File name: Pandora113s1_Cordoba_20240830_L2Fit_fout2c2d20230530p1-8.txt File generation date: 20240831T042328.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 113 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora113_OF_v4d20210811.txt Instrument calibration file used: Pandora113s1_CF_v2d20230530.txt Level 1 file used: Pandora113s1_Cordoba_20240830_L1_smca1c2d20230530p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20240830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Redoing lab cal analysis from 2021 using new measurements + creating OoB CF First and last pixel inside fitting window: 208 352 Nominal wavelengths inside fitting window [nm]: 305.0013 305.1409 305.2805 305.4201 305.5597 305.6993 305.8388 305.9783 306.1179 306.2574 306.3969 306.5364 306.6758 306.8153 306.9548 307.0942 307.2336 307.3730 307.5124 307.6518 307.7912 307.9306 308.0699 308.2093 308.3486 308.4879 308.6272 308.7665 308.9058 309.0451 309.1844 309.3236 309.4628 309.6021 309.7413 309.8805 310.0197 310.1588 310.2980 310.4372 310.5763 310.7154 310.8545 310.9936 311.1327 311.2718 311.4109 311.5499 311.6890 311.8280 311.9670 312.1060 312.2450 312.3840 312.5230 312.6619 312.8009 312.9398 313.0787 313.2176 313.3565 313.4954 313.6343 313.7732 313.9120 314.0509 314.1897 314.3285 314.4673 314.6061 314.7449 314.8836 315.0224 315.1611 315.2998 315.4385 315.5773 315.7159 315.8546 315.9933 316.1319 316.2706 316.4092 316.5478 316.6864 316.8250 316.9636 317.1022 317.2407 317.3793 317.5178 317.6563 317.7948 317.9333 318.0718 318.2103 318.3487 318.4872 318.6256 318.7640 318.9024 319.0408 319.1792 319.3176 319.4560 319.5943 319.7326 319.8710 320.0093 320.1476 320.2859 320.4241 320.5624 320.7006 320.8389 320.9771 321.1153 321.2535 321.3917 321.5299 321.6680 321.8062 321.9443 322.0824 322.2206 322.3587 322.4967 322.6348 322.7729 322.9109 323.0490 323.1870 323.3250 323.4630 323.6010 323.7390 323.8769 324.0149 324.1528 324.2908 324.4287 324.5666 324.7045 324.8423 324.9802 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-389: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240830T162540.9Z 9008.684501 284 1 5.62 2 40.39 356.28 68.64 321.95 0.00 1 0.00 1 0 17 1.019e-02 7.495e-03 4.536e-03 2.749e-03 1.924067e-01 1.374358e-03 2.072662e-03 -6.000000e+00 5.701453e-03 227.32 -2.00 3.11 -2.00 315.41 0.00e+00 5.085703e-04 1.287028e-04 2.703648e-05 -6.000000e+00 2.503653e-04 282.23 -2.00 20.00 -2.00 314.80 0.00e+00 1.312 0.000 302.00 328.00 3 4.2047e+00 3.5313e-03 1.5374e-02 -6.0000e+00 1.4168e-02 1.9398e-02 3.9290e-03 8.7253e-03 -6.0000e+00 1.5359e-02 -3.9324e-03 2.2604e-03 4.2836e-03 -6.0000e+00 9.1463e-03 -1.9515e-03 1.0384e-03 1.2556e-03 -6.0000e+00 3.9586e-03 