File name: Pandora124s1_ComodoroRivadavia_20190103_L2Fit_fwvt1c7d20181107p1-8.txt File generation date: 20240926T123635.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v7d20181107.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190103_L1_smca1c7d20181107p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 2 for SO2 First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0748 492.1956 492.3165 492.4373 492.5581 492.6788 492.7996 492.9203 493.0410 493.1618 493.2824 493.4031 493.5238 493.6444 493.7650 493.8856 494.0062 494.1268 494.2473 494.3679 494.4884 494.6089 494.7294 494.8499 494.9703 495.0907 495.2112 495.3316 495.4520 495.5723 495.6927 495.8130 495.9333 496.0536 496.1739 496.2942 496.4144 496.5347 496.6549 496.7751 496.8953 497.0154 497.1356 497.2557 497.3758 497.4959 497.6160 497.7361 497.8561 497.9762 498.0962 498.2162 498.3362 498.4561 498.5761 498.6960 498.8159 498.9358 499.0557 499.1756 499.2954 499.4152 499.5350 499.6548 499.7746 499.8944 500.0141 500.1339 500.2536 500.3733 500.4929 500.6126 500.7322 500.8519 500.9715 501.0911 501.2106 501.3302 501.4497 501.5693 501.6888 501.8083 501.9277 502.0472 502.1666 502.2860 502.4054 502.5248 502.6442 502.7636 502.8829 503.0022 503.1215 503.2408 503.3601 503.4793 503.5986 503.7178 503.8370 503.9562 504.0753 504.1945 504.3136 504.4327 504.5518 504.6709 504.7900 504.9090 505.0280 505.1470 505.2660 505.3850 505.5040 505.6229 505.7418 505.8607 505.9796 506.0985 506.2174 506.3362 506.4550 506.5738 506.6926 506.8114 506.9302 507.0489 507.1676 507.2863 507.4050 507.5237 507.6423 507.7610 507.8796 507.9982 508.1168 508.2353 508.3539 508.4724 508.5909 508.7094 508.8279 508.9464 509.0648 509.1832 509.3016 509.4200 509.5384 509.6568 509.7751 509.8934 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190103T085254.0Z 6942.370069 243 1 32.00 2 89.81 123.57 72.91 98.53 0.00 1 0.00 1 0 22 6.262e-02 6.103e-02 6.113e-02 6.003e-02 2.152326e+04 4.751990e+03 1.316900e+03 -6.000000e+00 3.346660e+03 279.48 -2.00 20.00 -2.00 505.43 0.00e+00 4.155728e-03 1.628928e-03 3.266099e-04 -6.000000e+00 1.723317e-03 279.48 -2.00 20.00 -2.00 500.47 0.00e+00 1.851899e+00 1.215851e+00 1.680444e-01 -6.000000e+00 1.239611e+00 232.36 -2.00 3.76 -2.00 502.03 0.00e+00 20.190 0.097 489.00 513.00 1 7.9595e+00 9.2957e-02 3.5358e-02 -6.0000e+00 9.4617e-02 4.8629e-02 2.3351e-02 4.1924e-03 -6.0000e+00 2.4971e-02 3.1377e-05 -5.3340e-03 4.8043e-03 1.3507e-04 -6.0000e+00 5.7349e-03 -2.8294e-02 2.1515e-04 12 9 8 11 8 0 -19.80 21.56 6.89 -0.02829 -0.06529 8 2 1 4 0 4000.000 25.68 20.01 21.56 593 -989 -970 1154 5652 1291 3390 11243 5549 3876 -1835 -915 -7302 5633 10558 2764 -8607 -6181 -5457 -479 1100 766 -2056 -7675 -4751 6048 -1406 5211 -4029 3038 -2124 3088 5475 -805 -9383 4234 -674 -187 2173 4577 -940 9009 6793 2689 4951 2285 3342 4888 -467 2825 -5709 -10896 -2145 -4775 7507 -3603 5596 -6970 -4477 -3551 10026 7129 -6489 1990 -2268 782 6845 -10119 12035 -7976 1094 5178 8883 -4493 8049 -11275 -443 420 -2553 -3982 7901 -4816 -9709 7316 2942 -3096 -893 -12494 -5523 -570 1979 -7325 -4754 7965 7540 8225 -5702 -5646 10103 8932 -12105 8625 -8631 3761 -8221 9311 184 13045 -6745 10101 6923 3825 -5770 6875 -8888 14034 -1936 3648 -1398 5892 -1334 4216 -786 7650 -3406 -7024 680 9610 4966 6337 -4437 340 2751 -817 -8791 8579 4977 35 -2119 -7405 7768 2666 -1322 -661 -29 -8486 8371 -5945 14939 -2999 553 -877 -891 1081 5217 1274 3344 10377 5423 3805 -1876 -915 -7664 5122 9076 2576 -9112 -6544 -5901 -501 1135 794 -2195 -8716 -5289 6075 -1520 5234 -4338 2942 -2114 2920 5153 -838 -11038 4407 -732 -199 2242 4577 -995 8723 6823 2860 5219 2491 3598 5131 -510 2914 -6225 -12176 -2165 -4969 7099 -3945 5748 -8231 -5166 -4048 9980 7354 -7722 2178 -2576 849 6875 -11858 11162 -8914 1103 5014 8360 -4900 7830 -13264 -459 422 -2599 -4071 7150 -4969 -9830 6786 2683 -3031 -856 -13333 -5430 -529 1796 -7386 -4733 6961 6430 6670 -5079 -4839 7216 6342 -10527 6197 -7688 3144 -8186 8020 175 10797 -6745 8573 6166 3568 -5963 6268 -9485 11969 -1968 3586 -1463 5693 -1356 3950 -760 6782 -3405 -7348 663 8600 4653 5857 -4549 327 2543 -779 -9123 7605 4684 35 -2217 -8307 7604 2777 -1444 -719 -31 -9911 8159 -6568 13181 -3150 SO 20190103T085658.0Z 6942.372894 247 1 32.00 2 89.22 122.85 72.23 97.86 0.00 1 0.00 1 0 22 8.053e-02 7.914e-02 6.314e-02 6.164e-02 1.538351e+04 4.642420e+03 1.233696e+03 -6.000000e+00 4.304227e+03 279.48 -2.00 20.00 -2.00 505.24 0.00e+00 -1.773358e-04 1.666274e-03 4.324517e-05 -6.000000e+00 2.214973e-03 279.48 -2.00 20.00 -2.00 500.02 0.00e+00 1.227108e-01 1.260575e+00 4.995580e-02 -6.000000e+00 1.589837e+00 232.36 -2.00 3.76 -2.00 501.62 0.00e+00 19.132 0.082 489.00 513.00 1 8.3360e+00 9.6660e-02 2.9873e-02 -6.0000e+00 1.2141e-01 1.4477e-01 2.4522e-02 2.4460e-03 -6.0000e+00 3.1934e-02 3.0464e-05 -3.1390e-03 5.0071e-03 1.3215e-04 -6.0000e+00 7.3652e-03 -1.2637e-02 3.1899e-04 12 8 8 10 0 0 65.04 21.56 0.96 -0.01264 -0.03441 8 2 1 4 0 4000.000 25.68 20.02 21.56 -3727 4288 3993 70 -6549 8736 -8996 5402 -5102 5772 -11184 2947 -8220 6525 -6170 19078 -3265 8987 -8464 7927 -207 3174 4465 7492 -3452 6939 -2498 8143 -14315 -3718 -13103 -539 5209 12455 114 6369 5235 8809 -6659 -5851 -355 1244 -679 8368 4761 138 17000 -8922 14079 4552 6044 -2205 2439 -9597 4348 -12203 9278 -3330 1515 -8875 11285 -6571 16228 -3521 3658 -1520 15253 -10915 8545 -5492 12085 -12978 2281 -7782 20362 -5444 979 -9186 -1373 -1463 3143 -11244 1368 4493 11518 -7258 -3381 2423 -3325 2561 7571 5858 9055 3489 -5229 5758 329 5740 771 404 -5756 -2515 -13801 -3081 -799 14795 1508 19834 -10965 6813 -16379 3719 -5010 -1184 -13849 654 5786 4775 8471 12787 -5483 4463 1749 10517 2635 11444 -3037 14008 -4035 8204 1739 800 -5855 7027 -2476 15441 -2986 5346 6827 -6250 8381 -6069 7258 -10689 4753 -2416 -615 -13391 6985 -8151 -3940 4273 4140 78 -7394 8645 -10825 5672 -5926 5927 -13406 3026 -9280 6276 -6707 16221 -3535 8852 -10185 8176 -232 3436 4771 7797 -4025 7286 -2867 8286 -17692 -3990 -15220 -556 5203 12036 128 6747 5545 8881 -7734 -6687 -385 1335 -751 8553 5087 154 15954 -10695 13147 4547 5757 -2223 2323 -10434 4243 -14515 9096 -3728 1612 -10433 10854 -7602 15004 -3959 3790 -1631 13606 -12475 7940 -5792 10612 -14713 2247 -8605 17123 -5868 969 -9859 -1346 -1427 2935 -12224 1322 4258 10328 -7925 -3550 2386 -3199 2499 7070 5231 7891 3176 -5030 4769 277 4432 612 317 -4817 -2094 -13515 -2871 -759 12191 1412 15231 -11353 5937 -18231 3417 -5036 -1144 -15176 624 5317 4490 7675 10923 -5488 3948 1570 8666 2364 9430 -2896 11240 -3864 6937 1553 708 -5456 5729 -2232 11857 -2821 4728 6038 -6390 7484 -6310 6638 -11713 4449 -2407 -592 -14327 5997 -8123 SO 20190103T090059.0Z 6942.375683 251 1 32.00 2 88.63 122.14 71.55 97.20 0.00 1 0.00 1 0 22 5.581e-02 5.471e-02 5.025e-02 4.920e-02 1.082258e+04 3.523958e+03 6.655264e+02 -6.000000e+00 2.982364e+03 279.48 -2.00 20.00 -2.00 505.21 0.00e+00 1.480142e-03 1.327985e-03 6.435741e-05 -6.000000e+00 1.535667e-03 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