File name: Pandora124s1_ComodoroRivadavia_20181205_L2Fit_fwvt1c7d20181107p1-8.txt File generation date: 20240926T122147.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v7d20181107.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20181205_L1_smca1c7d20181107p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20181205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 2 for SO2 First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0748 492.1956 492.3165 492.4373 492.5581 492.6788 492.7996 492.9203 493.0410 493.1618 493.2824 493.4031 493.5238 493.6444 493.7650 493.8856 494.0062 494.1268 494.2473 494.3679 494.4884 494.6089 494.7294 494.8499 494.9703 495.0907 495.2112 495.3316 495.4520 495.5723 495.6927 495.8130 495.9333 496.0536 496.1739 496.2942 496.4144 496.5347 496.6549 496.7751 496.8953 497.0154 497.1356 497.2557 497.3758 497.4959 497.6160 497.7361 497.8561 497.9762 498.0962 498.2162 498.3362 498.4561 498.5761 498.6960 498.8159 498.9358 499.0557 499.1756 499.2954 499.4152 499.5350 499.6548 499.7746 499.8944 500.0141 500.1339 500.2536 500.3733 500.4929 500.6126 500.7322 500.8519 500.9715 501.0911 501.2106 501.3302 501.4497 501.5693 501.6888 501.8083 501.9277 502.0472 502.1666 502.2860 502.4054 502.5248 502.6442 502.7636 502.8829 503.0022 503.1215 503.2408 503.3601 503.4793 503.5986 503.7178 503.8370 503.9562 504.0753 504.1945 504.3136 504.4327 504.5518 504.6709 504.7900 504.9090 505.0280 505.1470 505.2660 505.3850 505.5040 505.6229 505.7418 505.8607 505.9796 506.0985 506.2174 506.3362 506.4550 506.5738 506.6926 506.8114 506.9302 507.0489 507.1676 507.2863 507.4050 507.5237 507.6423 507.7610 507.8796 507.9982 508.1168 508.2353 508.3539 508.4724 508.5909 508.7094 508.8279 508.9464 509.0648 509.1832 509.3016 509.4200 509.5384 509.6568 509.7751 509.8934 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181205T084139.0Z 6913.362257 314 1 32.00 2 89.80 122.83 82.89 100.69 0.00 1 0.00 1 0 36 1.994e-01 1.682e-01 1.777e-01 1.607e-01 1.499742e+04 1.292962e+04 2.426838e+03 -6.000000e+00 1.060409e+04 278.27 -2.00 20.00 -2.00 505.19 0.00e+00 -2.568373e-03 4.357836e-03 1.379115e-04 -6.000000e+00 5.504535e-03 278.27 -2.00 20.00 -2.00 499.36 0.00e+00 3.786070e-01 3.515182e+00 2.293211e-01 -6.000000e+00 4.005634e+00 231.62 -2.00 3.76 -2.00 501.04 0.00e+00 20.211 0.097 489.00 513.00 1 9.1553e+00 2.6501e-01 3.5241e-02 -6.0000e+00 3.0437e-01 2.0382e-01 7.1439e-02 2.3112e-03 -6.0000e+00 8.2389e-02 1.1391e-05 -8.5495e-03 1.3195e-02 1.9693e-04 -6.0000e+00 1.8254e-02 1.3060e-01 -1.9664e-03 12 8 8 10 0 0 -93.04 21.77 23.52 0.13060 0.07130 8 2 1 4 0 4000.000 25.90 20.00 21.77 900000 18975 17667 21430 19503 29737 -11946 19187 -451 17775 -19671 31331 -5294 7084 -25643 17500 2704 -26357 -995 -15422 216 18633 -1947 2991 -10623 -11294 8537 2868 8501 -13001 16524 -13140 18300 4240 54586 7343 2317 13194 44179 -3530 19822 3416 2149 3703 3394 -9858 12774 -17680 -19576 8704 7713 -11546 -8795 5911 21255 -1392 -17578 -6417 -4476 -7106 31980 1495 -16035 -7724 -72 2967 -21366 20167 7828 7626 1372 54703 -8946 33720 1974 7177 2961 56683 -15877 26715 14672 42329 35117 24164 11671 -7189 -5662 33621 -36471 33161 19987 27442 6543 -4524 -516 16137 -5176 27222 43823 4244 -914 -3796 -10328 1878 34633 -12426 -14499 1709 12725 8443 19773 18398 -21198 -13400 -6849 -17843 -9763 975 15239 -11170 41738 4568 45206 -21779 -19250 -21406 41446 -2718 -25809 -4277 37007 -64 2952 10850 7781 -6399 45872 -6892 14438 1070 16269 7903 31364 13940 -13230 450 15822 4346 23818 -9043 900000 17426 16457 