File name: Pandora125s1_Cordoba_20180815_L2Fit_fwvt1c5d20170323p1-8.txt File generation date: 20250311T143122.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v3d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20180815_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20180815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2356 492.3572 492.4787 492.6001 492.7216 492.8431 492.9645 493.0859 493.2073 493.3287 493.4501 493.5714 493.6927 493.8141 493.9354 494.0566 494.1779 494.2992 494.4204 494.5416 494.6628 494.7840 494.9052 495.0263 495.1474 495.2686 495.3897 495.5107 495.6318 495.7529 495.8739 495.9949 496.1159 496.2369 496.3579 496.4788 496.5997 496.7206 496.8415 496.9624 497.0833 497.2041 497.3250 497.4458 497.5666 497.6874 497.8081 497.9289 498.0496 498.1703 498.2910 498.4117 498.5323 498.6530 498.7736 498.8942 499.0148 499.1354 499.2560 499.3765 499.4970 499.6175 499.7380 499.8585 499.9790 500.0994 500.2198 500.3403 500.4606 500.5810 500.7014 500.8217 500.9420 501.0624 501.1826 501.3029 501.4232 501.5434 501.6636 501.7838 501.9040 502.0242 502.1444 502.2645 502.3846 502.5047 502.6248 502.7449 502.8649 502.9850 503.1050 503.2250 503.3450 503.4649 503.5849 503.7048 503.8247 503.9446 504.0645 504.1844 504.3042 504.4241 504.5439 504.6637 504.7835 504.9032 505.0230 505.1427 505.2624 505.3821 505.5018 505.6215 505.7411 505.8607 505.9803 506.0999 506.2195 506.3391 506.4586 506.5781 506.6976 506.8171 506.9366 507.0561 507.1755 507.2949 507.4143 507.5337 507.6531 507.7725 507.8918 508.0111 508.1304 508.2497 508.3690 508.4882 508.6074 508.7267 508.8459 508.9650 509.0842 509.2034 509.3225 509.4416 509.5607 509.6798 509.7988 509.9179 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180815T105648.0Z 6801.456111 444 1 32.01 2 89.71 73.32 125.53 118.99 0.00 1 0.00 1 0 15 4.484e-02 4.437e-02 3.484e-02 3.458e-02 5.602609e+03 2.387761e+03 3.046558e+02 -6.000000e+00 2.591647e+03 281.90 -2.00 20.00 -2.00 505.38 0.00e+00 3.468883e-03 9.798312e-04 2.115018e-04 -6.000000e+00 1.280862e-03 281.90 -2.00 20.00 -2.00 500.53 0.00e+00 1.770567e+00 7.064140e-01 6.340016e-02 -6.000000e+00 9.134924e-01 226.61 -2.00 3.11 -2.00 502.15 0.00e+00 20.108 0.067 489.00 513.00 1 8.8650e+00 5.4175e-02 3.0176e-02 -6.0000e+00 7.0102e-02 8.6837e-02 1.3565e-02 1.9819e-03 -6.0000e+00 1.8123e-02 1.4344e-05 -1.4149e-03 3.9114e-03 8.7691e-05 -6.0000e+00 5.2294e-03 1.1918e-01 -1.0437e-03 12 9 8 11 8 0 94.80 21.51 1.53 0.11918 0.10936 8 2 1 4 0 4000.000 26.41 20.00 21.51 -8561 6476 -1043 -1552 13186 1899 267 -5403 4707 -4866 1305 -2187 895 -1569 -3947 -4208 7947 2078 -3161 1860 -4034 2581 -2920 -1643 972 8130 -7202 6621 -609 3861 6763 -1986 -3744 -419 2964 -4339 1137 -6456 5192 -3845 10733 -1724 7413 5391 -2832 -3244 -991 4012 4091 548 2542 2915 -11176 -4108 -4167 1721 4678 -1721 -397 4704 -4326 1906 900 -3493 2888 1208 10055 -569 8392 -1919 -1509 -11915 -59 3706 2003 -992 -1035 3957 -4633 -1954 991 3385 -134 6490 -397 -12 -271 6526 -1293 1470 1499 -4730 4403 -8007 2198 -3212 2060 2821 -84 -174 2543 3330 1082 -907 -1114 2511 941 -2271 166 5682 -2193 139 -2256 5112 -1700 -3417 1054 -2560 2021 -695 3897 -7962 2685 -3927 6798 -5585 768 -3953 -1674 2050 6052 -3364 -970 1488 7159 5682 -3906 -3630 -2857 13496 -105 1493 -7411 7967 -2951 2717 -437 -5296 1104 -8805 5823 -1041 -1606 12100 1994 289 -6239 4899 -5514 1370 -2343 918 -1633 -4193 -4509 7660 2170 -3543 2005 -4248 2550 -3058 -1707 988 7688 -7888 6224 -601 3563 5995 -1935 -3794 -422 