 10 0 0 95.03 21.39 0.26 -0.00858 -0.01870 86 20 1 5 0 566.420 25.58 20.00 21.39 22.61 34.3 962.99 -97522 -198141 -179364 -187020 -206774 -50947 -211385 -154621 -211424 110176 -157538 -6652 -159172 -10632 -102990 900000 -52253 127207 -47421 -4306 -8075 19284 -25340 -41340 -18964 -71343 -35059 -90791 82313 -18099 23837 -26145 7644 -19171 31032 -33411 33415 11307 346699 8406 11458 8217 10330 13167 6759 9324 1665 17424 3608 32030 12778 25137 10238 24544 15407 19344 3318 11606 6328 4861 7326 9674 12643 10260 10333 6362 11786 2248 12627 5488 9166 1929 7083 228 6574 -4107 4043 -3358 506 1224 -235 -1267 -1984 -1279 -2801 -789 -1595 649 -447 1775 -452 1030 -2044 1264 -2063 -1364 -1528 -825 -1338 -904 -439 -1216 -1601 -1385 -2869 -2947 -2604 -1970 795 -951 299 -301 834 276 -34 -218 540 170 259 -197 -118 1023 999 1326 593 1813 1001 1923 61 877 16 765 -169 220 -368 268 -331 389 -272 -480 151 -921 -572 -651 -4056 -3263 -3519 -4232 -263 -4502 -2065 -5158 569 -2545 -34 -3752 -81 -2440 900000 -1035 658 -1072 -66 -129 238 -480 -970 -368 -2412 -838 -3676 610 -394 439 -918 224 -793 774 -1490 871 407 1792 445 661 503 654 836 465 644 128 1196 301 2263 1178 2297 1190 2700 1972 2456 486 1615 898 687 1045 1486 2079 1979 2130 1353 2390 523 2899 1556 2784 635 2191 71 1818 -1133 962 -879 144 416 -93 -583 -1023 -672 -1599 -472 -1008 413 -291 1094 -266 582 -1158 717 -1314 -1013 -1290 -808 -1459 -992 -456 -1163 -1385 -1211 -2627 -2863 -2670 -2179 912 -1255 426 -467 1305 427 -50 -312 797 254 411 -327 -195 1606 1516 1999 863 2528 1373 2707 96 1557 32 1598 -368 506 -887 679 -865 1030 -708 -1234 361 -2164 -1279 SS 20220829T055626.2Z 8276.247525 76 1 40.50 2 79.10 88.57 97.66 74.74 0.00 1 0.00 1 0 17 3.070e-01 1.033e-02 1.901e-01 5.424e-03 6.017734e-01 2.900088e-03 7.494411e-03 -6.000000e+00 1.791698e-01 230.84 -2.00 3.80 -2.00 320.69 0.00e+00 3.780904e-03 1.170148e-03 1.811744e-03 -6.000000e+00 7.797573e-03 282.41 -2.00 20.00 -2.00 320.09 0.00e+00 5.091 0.003 302.00 328.00 3 3.3376e+00 9.0803e-03 6.1596e-02 -6.0000e+00 4.4840e-01 1.4174e-01 1.1632e-02 3.5681e-02 -6.0000e+00 4.8524e-01 -1.2678e-01 1.0994e-02 1.9071e-02 -6.0000e+00 2.8833e-01 4.7573e-02 5.4436e-03 6.5615e-03 -6.0000e+00 1.2180e-01 6.2513e-05 -7.3737e-04 1.5576e-04 8.4793e-05 -6.0000e+00 8.5127e-03 -8.4880e-03 -7.2751e-05 12 9 9 12 1 1 99.65 21.42 0.21 -0.00849 -0.01403 19 6 1 5 0 2015.690 25.58 20.00 21.42 23.40 34.6 967.19 -119273 -33579 -100642 -111761 -91092 -2627 -123684 -28862 -121019 -33941 -136962 -30546 36707 -35557 -55638 -10389 -64380 10739 -36077 -43796 -22910 33055 24784 -32275 18626 4704 10894 -26545 -1570 47700 -6126 -6288 8562 -6356 5050 -23311 3401 21448 91812 -1409 -332 3945 -7008 5461 -2802 6769 -4969 961 -2375 12893 -620 7455 4522 2418 2675 