File name: Pandora125s1_Cordoba_20190709_L2Fit_fwvt1c3d20170323p1-8.txt File generation date: 20250228T141513.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190709_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190709 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.0835 492.2050 492.3266 492.4481 492.5696 492.6911 492.8125 492.9340 493.0554 493.1768 493.2982 493.4196 493.5409 493.6623 493.7836 493.9049 494.0262 494.1475 494.2687 494.3900 494.5112 494.6324 494.7536 494.8748 494.9959 495.1171 495.2382 495.3593 495.4804 495.6015 495.7225 495.8436 495.9646 496.0856 496.2066 496.3276 496.4486 496.5695 496.6904 496.8113 496.9322 497.0531 497.1740 497.2948 497.4156 497.5364 497.6572 497.7780 497.8988 498.0195 498.1402 498.2609 498.3816 498.5023 498.6229 498.7436 498.8642 498.9848 499.1054 499.2260 499.3465 499.4671 499.5876 499.7081 499.8286 499.9491 500.0695 500.1900 500.3104 500.4308 500.5512 500.6715 500.7919 500.9122 501.0326 501.1529 501.2731 501.3934 501.5137 501.6339 501.7541 501.8743 501.9945 502.1147 502.2348 502.3550 502.4751 502.5952 502.7153 502.8353 502.9554 503.0754 503.1954 503.3154 503.4354 503.5554 503.6753 503.7952 503.9152 504.0351 504.1549 504.2748 504.3946 504.5145 504.6343 504.7541 504.8739 504.9936 505.1134 505.2331 505.3528 505.4725 505.5922 505.7118 505.8315 505.9511 506.0707 506.1903 506.3099 506.4294 506.5490 506.6685 506.7880 506.9075 507.0269 507.1464 507.2658 507.3853 507.5047 507.6240 507.7434 507.8628 507.9821 508.1014 508.2207 508.3400 508.4593 508.5785 508.6977 508.8170 508.9362 509.0553 509.1745 509.2936 509.4128 509.5319 509.6510 509.7701 509.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190709T112054.0Z 7129.472847 474 1 32.00 2 89.74 63.27 143.91 153.32 0.00 1 0.00 1 0 29 1.474e-01 1.659e-01 8.803e-02 8.417e-02 -3.578562e+03 5.062837e+03 3.946408e+02 -6.000000e+00 8.537666e+03 282.36 -2.00 20.00 -2.00 505.30 0.00e+00 1.857841e-02 2.310982e-03 1.188586e-03 -6.000000e+00 4.213480e-03 282.36 -2.00 20.00 -2.00 500.10 0.00e+00 5.856597e+00 1.698876e+00 1.916345e-01 -6.000000e+00 2.978276e+00 225.23 -2.00 3.11 -2.00 501.74 0.00e+00 20.152 0.067 489.00 513.00 1 8.2005e+00 1.3028e-01 4.2870e-02 -6.0000e+00 2.2897e-01 8.8558e-02 3.2357e-02 2.7484e-03 -6.0000e+00 5.8603e-02 1.6326e-05 4.1317e-02 8.3649e-03 3.9287e-04 -6.0000e+00 1.7158e-02 6.7478e-02 -1.9632e-05 12 9 8 11 8 0 84.41 21.50 3.46 0.06748 0.35407 8 2 1 4 0 4000.000 27.05 20.01 21.50 -7245 23456 8054 19425 12805 919 20586 -14675 -5173 -19643 12431 -6420 14143 -4179 9276 3116 4305 10943 6643 -10048 -5330 4322 -4373 32119 -19142 1949 -11309 3602 -2398 10680 6583 3490 -55 -3796 -5728 16599 11730 -12566 27145 -485 10045 -137 25251 3266 7324 1061 5455 10346 9667 6735 -596 17360 18395 -63011 7206 54821 -324 28188 -1439 25349 12450 12559 -2673 -13195 7211 793 14900 -12975 6821 2767 35177 3780 7418 -30 25412 991 1050 8141 937 14579 6785 14344 -11079 16129 -13460 18516 -1478 12561 -18575 14307 6320 15205 -7972 -7070 -1293 -542 -130 -11296 328 -3931 15256 -14794 6779 -11785 -9753 -26757 -2232 6518 -1664 38609 -6171 24817 -4934 10371 -6023 16235 -14625 21464 -6656 3227 15062 -1130 11973 -1272 11261 -7990 20596 -953 9809 -18117 7517 16667 12769 -11415 12782 -10283 16879 4675 -4200 12328 3236 26208 -13464 -13930 -6585 16095 10396 -2763 1177 -8691 21276 8694 18931 13343 1068 19290 -19142 -6011 -25917 11742 -7268 13041 -4668 9179 3317 4550 10829 6873 -12354 -6313 4698 -5212 26486 -23809 2089 -12356 3645 -2589 10328 