1.8023e-03 1.0949e-03 7.3057e-05 1.4012e-05 -6.0000e+00 2.5633e-04 4.3177e-02 0.0000e+00 12 9 1 12 1 1 99.91 22.67 0.45 0.04318 0.05140 8 20 1 5 0 623.790 26.73 20.00 22.67 19.81 6.4 1001.92 729 1440 -217 -1716 -2306 -1833 -1162 599 2356 -570 -896 -3179 -1275 -186 -607 148 -118 867 707 2096 689 588 1007 -41 69 1347 1003 40 -162 -414 -284 773 1742 1301 -2103 -2952 -4171 -1825 -744 -515 -973 -1194 -153 -885 28 132 -382 -117 -1108 -1021 523 690 369 710 522 1256 1285 636 1123 84 536 1478 1272 1428 1498 406 -468 -727 -450 729 504 846 730 465 55 115 -60 -689 -1157 -1451 -1337 -1362 -1475 -2056 -1597 -1235 -10 311 104 569 711 832 -508 -560 -634 251 307 685 711 537 39 -142 -1224 -774 0 -1002 -783 -578 -777 39 111 335 792 734 -258 -259 -339 -440 204 352 64 108 315 395 339 813 378 132 332 695 538 489 20 -504 -92 223 -28 225 468 -48 -28 -313 -868 -785 900000 196 417 -65 -485 -571 -419 -274 156 677 -177 -271 -967 -415 -62 -232 61 -51 374 315 949 325 273 464 -20 33 656 493 20 -75 -182 -127 364 872 640 -1090 -1429 -2124 -963 -465 -356 -704 -910 -119 -701 22 103 -295 -87 -800 -764 392 515 293 587 449 1086 1132 535 983 73 465 1251 1167 1408 1452 403 -420 -639 -388 644 507 860 764 482 55 112 -56 -577 -926 -1235 -1208 -1372 -1535 -2263 -1729 -1432 -12 382 131 715 856 969 -571 -569 -656 257 345 804 873 699 50 -179 -1428 -899 0 -1258 -987 -758 -1061 52 158 477 1135 1058 -348 -332 -426 -545 261 458 87 151 437 533 464 1048 490 161 395 865 683 654 28 -701 -131 318 -42 335 712 -75 -43 -467 -1318 -1152 900000 SS 20240830T163006.6Z 9008.687576 287 1 48.52 2 40.46 354.60 69.20 321.10 0.00 1 0.00 1 0 17 4.012e-02 1.440e-02 2.393e-02 9.536e-03 1.989849e-01 4.720484e-03 2.147740e-03 -6.000000e+00 2.244736e-02 227.32 -2.00 3.11 -2.00 316.88 0.00e+00 1.009834e-03 6.020801e-04 2.621116e-04 -6.000000e+00 9.854781e-04 282.23 -2.00 20.00 -2.00 316.17 0.00e+00 1.313 0.000 302.00 328.00 3 7.0520e+00 1.2365e-02 1.5547e-02 -6.0000e+00 5.5782e-02 5.0128e-02 1.3865e-02 8.9637e-03 -6.0000e+00 6.0463e-02 1.6457e-03 8.1740e-03 4.4420e-03 -6.0000e+00 3.6006e-02 -4.3508e-03 3.9679e-03 1.3750e-03 -6.0000e+00 1.5591e-02 1.0118e-04 1.4771e-03 2.6178e-04 1.2979e-05 -6.0000e+00 1.0086e-03 4.0519e-02 0.0000e+00 12 8 8 10 0 0 99.95 22.67 0.70 0.04052 0.05162 21 5 1 5 0 2310.500 26.73 20.00 22.67 20.01 6.4 1003.32 2299 17059 -9431 7242 -1376 -17662 22213 -1648 11210 -7671 -4163 -3079 -3624 10561 -4632 383 -528 4150 795 -45 5893 -4295 2179 -8229 -149 -2802 1985 4348 -503 4775 -10035 1371 -2545 2670 4137 -1019 619 -6565 4263 -2553 810 -614 630 -1028 -1706 3066 7 387 -2944 -2267 -270 -116 2990 -568 1029 -255 1453 648 1032 458 -419 3878 -823 3380 1475 1255 -32 -193 300 -816 275 256 1443 -359 1889 2090 -96 -2267 -4073 -1797 -2244 -1274 -3130 -1557 -872 -1067 284 758 561 1681 -86 746 -2205 -422 -3077 -751 -464 671 1169 171 1020 -2166 -1619 -767 -545 -1627 -1087 778 -1304 1306 852 1412 1300 190 1471 -1504 -898 -1797 430 178 623 801 630 1203 -848 1085 524 -1204 -385 -1649 525 607 -3 -1029 -212 552 236 1003 -995 1303 285 -2 -1000 -1149 900000 358 2505 -1819 1115 -202 -2823 2523 -262 1760 -1514 -773 -560 -722 2085 -1195 103 -148 1137 233 -14 1737 -1378 652 -2840 -50 -1005 684 1391 -156 1335 -3297 431 -894 940 1365 -328 204 -2632 1833 -1383 471 -380 396 -669 -1112 1909 4 237 -1800 -1339 -159 -73 1927 -395 731 -186 1063 482 753 330 -305 2845 -683 2888 1337 1094 -25 -143 218 -656 246 246 1409 -352 1745 1789 -75 -1638 -2860 -1310 -1848 -1153 -3135 -1611 -932 -1222 343 961 731 2164 -108 863 -2387 -408 -2943 -742 -501 786 1496 233 1354 -2774 -1899 -850 -625 -2053 -1437 1051 -1862 1893 1308 2258 2108 300 2139 -2058 -1140 -2271 552 245 916 1218 956 1774 -1230 1472 684 -1505 -467 -2123 708 858 -4 -1522 -319 866 393 1706 -1757 2288 500 -4 -1667 -1861 900000 SS 20240830T163438.6Z 9008.690725 290 1 47.81 2 40.57 352.88 69.78 320.23 0.00 1 0.00 1 0 21 1.365e-02 8.582e-03 1.038e-02 4.407e-03 1.976195e-01 2.185205e-03 2.126128e-03 -6.000000e+00 7.630757e-03 227.32 -2.00 3.11 -2.00 316.72 0.00e+00 2.811629e-07 2.675545e-04 3.175980e-05 -6.000000e+00 3.351421e-04 282.23 -2.00 20.00 -2.00 316.01 0.00e+00 1.315 0.000 302.00 328.00 3 6.0903e+00 5.7085e-03 1.5572e-02 -6.0000e+00 1.8962e-02 4.2588e-02 6.3925e-03 8.9904e-03 -6.0000e+00 2.0559e-02 -2.1046e-03 3.7492e-03 4.4341e-03 -6.0000e+00 1.2242e-02 -4.7826e-03 1.8059e-03 1.2633e-03 -6.0000e+00 5.2968e-03 2.6781e-04 1.1193e-03 1.2073e-04 1.3698e-05 -6.0000e+00 3.4321e-04 4.5146e-02 0.0000e+00 11 8 0 10 0 0 99.95 22.67 0.59 0.04515 0.05356 37 10 1 5 0 1292.040 26.73 20.00 22.67 20.12 6.3 1003.87 884 -3077 472 -2224 3079 -1108 -531 -864 234 1580 -2689 900 -3739 -66 2721 -129 -801 -1718 2146 -2435 3185 2011 -575 465 -1496 1795 -736 227 2029 2492 410 451 3496 -691 690 -4876 -2952 -2938 -754 -268 -2377 244 -325 465 -695 -532 132 -1422 34 -2856 2110 337 1881 1168 500 786 -418 1486 -10 960 467 872 1012 874 2175 -522 260 -2270 -555 618 86 1298 -83 558 674 1349 -82 -1590 -956 -2621 -1283 -1489 -807 -2338 -1007 -834 -610 573 634 1010 842 513 50 -1383 -436 -426 495 449 1094 843 647 -143 -1521 -631 -759 -918 -971 -420 -719 -545 575 706 718 210 -57 -307 -1049 -441 -802 318 -408 522 337 402 177 289 699 -532 478 909 724 894 -303 -680 -404 389 199 374 625 204 151 -760 -669 -786 900000 147 -577 87 -393 454 -159 -79 -145 44 306 -527 169 -795 -15 690 -37 -236 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