File name: Pandora67s1_Cologne_20231025_L2Fit_fout2c2d20191024p1-8.txt File generation date: 20231026T094432.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20191024.txt Level 1 file used: Pandora67s1_Cologne_20231025_L1_smca1c2d20191024p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20231025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231025T072442.5Z 8698.308825 133 1 48.83 2 80.46 122.87 137.55 338.32 0.00 1 0.00 1 0 25 3.356e-01 8.167e-03 1.759e-01 4.038e-03 6.580227e-01 2.143165e-03 8.014869e-03 -6.000000e+00 1.906096e-01 223.45 -2.00 3.80 -2.00 320.98 0.00e+00 3.227307e-03 9.272985e-04 6.123012e-04 -6.000000e+00 8.485812e-03 275.42 -2.00 20.00 -2.00 320.50 0.00e+00 5.754 0.004 302.00 328.00 3 2.3572e+00 6.7739e-03 6.7849e-02 -6.0000e+00 4.6962e-01 1.5665e-01 9.1629e-03 3.8096e-02 -6.0000e+00 5.1199e-01 -1.3981e-01 9.6993e-03 2.0387e-02 -6.0000e+00 3.0442e-01 4.8773e-02 4.7502e-03 7.6139e-03 -6.0000e+00 1.3070e-01 8.7313e-05 -7.7099e-04 1.1557e-04 8.6874e-05 -6.0000e+00 9.3974e-03 -1.1888e-03 -6.5938e-05 11 8 0 10 0 0 96.94 20.76 0.21 -0.00119 -0.00698 50 12 1 5 0 976.410 25.07 20.00 20.76 16.04 35.5 943.09 900000 53756 -125736 -119410 900000 -155407 -102370 -126069 -101971 -120856 -64665 -96917 83212 -67486 -57072 -38273 -10339 14828 -11795 -34812 1676 31975 -19963 -24364 -36628 -23102 -27048 -27019 -11729 35395 -22585 11519 -10439 4659 -20262 -9276 -22427 4536 43535 7159 -5796 1063 -6876 -219 2620 -7443 3416 -7204 3320 3616 5784 2209 5061 1334 4412 3096 640 3589 1107 -1968 690 1126 3506 3409 208 4426 2057 4000 3149 2803 1243 508 -211 1337 -693 -359 -1890 -1169 -1362 345 411 -1090 -3825 -1288 -1282 -1654 -1086 238 1161 488 1667 1333 730 -1135 -108 -114 127 682 274 -701 49 -830 -1338 -250 -516 -435 -989 -977 48 162 -195 83 147 747 -190 693 367 700 -500 188 -722 295 581 239 219 -352 470 1014 737 -164 52 21 -641 -132 54 -93 -1 421 -419 -184 584 -429 -132 900000 212 -1287 -1109 900000 -1909 -840 -1409 -1012 -1579 -530 -1221 328 -1052 -1015 -681 -158 204 -221 -866 30 435 -465 -648 -1177 -687 -860 -834 -307 668 -882 379 -479 205 -1058 -453 -1341 244 2015 553 -554 102 -754 -23 273 -881 372 -907 396 463 813 360 878 263 898 663 140 785 241 -436 155 267 925 1017 67 1348 642 1270 1105 1095 546 235 -97 572 -276 -133 -665 -415 -543 155 216 -644 -2554 -890 -949 -1270 -867 193 936 382 1239 932 497 -808 -85 -101 125 749 328 -848 55 -893 -1313 -249 -535 -476 -1150 -1188 63 232 -302 135 243 1186 -289 1029 548 1055 -805 313 -1208 472 897 366 322 -502 667 1437 1142 -280 98 41 -1299 -281 121 -218 -3 996 -1003 -431 1281 -925 -275 SS 20231025T073354.7Z 8698.315216 139 1 48.72 2 79.26 124.80 137.98 341.47 0.00 1 0.00 1 0 17 2.357e-01 6.098e-03 8.152e-02 2.114e-03 5.953957e-01 1.094355e-03 7.316636e-03 -6.000000e+00 1.336668e-01 223.45 -2.00 3.80 -2.00 320.65 0.00e+00 2.815079e-03 4.326342e-04 4.986775e-04 -6.000000e+00 5.813198e-03 275.42 -2.00 20.00 -2.00 320.14 0.00e+00 5.166 0.003 302.00 328.00 3 1.8024e+00 3.3363e-03 6.0900e-02 -6.0000e+00 3.2959e-01 5.5240e-02 4.3304e-03 3.4048e-02 -6.0000e+00 3.5913e-01 -4.0576e-02 4.3984e-03 1.7837e-02 -6.0000e+00 2.1375e-01 8.3885e-03 2.2006e-03 6.5440e-03 -6.0000e+00 9.1043e-02 2.8923e-04 -6.8253e-04 6.0420e-05 6.9248e-05 -6.0000e+00 6.5239e-03 -1.5999e-03 -4.5531e-05 