File name: Pandora67s1_Cologne_20230822_L2Fit_fout2c2d20191024p1-8.txt File generation date: 20230823T021051.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20191024.txt Level 1 file used: Pandora67s1_Cologne_20230822_L1_smca1c2d20191024p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20230822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230822T052003.0Z 8634.222257 65 1 48.35 2 83.17 79.58 137.06 39.29 0.00 1 0.00 1 0 17 4.389e-01 4.024e-02 3.103e-01 2.082e-02 7.455912e-01 1.157963e-02 9.643743e-03 -6.000000e+00 2.574558e-01 231.67 -2.00 3.80 -2.00 321.52 0.00e+00 2.048782e-02 5.037836e-03 1.785461e-03 -6.000000e+00 1.121543e-02 283.08 -2.00 20.00 -2.00 320.92 0.00e+00 7.676 0.010 302.00 328.00 3 2.4132e+00 3.9142e-02 8.8108e-02 -6.0000e+00 6.4591e-01 1.2423e+00 4.6816e-02 4.7608e-02 -6.0000e+00 6.9894e-01 -1.2849e+00 3.2714e-02 2.3239e-02 -6.0000e+00 4.1545e-01 4.7991e-01 1.6400e-02 1.7341e-02 -6.0000e+00 1.7524e-01 8.9749e-06 -2.5732e-03 5.8877e-04 2.5474e-04 -6.0000e+00 1.2565e-02 3.2700e-03 7.4275e-05 12 9 8 11 32 0 -22.61 21.90 0.91 0.00327 -0.01607 13 3 1 5 0 3718.560 26.00 20.00 21.90 27.98 36.7 1007.29 47193 5464 -39184 160689 -22925 -57402 -91145 -78031 -60084 7444 -21724 -69605 127370 8315 -78292 900000 -2713 188229 -23402 5442 58793 97604 -15559 2164 -55550 62700 -2562 13513 900000 214057 71824 -10674 40763 3076 140195 69305 35480 72161 900000 -3439 78346 4854 13813 3410 23337 56361 22911 12961 1849 75308 35074 62558 15437 43979 -2057 6637 -12913 77061 -3421 31095 19261 25114 29294 15750 13936 17942 -1088 21926 -161 7980 3541 24224 3601 4837 -10481 1721 22235 -18347 -154 -457 6840 -3086 -16595 -2606 -3476 -4312 -332 66 7951 392 -10303 -559 -3204 4890 1309 4090 -1165 4160 -693 2249 -5734 921 -11626 -580 -8625 4148 -763 -3965 1393 -1789 -3936 627 810 -2639 -3582 3486 4297 -2504 -359 2823 -931 355 5162 1129 5304 4165 3539 126 2292 -1331 1797 1579 -4509 -1599 1339 1917 131 292 -664 1171 3661 -1140 -6098 1204 233 -2617 3261 -1003 -3035 -6148 -4343 -2665 164 -601 -3398 2585 318 -8771 900000 -192 3820 -2205 386 2351 2454 -1119 123 -5179 1793 -134 573 900000 4344 2363 -921 2420 277 3020 2791 2084 3244 900000 -405 4432 582 1569 440 2495 4488 2599 1645 272 5736 4281 6309 2609 5990 -440 1307 -2998 7338 -672 4302 3103 4193 5332 3659 3478 4201 -300 4981 -48 2481 1256 7293 1279 1597 -3569 467 4635 -5746 -45 -162 2613 -1490 -9917 -1424 -2029 -2692 -207 42 4707 242 -6569 -305 -1733 2510 782 2749 -958 3791 -723 2300 -6015 834 -10701 -472 -7986 3627 -731 -4255 1541 -2305 -5755 944 1240 -4093 -5366 4746 5845 -3765 -561 4455 -1517 549 7459 1636 7054 5512 4597 173 3487 -2359 3390 3204 -10189 -3715 3237 4869 342 775 -1786 3001 8692 -2673 -14346 SS 20230822T054652.1Z 8634.240881 73 1 48.43 2 78.99 84.71 134.36 47.40 0.00 1 0.00 1 0 25 2.595e-01 7.389e-03 9.416e-02 2.315e-03 5.683746e-01 1.238598e-03 7.020063e-03 -6.000000e+00 1.516360e-01 231.67 -2.00 3.80 -2.00 320.69 0.00e+00 4.213452e-03 4.990429e-04 3.929224e-04 -6.000000e+00 6.603615e-03 283.08 -2.00 20.00 -2.00 320.07 0.00e+00 5.046 0.003 302.00 328.00 3 2.1164e+00 3.9008e-03 6.0067e-02 -6.0000e+00 3.8018e-01 2.3150e-02 5.0015e-03 3.3632e-02 -6.0000e+00 4.1135e-01 -5.5917e-02 4.7153e-03 1.7245e-02 -6.0000e+00 2.4434e-01 1.4426e-02 2.3320e-03 