2945 -4667 1152 -6998 4968 -4016 9725 -1786 7094 5326 -3062 -3525 -1046 3975 3972 538 2389 2683 -11799 -4093 -4258 1701 4569 -1808 -412 4647 -4689 1947 930 -3757 2886 1211 9083 -564 7509 -1885 -1470 -12915 -57 3494 1923 -972 -1000 3586 -4538 -1859 918 3076 -127 5807 -384 -11 -262 5895 -1263 1403 1443 -4901 4189 -8589 2097 -3165 1878 2493 -75 -153 2196 2914 998 -879 -1098 2388 903 -2238 160 5229 -2217 139 -2343 4978 -1785 -3674 1089 -2738 2048 -714 3773 -8608 2607 -4090 6390 -5960 769 -4151 -1715 2013 5655 -3410 -950 1420 6508 5325 -4102 -3863 -3056 12381 -111 1563 -8514 7849 -3224 2769 -452 -5651 1097 SO 20180815T110117.0Z 6801.459225 448 1 32.00 2 88.80 72.73 124.72 118.14 0.00 1 0.00 1 0 15 1.714e-02 1.706e-02 1.421e-02 1.417e-02 6.904327e+03 9.754125e+02 3.955174e+02 -6.000000e+00 9.914324e+02 281.90 -2.00 20.00 -2.00 505.39 0.00e+00 8.673448e-04 4.012796e-04 6.710320e-05 -6.000000e+00 4.894730e-04 281.90 -2.00 20.00 -2.00 500.75 0.00e+00 2.117816e+00 2.840525e-01 6.668003e-02 -6.000000e+00 3.480056e-01 226.61 -2.00 3.11 -2.00 502.32 0.00e+00 18.202 0.050 489.00 513.00 1 8.1999e+00 2.1737e-02 2.6707e-02 -6.0000e+00 2.6731e-02 3.0885e-02 5.4943e-03 1.9925e-03 -6.0000e+00 6.8682e-03 3.6712e-05 -2.4643e-03 1.5688e-03 3.4870e-05 -6.0000e+00 1.9985e-03 -4.0864e-02 2.7180e-04 12 8 8 10 0 0 -14.24 21.52 2.88 -0.04086 -0.05796 8 2 1 4 0 4000.000 26.41 20.00 21.52 -2088 -3092 2035 -39 1049 787 -1355 2904 -212 3294 -1272 -504 -3824 2086 -598 -1988 -2502 69 708 -603 36 580 2794 -555 1109 -209 267 -969 -554 -620 -1333 4067 -1156 -1035 -611 116 666 1946 -4056 1452 -2422 360 -144 3127 1881 1087 1245 -35 2515 -1955 2152 -4810 1983 -1305 313 1309 1145 -1037 351 2372 -1080 -110 -2408 2039 -499 2961 -30 4 83 1852 -1942 -2410 636 -353 1079 445 646 -3422 -406 -4168 2031 -1967 578 1106 3179 -2755 756 506 -865 -995 -1203 254 -3584 3852 155 1538 -879 -459 -1095 627 -969 1458 514 1280 -873 -60 299 -171 -709 1136 1647 -2094 1804 954 2085 -795 856 665 1802 1545 -2282 2124 -1529 -1081 -2086 2727 71 1140 -2376 -1878 -1260 -682 461 -1446 1493 113 1831 -296 -714 -884 673 -754 1803 -126 425 -714 1243 -122 -1818 -1954 -2981 1921 -39 1060 816 -1457 3012 -226 3362 -1230 -521 -3702 2061 -556 -1892 -2440 68 698 -609 37 583 2760 -570 1122 -214 269 -976 -544 -596 -1281 3744 -1150 -1057 -633 120 679 1943 -4264 1441 -2507 366 -149 3154 1932 1124 1274 -35 2452 -1945 2007 -4735 1823 -1260 305 1294 1153 -1073 359 2379 -1124 -114 -2548 2054 -511 2884 -30 3 80 1741 -1893 -2375 614 -347 1045 429 612 -3337 -382 -4069 1873 -1902 550 1058 3004 -2775 737 494 -857 -993 -1214 255 -3744 3698 152 1444 -824 -420 -992 556 -885 1339 494 1257 -889 -61 299 -171 -715 1135 1659 -2216 1853 995 2166 -856 911 708 1878 1593 -2412 2135 -1595 -1128 -2207 2757 74 1171 -2523 -1972 -1301 -693 460 -1477 1500 118 1906 -295 -726 -910 688 -787 1840 -131 436 -732 1228 -121 -1827 SO 20180815T110532.0Z 6801.462176 452 1 32.00 2 87.94 72.16 123.94 117.34 0.00 1 0.00 1 0 22 7.115e-03 7.052e-03 4.141e-03 4.130e-03 9.416737e+03 2.886395e+02 6.427626e+02 -6.000000e+00 4.114489e+02 281.90 -2.00 20.00 -2.00 505.35 0.00e+00 1.270892e-03 1.162613e-04 7.704135e-05 -6.000000e+00 2.032132e-04 281.90 -2.00 20.00 -2.00 500.82 0.00e+00 1.259422e+00 8.157844e-02 6.594177e-02 -6.000000e+00 1.446417e-01 226.61 -2.00 3.11 -2.00 502.35 0.00e+00 15.911 0.033 489.00 513.00 1 7.1952e+00 6.2441e-03 2.3248e-02 -6.0000e+00 1.1107e-02 4.6118e-04 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