File name: Pandora113s1_Cordoba_20250715_L2Fit_fout2c2d20230530p1-8.txt File generation date: 20250716T042741.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 113 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora113_OF_v4d20210811.txt Instrument calibration file used: Pandora113s1_CF_v2d20230530.txt Level 1 file used: Pandora113s1_Cordoba_20250715_L1_smca1c2d20230530p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20250715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Redoing lab cal analysis from 2021 using new measurements + creating OoB CF First and last pixel inside fitting window: 208 352 Nominal wavelengths inside fitting window [nm]: 305.0013 305.1409 305.2805 305.4201 305.5597 305.6993 305.8388 305.9783 306.1179 306.2574 306.3969 306.5364 306.6758 306.8153 306.9548 307.0942 307.2336 307.3730 307.5124 307.6518 307.7912 307.9306 308.0699 308.2093 308.3486 308.4879 308.6272 308.7665 308.9058 309.0451 309.1844 309.3236 309.4628 309.6021 309.7413 309.8805 310.0197 310.1588 310.2980 310.4372 310.5763 310.7154 310.8545 310.9936 311.1327 311.2718 311.4109 311.5499 311.6890 311.8280 311.9670 312.1060 312.2450 312.3840 312.5230 312.6619 312.8009 312.9398 313.0787 313.2176 313.3565 313.4954 313.6343 313.7732 313.9120 314.0509 314.1897 314.3285 314.4673 314.6061 314.7449 314.8836 315.0224 315.1611 315.2998 315.4385 315.5773 315.7159 315.8546 315.9933 316.1319 316.2706 316.4092 316.5478 316.6864 316.8250 316.9636 317.1022 317.2407 317.3793 317.5178 317.6563 317.7948 317.9333 318.0718 318.2103 318.3487 318.4872 318.6256 318.7640 318.9024 319.0408 319.1792 319.3176 319.4560 319.5943 319.7326 319.8710 320.0093 320.1476 320.2859 320.4241 320.5624 320.7006 320.8389 320.9771 321.1153 321.2535 321.3917 321.5299 321.6680 321.8062 321.9443 322.0824 322.2206 322.3587 322.4967 322.6348 322.7729 322.9109 323.0490 323.1870 323.3250 323.4630 323.6010 323.7390 323.8769 324.0149 324.1528 324.2908 324.4287 324.5666 324.7045 324.8423 324.9802 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-389: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250715T121631.0Z 9327.511470 277 1 44.94 2 79.10 56.22 65.71 282.04 0.00 1 0.00 1 0 25 3.228e-01 1.254e-02 2.264e-01 6.505e-03 5.612437e-01 3.383398e-03 5.940557e-03 -6.000000e+00 1.793708e-01 225.42 -2.00 3.11 -2.00 321.04 0.00e+00 3.377260e-03 1.505075e-03 2.627881e-03 -6.000000e+00 7.928259e-03 282.22 -2.00 20.00 -2.00 320.48 0.00e+00 5.098 0.001 302.00 328.00 3 2.6370e+00 1.1090e-02 5.6244e-02 -6.0000e+00 4.4379e-01 6.3652e-02 1.4666e-02 2.9610e-02 -6.0000e+00 4.8163e-01 -1.4134e-01 1.4094e-02 1.6549e-02 -6.0000e+00 2.8724e-01 5.4362e-02 6.8861e-03 5.6586e-03 -6.0000e+00 1.2494e-01 1.6116e-04 2.9510e-04 1.8110e-04 7.5698e-05 -6.0000e+00 8.1097e-03 3.7840e-02 0.0000e+00 12 9 9 12 1 1 99.89 22.51 0.50 0.03784 0.04006 51 14 1 5 0 864.120 26.62 20.00 22.51 19.26 17.7 969.83 -162931 -31713 -125786 -40204 -57330 19843 -28626 -128497 66220 -141833 -27502 -115778 -104371 -45550 -16753 -18005 -54055 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-317 830 -31 466 -1315 -2923 -484 -1979 19 -645 -617 -783 -855 611 -835 1264 -281 439 -295 -8 631 -2316 232 -1851 714 773 909 -230 -1621 -522 -2448 -623 -1094 -595 -2199 -2003 43 -1191 2080 164 1440 531 551 -10 -1192 -104 -1044 301 112 1852 1776 1030 1444 102 527 -533 2032 1066 -53 148 -647 -302 -434 -11 97 1269 767 -1090 -648 -2572 444 900000 SS 20250715T122203.2Z 9327.515315 280 1 19.59 2 78.13 55.36 66.85 281.25 0.00 1 0.00 1 0 17 2.611e-01 9.813e-03 8.150e-02 3.877e-03 5.251301e-01 1.972104e-03 5.493507e-03 -6.000000e+00 1.450822e-01 225.42 -2.00 3.11 -2.00 320.60 0.00e+00 2.124050e-03 7.754919e-04 1.618760e-03 -6.000000e+00 6.412418e-03 282.22 -2.00 20.00 -2.00 320.01 0.00e+00 4.712 0.001 302.00 328.00 3 1.9162e+00 6.1356e-03 5.1524e-02 -6.0000e+00 3.5896e-01 1.3622e-02 7.7470e-03 2.5614e-02 -6.0000e+00 3.8955e-01 -9.8157e-02 7.0810e-03 1.3577e-02 -6.0000e+00 2.3232e-01 4.1195e-02 3.5664e-03 4.4212e-03 -6.0000e+00 1.0106e-01 4.9760e-04 1.4260e-04 1.0714e-04 5.4166e-05 -6.0000e+00 6.5589e-03 3.7427e-02 0.0000e+00 12 9 9 12 1 1 99.47 22.51 0.46 0.03743 0.03850 52 34 1 5 0 369.530 26.62 20.00 22.51 19.31 17.7 970.31 -159365 -53625 -77779 -32832 -49963 -97994 -71891 -118672 -88873 -83686 -54454 -20447 -35890 -54835 -25360 -11702 -18504 -3343 2256 -4191 -1150 -27251 -7137 -14538 10962 -2558 462 -15275 -7406 -9987 -24363 -10579 -5597 1758 -3987 -669 301 -9615 4388 -3086 7964 4699 4684 5793 4642 2446 -452 2730 -232 6132 2796 2522 7516 3785 4493 1868 3375 1435 1744 1741 1246 2550 2133 3263 3022 3396 1822 2423 1187 -46 261 524 2605 1754 404 -421 -1097 -3337 -3921 -2359 -2119 -1349 -1705 -2267 -2198 -1955 -176 221 1105 1291 412 819 -558 -973 -1091 -723 -830 171 708 526 -83 -299 -1047 -1085 -493 -1245 -1412 -976 -1356 108 580 857 470 325 568 -573 -555 278 35 173 202 -5 102 776 807 321 511 271 761 557 -6 -64 -67 -695 164 78 149 104 106 236 -339 -225 -301 -413 900000 -4711 -710 -1412 -372 -605 -1816 -1087 -2978 -2083 -2025 -1009 -286 -706 -1638 -700 -336 -579 -107 74 -141 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2.7513e-01 1.6550e-03 7.1681e-03 2.4106e-02 -6.0000e+00 2.9857e-01 -7.6463e-02 6.3368e-03 1.2442e-02 -6.0000e+00 1.7807e-01 3.0898e-02 3.2438e-03 3.8081e-03 -6.0000e+00 7.7464e-02 6.0403e-04 3.4874e-04 1.0475e-04 4.4731e-05 -6.0000e+00 5.0269e-03 3.7165e-02 0.0000e+00 12 9 1 12 9 1 99.30 22.51 0.54 0.03716 0.03979 37 34 1 5 0 363.380 26.62 20.00 22.51 19.45 17.8 971.08 -56018 -65932 35503 -70187 -31587 -69724 -95798 -55635 -69684 -21385 -73442 -50542 -69444 -32226 -25933 -17877 -2491 -25138 -13072 -22603 -4445 -9227 -1864 -4471 -8579 -2613 -9459 -13859 -11658 -10061 -2351 -7826 -1731 -3746 -696 -13851 -11481 -8344 1701 6650 3557 8893 478 4955 1549 4426 3707 -829 4200 -1239 2850 115 2196 497 2310 3696 2494 4156 -201 999 -86 2461 2038 3205 4715 1146 1771 1331 -758 739 1804 1435 994 1195 545 4 -1782 -3512 -2531 -3477 -1132 -1618 -1310 -2891 -1654 -198 -635 820 -128 751 995 634 -485 -1146 -1586 -653 -551 -15 768 495 23 -216 -1013 -803 -1205 -1101 -1479 -739 -552 -237 643 670 1056 252 100 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