6.9493e-03 -6.0000e+00 1.0292e-01 2.4491e-04 -1.0259e-03 6.8209e-05 7.2986e-05 -6.0000e+00 7.1997e-03 3.5963e-03 -5.4939e-05 11 8 0 10 0 0 98.94 21.95 0.32 0.00360 -0.00411 122 29 1 5 0 396.900 26.11 20.00 21.95 28.97 36.8 1012.60 -62805 -105370 42508 -115915 -74236 -107437 -62953 -108906 -79819 -90687 -1573 -81403 -9919 -39241 -26544 -1975 -25053 5068 -21153 2570 -21315 6721 -21878 1198 -22463 8258 -28702 3045 -19905 9238 -12332 -2298 -7056 -4740 -5140 -7291 -5788 -2237 17600 -3566 2095 -3177 1820 -1184 2814 -3745 2843 -3194 2325 944 3908 2555 4041 1414 732 1907 842 61 -557 629 1656 3653 3420 4052 -460 3128 584 1988 773 2018 400 1737 31 732 -1292 527 -1682 -2039 -463 -1237 -555 -1347 -2843 -1800 -503 -1292 145 -283 1378 315 808 260 965 -89 297 -50 360 667 -29 -198 -423 -860 -633 -47 -1895 -1192 -516 -424 -354 813 -138 120 78 863 -27 818 133 420 -359 -222 -848 181 277 121 655 198 483 1136 374 194 122 -215 -163 198 2 -243 -80 248 -468 -124 338 -296 -109 -454 -1356 134 -1727 -670 -1358 -554 -1696 -1045 -1433 -11 -1396 -105 -709 -527 -37 -656 109 -640 65 -702 168 -770 36 -913 261 -1225 101 -818 311 -610 -109 -404 -283 -295 -431 -378 -166 1304 -391 244 -417 240 -166 387 -566 411 -504 361 158 706 520 882 345 190 508 233 17 -153 170 463 1103 1072 1409 -174 1105 209 720 309 915 204 916 16 369 -611 220 -671 -819 -203 -641 -331 -853 -1998 -1328 -394 -1093 127 -257 1241 277 657 198 700 -66 242 -47 360 762 -36 -246 -498 -934 -679 -50 -2070 -1368 -621 -548 -496 1159 -218 199 129 1366 -41 1166 192 631 -577 -375 -1445 297 442 187 957 280 709 1590 584 337 218 -410 -326 414 4 -544 -185 580 -1109 -282 729 -613 -232 SS 20230822T055253.1Z 8634.245059 76 1 48.51 2 78.05 85.86 133.70 49.12 0.00 1 0.00 1 0 25 1.701e-01 6.368e-03 9.001e-02 2.672e-03 5.292349e-01 1.416971e-03 6.538263e-03 -6.000000e+00 9.943177e-02 231.67 -2.00 3.80 -2.00 320.44 0.00e+00 3.376081e-03 5.303890e-04 3.879863e-04 -6.000000e+00 4.329747e-03 283.08 -2.00 20.00 -2.00 319.80 0.00e+00 4.679 0.002 302.00 328.00 3 2.7740e+00 4.3351e-03 5.5665e-02 -6.0000e+00 2.4930e-01 -7.3078e-03 5.4353e-03 3.0989e-02 -6.0000e+00 2.6971e-01 -4.5259e-03 5.0061e-03 1.5827e-02 -6.0000e+00 1.6021e-01 -6.0106e-03 2.5135e-03 5.9748e-03 -6.0000e+00 6.7495e-02 1.8669e-04 -7.3808e-04 7.8836e-05 6.2325e-05 -6.0000e+00 4.7200e-03 3.0788e-03 -2.8825e-05 10 0 0 10 0 0 99.79 21.97 0.13 0.00308 -0.00247 84 20 1 5 0 577.420 26.11 20.01 21.97 29.44 36.9 1015.14 -85322 -33009 -73909 25109 -75325 -7047 -80907 -33752 -85631 -25396 -40616 -5318 -3118 -2911 -9465 3078 -3515 -14860 -14379 -16600 9095 -7261 3813 -3812 2502 -10794 9754 -4721 6312 -1553 2369 -2646 1853 -8645 1836 -4921 -5387 104 15802 -4673 -2254 -1385 -2947 -130 -2760 -187 -479 1645 -2279 6236 1212 3451 1235 2303 1381 342 589 126 -1077 422 522 978 2016 1901 180 816 -14 -89 1933 936 1543 -44 854 -765 -111 -114 438 -1608 -41 -993 -646 -1423 -2722 -1662 -1132 -783 278 390 484 581 349 1078 275 719 508 352 888 786 -119 -34 -112 -667 -702 7 -1826 -1204 -842 -615 501 306 488 117 135 76 223 614 471 56 -76 -144 -719 -24 202 66 543 -4 316 1154 127 241 -176 -240 -586 345 -286 -50 -99 340 -360 -57 393 -80 -173 -1009 -279 -970 128 -926 -46 -1155 -338 -1562 -286 -555 -58 -41 -48 -199 68 -92 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