2965 -298 4420 -2240 -84 3033 4583 7327 1469 2033 2248 1920 -481 1175 -5 704 391 2115 -1309 994 -513 1029 -1550 -628 -450 153 -88 -2672 -428 -1999 -1203 -549 203 -254 1529 83 1126 -1265 -364 308 -771 -503 1138 -165 -250 -1147 -525 -1233 -283 -1092 -456 -1521 -1895 793 464 602 654 229 -199 -348 1142 341 149 80 -165 -34 803 997 295 -202 704 -315 933 170 -62 -9 -213 -737 65 118 98 64 98 -138 -267 783 -663 -390 -1586 -227 -1396 -1677 -1016 -14 -2051 -212 -2375 -319 -3565 -328 261 -625 -1456 -212 -2473 221 -1250 -1731 -753 656 546 -1325 501 153 343 -1145 -53 1100 -272 -327 443 -410 279 -1660 212 1305 3452 -153 -39 478 -1001 709 -401 902 -760 142 -379 1879 -115 1416 940 559 655 750 -80 1132 -598 -22 787 1284 2255 525 756 811 687 -181 472 -2 353 206 1091 -663 462 -218 400 -618 -274 -225 88 -57 -1905 -316 -1608 -1006 -478 181 -229 1311 69 859 -945 -273 253 -718 -527 1319 -207 -314 -1374 -585 -1289 -291 -1190 -523 -1858 -2443 1058 673 945 1065 376 -323 -534 1675 503 229 128 -272 -56 1303 1568 459 -301 1021 -447 1337 267 -105 -17 -407 -1484 134 255 221 148 227 -322 -611 1704 -1417 -801 SS 20220829T060130.3Z 8276.251045 79 1 48.42 2 78.30 89.55 96.93 75.73 0.00 1 0.00 1 0 25 2.376e-01 6.270e-03 6.132e-02 2.004e-03 5.782640e-01 1.067701e-03 7.141404e-03 -6.000000e+00 1.386852e-01 230.84 -2.00 3.80 -2.00 320.50 0.00e+00 2.482263e-03 4.085936e-04 4.637559e-04 -6.000000e+00 6.034573e-03 282.41 -2.00 20.00 -2.00 319.89 0.00e+00 4.771 0.002 302.00 328.00 3 2.1417e+00 3.2695e-03 5.7968e-02 -6.0000e+00 3.4708e-01 3.5725e-02 4.1380e-03 3.3624e-02 -6.0000e+00 3.7557e-01 -4.0101e-02 3.8773e-03 1.7135e-02 -6.0000e+00 2.2316e-01 9.1308e-03 1.9397e-03 5.7725e-03 -6.0000e+00 9.4295e-02 2.9877e-04 -7.5478e-04 5.7670e-05 6.4625e-05 -6.0000e+00 6.5869e-03 -9.1126e-03 -3.4969e-05 10 0 0 10 0 0 94.18 21.43 0.25 -0.00911 -0.01478 118 28 1 5 0 410.250 25.58 20.00 21.43 23.56 34.4 967.26 -53092 -45671 -95824 -98302 -92539 -69713 -85262 -85817 -101127 -44564 -36222 -59715 -59227 -26007 -36975 -5868 -12135 -7328 -3436 -18074 -7791 -9490 -5734 -8694 -10561 -14701 -17987 -10079 -11809 -1754 -5951 -7896 -513 -8417 -7643 -7834 -7966 276 11719 1296 -1190 74 -1999 343 -189 602 -837 1419 1520 4277 2231 1994 2096 1714 1406 1868 631 1065 -163 -62 1564 2891 3380 2709 1231 1248 401 -143 1319 1093 685 582 418 259 -117 -379 -167 -1134 152 -1156 -724 -1079 -2133 -1391 -1058 -798 -494 142 615 217 656 784 50 553 272 38 454 623 -221 -89 -169 -838 -457 122 -1119 -1318 -929 -683 -222 291 194 284 176 203 64 754 167 398 -102 -141 -596 459 172 184 286 230 164 1198 338 107 92 -19 -397 128 -319 -131 1 410 -311 -164 153 -335 -51 -363 -339 -1273 -1306 -1067 -640 -1000 -1140 -1778 -488 -382 -898 -1111 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