6810 3793 -57 -4069 -6220 15679 10720 -14853 22011 -529 10078 -154 22210 3568 7600 1152 5548 9812 9101 6526 -630 15747 16938 -133364 7626 36165 -371 24407 -1681 22645 12576 12514 -3049 -16412 7185 828 13310 -15158 6515 2757 25382 3714 6932 -30 19209 947 996 7160 883 11922 5968 11632 -11496 12635 -14059 13996 -1371 10272 -21190 11994 5820 12851 -8437 -7288 -1226 -495 -115 -11023 284 -3566 11428 -14843 5404 -11176 -9048 -29787 -1994 5509 -1578 25205 -6446 19271 -5187 9336 -6332 13499 -16382 16667 -6861 3038 12731 -1134 10614 -1293 10137 -8730 16842 -956 8695 -20916 6663 13515 10881 -12550 11155 -11376 14267 4466 -4387 10929 3135 19991 -14988 -15221 -6561 12719 8787 -2716 1132 SO 20190709T112517.0Z 7129.475891 478 1 32.01 2 88.91 62.69 143.48 151.71 0.00 1 0.00 1 0 22 5.269e-02 6.118e-02 3.587e-02 3.548e-02 5.148896e+03 2.423750e+03 4.677970e+02 -6.000000e+00 3.051657e+03 282.36 -2.00 20.00 -2.00 505.33 0.00e+00 1.783936e-03 9.892209e-04 1.176603e-04 -6.000000e+00 1.506840e-03 282.36 -2.00 20.00 -2.00 500.29 0.00e+00 2.052576e+00 7.140969e-01 3.476633e-02 -6.000000e+00 1.068435e+00 225.23 -2.00 3.11 -2.00 501.94 0.00e+00 18.480 0.052 489.00 513.00 1 8.0683e+00 5.4751e-02 2.6833e-02 -6.0000e+00 8.2082e-02 8.7296e-02 1.3660e-02 1.6913e-03 -6.0000e+00 2.1107e-02 3.9981e-05 1.6425e-02 3.8912e-03 7.4640e-05 -6.0000e+00 6.1446e-03 -2.2627e-02 2.5774e-04 12 8 8 10 0 0 88.54 21.51 -0.78 -0.02263 0.09131 8 2 1 4 0 4000.000 27.05 20.00 21.51 5572 2198 7529 200 2914 -6628 2022 240 591 48 4038 -277 -5565 4812 7524 -640 1552 4564 4699 1077 -3675 5332 -2471 3939 -5366 -1615 390 -5055 -699 -8714 2976 2040 7736 4394 -6521 1800 -2238 1399 1951 7025 7255 -1773 -2691 5103 435 2632 -2281 963 -3579 -4302 -2984 7594 2674 -36927 3849 -1295 156 -2543 3137 4225 5046 3242 -1855 406 2131 2075 -1371 -200 4492 4516 5306 6870 1911 -82 5901 -1301 -706 -3234 2305 -7737 -480 1909 1819 3475 1336 8053 -4388 2637 -2290 133 1074 1028 4502 225 -3320 -7903 -960 940 -4872 3067 2620 4540 474 -2872 2303 -1558 -15244 -1879 -228 -7749 -2546 3122 -2795 -4933 -5712 -1334 4353 4783 4273 3304 3279 -2355 5265 -1908 9584 261 4363 3481 2807 1966 5427 1481 2917 8275 -2660 3308 128 6086 5194 5863 -3260 2876 -4193 -6322 4827 -3644 -1345 -7865 4537 5159 2167 7256 213 3084 -7833 2205 265 645 52 4134 -292 -6137 4775 7322 -687 1668 4846 5034 1201 -4309 5728 -2881 4320 -5907 -1698 432 -5286 -746 -9995 3066 2173 7994 4378 -7272 1835 -2354 1406 1944 6674 6934 -1875 -2900 5115 456 2676 -2398 959 -3639 -4299 -2896 6621 2487 -52305 3713 -1335 160 -2674 3117 4161 4941 3230 -1935 410 2080 1996 -1346 -192 4073 4081 4780 6149 1810 -79 5299 -1236 -658 -3072 2070 -7709 -447 1753 1686 3191 1258 7091 -4372 2452 -2248 129 1039 998 4186 214 -3203 -7783 -862 814 -4446 2612 2300 4038 451 -2854 2168 -1512 -16867 -1824 -220 -8170 -2581 3021 -2891 -5244 -6155 -1380 4237 4586 4060 3129 3087 -2346 4880 -1906 8550 256 4095 3287 2651 1851 4873 1372 2670 7263 -2650 3162 128 5818 5055 5706 -3493 2907 -4542 -6940 4670 -3768 -1340 -8338 4284 SO 20190709T112926.0Z 7129.478773 482 1 32.01 2 88.13 62.14 143.06 150.21 0.00 1 0.00 1 0 15 1.878e-02 1.860e-02 1.627e-02 1.620e-02 6.723287e+03 1.134969e+03 5.536967e+02 -6.000000e+00 1.087679e+03 282.36 -2.00 20.00 -2.00 505.38 0.00e+00 5.827977e-04 4.595903e-04 3.349031e-05 -6.000000e+00 5.372272e-04 282.36 -2.00 20.00 -2.00 500.53 0.00e+00 1.299888e+00 3.279158e-01 3.123640e-02 -6.000000e+00 3.812811e-01 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