10 0 0 10 0 0 71.34 20.78 0.23 -0.00160 -0.00673 160 38 1 5 0 304.420 25.07 20.01 20.78 16.39 35.7 944.64 -28891 -75663 -104327 -80326 -104983 -33090 -106068 -75605 -60964 -28733 -65882 -65243 -47290 -38846 -35016 -23766 -26591 -17838 -7205 -28688 1812 -8437 -8240 -18959 -5090 -19069 -5537 -21201 -13196 -5715 -6520 -3638 1191 -3209 -4631 -8701 -8703 868 9209 -415 -2601 461 -735 1661 -1229 20 -2235 1603 1766 2400 255 3646 2812 1470 1780 1877 211 -959 442 -1099 1073 885 3398 1827 2251 1949 1674 624 2264 947 1445 54 680 -205 -100 -115 -225 -1112 -350 -423 -973 -1227 -2616 -1136 -1443 -587 -936 527 506 674 780 813 171 1014 308 292 394 654 -105 -376 -297 -421 -355 -62 -830 -1034 -649 -1005 -112 186 -54 58 -36 107 185 454 454 539 85 -317 -506 90 79 535 267 145 163 1408 200 169 -128 -114 -320 104 -195 -112 -104 501 -371 -162 352 -362 -97 -131 -640 -1269 -745 -1147 -177 -1290 -764 -603 -225 -788 -888 -682 -657 -715 -519 -613 -418 -181 -860 45 -235 -243 -618 -155 -708 -185 -803 -453 -199 -272 -173 62 -189 -266 -522 -584 62 744 -44 -321 59 -101 230 -178 3 -343 244 280 404 45 690 586 339 435 476 56 -257 114 -285 283 257 1090 668 857 724 618 240 934 454 705 28 347 -108 -49 -50 -92 -459 -159 -227 -564 -813 -1927 -874 -1194 -515 -802 458 443 568 657 640 130 779 263 267 414 786 -128 -461 -367 -478 -367 -64 -927 -1222 -807 -1257 -150 277 -83 94 -58 169 293 683 683 845 133 -520 -833 143 130 842 401 212 230 2019 323 286 -237 -214 -628 214 -429 -245 -234 1142 -859 -359 778 -768 -199 SS 20231025T074931.3Z 8698.326057 148 1 18.29 2 77.29 128.14 138.55 346.92 0.00 1 0.00 1 0 25 2.912e-01 1.267e-02 1.473e-01 6.969e-03 5.187528e-01 3.594923e-03 6.481268e-03 -6.000000e+00 1.654550e-01 223.45 -2.00 3.80 -2.00 320.07 0.00e+00 3.220048e-03 1.185407e-03 3.734928e-04 -6.000000e+00 7.778090e-03 275.42 -2.00 20.00 -2.00 319.54 0.00e+00 4.422 0.002 302.00 328.00 3 3.8875e+00 1.0403e-02 5.2291e-02 -6.0000e+00 4.0769e-01 8.8460e-02 1.2703e-02 2.9374e-02 -6.0000e+00 4.4436e-01 -5.6939e-02 1.1644e-02 1.5071e-02 -6.0000e+00 2.6422e-01 2.0297e-02 6.0266e-03 5.9257e-03 -6.0000e+00 1.1299e-01 7.6211e-05 -6.0638e-04 2.0394e-04 5.9646e-05 -6.0000e+00 8.1987e-03 -1.6662e-03 -1.3440e-05 12 9 9 12 1 1 78.51 20.81 0.22 -0.00167 -0.00622 6 4 1 5 0 2612.080 25.07 20.00 20.81 16.66 35.5 945.51 -49052 -23194 -101412 -82367 900000 -91295 -98442 -49083 204419 -45628 900000 -83245 900000 -54575 45493 7327 8602 1548 45598 -25948 42765 64506 9256 90 -5318 -10338 18400 25255 -20700 45904 -18890 30275 649 21791 -8215 16393 -14052 28435 11874 5449 -4266 12491 -4774 -2637 -9034 -1426 -35 2325 575 145 5815 -340 8943 -2414 5464 -50 4029 -3424 2566 -2743 2880 -2798 3548 -236 1086 912 1674 -881 2155 473 1784 2531 530 -171 -2784 1085 -2217 1886 -2532 -317 -2954 -617 -4439 106 -1877 -451 -1794 905 369 1604 627 1005 1094 199 549 -202 1207 37 1395 -805 591 -1756 -419 504 68 -1196 -936 -2250 458 269 226 610 -1081 448 -361 1467 208 144 -401 426 -1335 1251 337 744 -213 244 -79 1224 687 415 192 -652 -466 -475 295 -304 -115 433 237 -821 976 -243 -611 -682 -286 -2786 -1820 900000 -2020 -2523 -867 1389 -939 900000 -2794 900000 -2119 835 225 289 60 1258 -1470 1301 1602 406 5 -302 -651 901 1112 -1379 1737 -1515 1757 56 1641 -785 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