19681 18935 26919 -15480 18589 -541 17867 -28587 26940 -6475 7549 -37266 16318 2914 -38304 -1145 -21104 259 18729 -2406 3514 -14279 -15319 9511 3370 9369 -17477 16009 -16550 16622 4467 35697 8004 2721 13902 33707 -4275 18725 3765 2394 4081 3781 -12655 13150 -24623 -27501 9065 7939 -13983 -10012 5655 17246 -1433 -21927 -7383 -5149 -8433 25561 1611 -20584 -9167 -79 3162 -28721 17585 7584 7296 1379 31799 -9751 24094 1960 6867 2976 32950 -18651 20059 12260 26656 23816 18436 10177 -7661 -6034 24430 -49626 24095 16460 20937 5739 -4477 -493 12884 -4947 18061 23655 3293 -730 -3073 -8943 1478 20642 -12576 -15653 1595 10589 7216 14898 14068 -24315 -14315 -6854 -19865 -9991 899 12338 -11933 26284 4109 26435 -24246 -20565 -23350 24236 -2476 -29604 -3944 22473 -56 2490 8297 6037 -5685 24245 -6278 10879 938 12441 6665 21162 11287 -14134 420 12633 3861 17142 -8847 SO 20181205T084558.0Z 6913.365255 318 1 32.00 2 89.16 122.06 82.17 99.97 0.00 1 0.00 1 0 8 1.174e-01 1.085e-01 9.490e-02 9.060e-02 9.632583e+02 5.551897e+03 4.337523e+02 -6.000000e+00 6.245031e+03 278.27 -2.00 20.00 -2.00 505.18 0.00e+00 5.608811e-04 2.487665e-03 1.011517e-04 -6.000000e+00 3.226088e-03 278.27 -2.00 20.00 -2.00 499.63 0.00e+00 3.182372e+00 1.881867e+00 1.048150e-01 -6.000000e+00 2.333704e+00 231.62 -2.00 3.76 -2.00 501.31 0.00e+00 19.039 0.081 489.00 513.00 1 8.5268e+00 1.4482e-01 3.0263e-02 -6.0000e+00 1.7789e-01 1.3564e-01 3.7548e-02 2.0573e-03 -6.0000e+00 4.7247e-02 2.0550e-05 -1.7151e-03 7.9556e-03 7.0587e-05 -6.0000e+00 1.0755e-02 7.2069e-02 -7.5769e-04 12 8 8 10 0 0 -366.67 21.77 -1.11 0.07207 0.06017 8 2 1 4 0 4000.000 25.90 20.00 21.77 -6398 -1332 -4226 6980 -5482 7978 -8775 7389 4999 13770 -16983 10770 2527 19298 -3156 17690 -7342 -802 3950 5715 -2975 15935 -10234 4893 3563 -6089 5896 -11630 973 -15842 -4851 -9455 -8599 -9270 10269 5379 37495 238 13028 -4790 26328 3744 -1581 -16593 18278 -9350 4799 -9407 18883 -10228 22619 -3858 -1941 -134 18413 -4629 -31 -2431 5235 10129 6952 11379 2966 -245 333 6784 198 1123 22367 4472 5214 1210 -7598 -3083 -3217 2146 -27275 26045 17321 7540 -758 9696 -14732 3279 -1525 828 -19712 14627 -8576 4428 1944 -1930 -13085 4015 -5754 4203 -7919 21218 -16981 18594 26608 27066 913 -1923 5641 -8964 17384 23303 -2068 11956 6810 21555 -11070 1967 3437 -8554 17057 3342 207 2316 8544 -12749 798 -2597 14612 -19131 4229 -844 24930 -2486 -7341 -12978 703 -13837 9895 -8259 5266 3174 700 -7336 20386 -6667 5906 13955 -1875 -12579 5585 3199 22901 -5836 -7195 -1439 -4846 7436 -6813 8853 -10846 8527 5462 13635 -22499 10664 2675 17000 -3448 15704 -8474 -887 4288 6205 -3535 15669 -13068 5379 3991 -7527 6442 -15010 1083 -20121 -5366 -10912 -9983 -11205 10589 5914 29701 270 12811 -5561 22293 3989 -1792 -22096 17349 -11749 5210 -11627 17279 -12223 18844 -4057 -1962 -132 15466 -5058 -33 -2706 5398 9891 6978 10957 3119 -266 357 6717 206 1135 18023 4244 4843 1165 -8042 -3158 -3339 2110 -35388 19386 13839 6591 -719 8343 -16298 3045 -1500 803 -23557 12386 -9136 4142 1871 -1950 -13940 3921 -5728 3731 -7783 15203 -17336 12970 16872 17163 770 -1732 4865 -9038 13338 16550 -1862 9325 5657 15718 -11372 1796 3117 -8787 13628 3072 196 2115 7205 -13096 708 -2388 11397 -20986 3674 -771 17547 -2301 -7122 -13167 611 -13687 7655 -7699 4374 2758 635 -7304 15512 -6680 5243 11503 -1819 -13560 4958 2840 16264 -5439 SO 20181205T085021.0Z 6913.368299 322 1 32.00 2 88.51 121.29 81.43 99.24 0.00 1 0.00 1 0 36 6.386e-02 6.157e-02 5.733e-02 5.588e-02 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