File name: Pandora67s1_Cologne_20230820_L2Fit_fout2c2d20191024p1-8.txt File generation date: 20230821T054158.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20191024.txt Level 1 file used: Pandora67s1_Cologne_20230820_L1_smca1c2d20191024p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20230820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230820T053432.9Z 8632.232325 81 1 49.43 2 80.48 81.83 116.36 58.32 0.00 1 0.00 1 0 25 4.177e-01 1.453e-02 2.055e-01 6.671e-03 6.344198e-01 3.650772e-03 7.761585e-03 -6.000000e+00 2.443448e-01 231.91 -2.00 3.80 -2.00 321.08 0.00e+00 5.792004e-03 1.640657e-03 6.332670e-04 -6.000000e+00 1.086303e-02 283.27 -2.00 20.00 -2.00 320.48 0.00e+00 5.758 0.004 302.00 328.00 3 3.1495e+00 1.2076e-02 6.8213e-02 -6.0000e+00 6.1286e-01 2.4038e-01 1.5883e-02 3.7882e-02 -6.0000e+00 6.6292e-01 -2.4280e-01 1.5099e-02 1.9887e-02 -6.0000e+00 3.9412e-01 8.4095e-02 7.2942e-03 8.6366e-03 -6.0000e+00 1.6726e-01 3.8630e-05 -1.2236e-03 1.9552e-04 9.6182e-05 -6.0000e+00 1.1888e-02 3.4537e-03 -2.3862e-05 12 8 8 10 0 0 73.45 21.97 0.28 0.00345 -0.00574 22 5 1 5 0 2246.600 26.11 20.00 21.97 28.72 36.9 1012.28 -159371 900000 -146962 -142805 -74072 -119834 -144116 -177468 -94189 -107281 18625 -139352 900000 -90723 2623 -47644 65425 -21457 -48104 -73217 33924 33389 56853 -36149 -23358 20270 -20470 -11815 29968 99691 -15843 -9947 -15371 30367 62324 -7228 -28862 43810 900000 21744 -2907 3680 -5574 6057 -9695 2892 1979 6035 432 21087 8173 7074 12886 5785 9177 -2384 1005 4131 4017 -1820 9867 760 13017 5292 2136 5148 3523 1060 51 502 2481 4203 955 2512 405 988 494 -2724 -2320 2275 -1124 502 -7292 1097 -3173 -2314 -1800 2474 838 204 -820 -141 874 -639 -135 -659 -342 413 737 -1656 8 -1546 81 -1007 -1492 -1591 -141 -2647 663 661 290 385 -44 287 -169 919 2 1 -1100 417 -245 570 280 873 915 545 -157 1483 664 1057 328 279 -1899 347 150 365 277 -351 30 -96 1224 -683 -1534 -2648 900000 -2690 -2407 -593 -1498 -2451 -4445 -1178 -1637 121 -3356 900000 -2292 33 -1180 613 -510 -1552 -3191 556 547 769 -1275 -759 446 -691 -355 608 1115 -650 -453 -822 1139 1686 -376 -1995 1775 900000 1529 -293 370 -626 648 -1191 334 236 714 56 2397 1135 1104 2068 1084 1758 -529 221 876 830 -395 1984 184 3171 1566 659 1554 1074 330 17 197 1055 1834 426 1044 157 355 167 -959 -877 971 -579 281 -4847 711 -2302 -1723 -1397 1896 657 160 -606 -97 571 -434 -101 -555 -333 445 861 -1980 9 -1597 77 -972 -1555 -1701 -157 -3255 835 925 438 615 -71 447 -258 1327 3 1 -1754 684 -404 904 432 1330 1329 768 -216 2078 1047 1803 601 549 -3916 738 334 854 666 -844 71 -228 2718 -1511 -3301 SS 20230820T054239.5Z 8632.237957 86 1 49.00 2 79.22 83.38 115.32 60.16 0.00 1 0.00 1 0 17 3.777e-01 1.164e-02 1.704e-01 4.813e-03 5.834960e-01 2.579868e-03 7.250218e-03 -6.000000e+00 2.208626e-01 231.91 -2.00 3.80 -2.00 320.75 0.00e+00 3.433735e-03 1.052014e-03 1.456229e-03 -6.000000e+00 9.617452e-03 283.27 -2.00 20.00 -2.00 320.13 0.00e+00 5.143 0.003 302.00 328.00 3 3.2425e+00 8.1627e-03 6.1454e-02 -6.0000e+00 5.5404e-01 1.2817e-01 1.0433e-02 3.4563e-02 -6.0000e+00 5.9931e-01 -1.2525e-01 9.6990e-03 1.8060e-02 -6.0000e+00 3.5597e-01 4.1271e-02 4.7874e-03 6.0097e-03 -6.0000e+00 1.4990e-01 6.8075e-05 -8.4623e-04 1.4103e-04 7.6923e-05 -6.0000e+00 1.0478e-02 3.5819e-03 -4.2668e-05 12 8 8 10 0 0 98.28 21.98 0.22 0.00358 -0.00278 36 8 1 5 0 1360.880 26.11 20.00 21.98 29.40 37.1 1015.94 -109061 -73452 -60873 -75387 -125752 -93570 -96257 -125831 -64538 -94159 76593 -125992 245177 -71343 1028 -57298 26112 -39321 -14419 -45794 27064 -16900 6317 -17768 10004 30153 -16141 11051 -14026 38524 -9286 9591 -19785 7786 -14541 6087 -19173 18708 56196 6804 -6154 -1753 -2467 4814 -3577 119 -18 2023 604 9953 6421 4258 5670 527 6189 -2569 197 -1271 4278 -3353 4853 -1807 7476 1717 3605 1328 3118 323 610 1574 2430 2645 1329 1632 -443 2713 -2174 -1234 -3366 1300 -605 1601 -5884 -632 -3184 -649 276 1662 -92 1281 -257 897 89 -1098 10 -564 855 237 804 -1821 -457 -1514 -360 -1259 -1482 -1995 -617 -1073 505 143 523 -3 344 214 -175 1493 341 195 -659 657 -210 457 -115 849 545 599 -167 1173 334 -6 905 -273 -802 116 -94 91 107 -51 -223 -413 936 -736 -392 -1427 -777 -621 -836 -2110 -1140 -1307 -2510 -816 -1692 359 -3609 1151 -1876 17 -1927 445 -1361 -420 -1886 585 -545 174 -660 305 792 -674 347 -542 1002 -441 439 -1366 443 -968 338 -1502 1204 3028 690 -780 -227 -339 632 -518 17 -3 296 93 1489 1105 830 1186 124 1454 -682 52 -341 1060 -890 1235 -540 2297 612 1307 477 1087 119 244 703 1190 1326 670 792 -201 1095 -859 -485 -1497 636 -344 1013 -4235 -458 -2539 -540 234 1435 -82 1077 -207 680 65 -826 8 -516 873 274 985 -2276 -532 -1662 -364 -1290 -1613 -2306 -743 -1370 677 210 814 -5 562 337 -266 2160 500 294 -1052 1083 -350 746 -184 1312 805 868 -236 1686 521 -10 1648 -530 -1614 239 -206 206 246 -120 -528 -954 2053 -1588 -816 SS 20230820T054807.4Z 8632.241753 89 1 48.48 2 78.36 84.42 114.62 61.39 0.00 1 0.00 1 0 17 1.596e-01 6.548e-03 1.033e-01 2.867e-03 5.479241e-01 1.520902e-03 6.746782e-03 -6.000000e+00 9.333982e-02 231.91 -2.00 3.80 -2.00 320.45 0.00e+00 2.698589e-03 5.727327e-04 5.780147e-04 -6.000000e+00 4.064330e-03 283.27 -2.00 20.00 -2.00 319.81 0.00e+00 4.795 0.002 302.00 328.00 3 2.8284e+00 4.6668e-03 5.7213e-02 -6.0000e+00 2.3414e-01 2.0849e-02 5.8760e-03 3.1935e-02 -6.0000e+00 2.5327e-01 -2.4455e-02 5.4365e-03 1.6325e-02 -6.0000e+00 1.5043e-01 2.7626e-03 2.7259e-03 5.5669e-03 -6.0000e+00 6.3351e-02 1.5340e-04 -7.7133e-04 8.3786e-05 6.1329e-05 -6.0000e+00 4.4277e-03 3.2116e-03 -4.1105e-05 11 8 0 10 0 0 98.25 22.00 0.21 0.00321 -0.00258 55 13 1 5 0 881.180 26.11 20.00 22.00 29.80 37.0 1017.98 -52926 9763 -56621 -27969 -57771 -42209 -51147 -44548 -85726 4877 -74322 -16062 28501 -10737 -36606 7101 -23623 -3362 -20966 -18987 -5403 1717 -2708 -13144 -766 -1185 -7591 -6033 2386 6574 464 -1376 -3193 -50 -2746 -6024 -5788 -3813 21943 -5174 -3442 -6922 -2116 -859 -4047 -2411 -1975 265 -1920 3602 4159 3031 3041 2719 2750 376 -1111 1320 -524 1163 569 1679 2503 2060 152 1409 139 276 1178 569 2339 1292 606 692 760 -209 -658 -1724 -149 -1333 -137 -1206 -3239 -1384 -1099 -443 -505 267 609 481 520 698 705 636 738 -443 361 1033 100 -514 -303 -995 -534 -47 -1736 -1029 -525 -564 194 195 7 83 217 150 191 477 638 261 15 -127 -507 294 47 305 484 94 -1 863 368 253 121 -135 -696 146 -249 53 -135 412 -394 -43 315 -282 -115 -432 51 -597 -214 -547 -345 -500 -460 -1512 39 -1327 -181 268 -180 -948 146 -709 -91 -732 -688 -176 52 -92 -538 -29 -49 -340 -257 91 262 23 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