File name: Pandora125s1_Cordoba_20190818_L2Fit_fwvt1c5d20170323p1-8.txt File generation date: 20250311T143028.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190818_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2356 492.3572 492.4787 492.6001 492.7216 492.8431 492.9645 493.0859 493.2073 493.3287 493.4501 493.5714 493.6927 493.8141 493.9354 494.0566 494.1779 494.2992 494.4204 494.5416 494.6628 494.7840 494.9052 495.0263 495.1474 495.2686 495.3897 495.5107 495.6318 495.7529 495.8739 495.9949 496.1159 496.2369 496.3579 496.4788 496.5997 496.7206 496.8415 496.9624 497.0833 497.2041 497.3250 497.4458 497.5666 497.6874 497.8081 497.9289 498.0496 498.1703 498.2910 498.4117 498.5323 498.6530 498.7736 498.8942 499.0148 499.1354 499.2560 499.3765 499.4970 499.6175 499.7380 499.8585 499.9790 500.0994 500.2198 500.3403 500.4606 500.5810 500.7014 500.8217 500.9420 501.0624 501.1826 501.3029 501.4232 501.5434 501.6636 501.7838 501.9040 502.0242 502.1444 502.2645 502.3846 502.5047 502.6248 502.7449 502.8649 502.9850 503.1050 503.2250 503.3450 503.4649 503.5849 503.7048 503.8247 503.9446 504.0645 504.1844 504.3042 504.4241 504.5439 504.6637 504.7835 504.9032 505.0230 505.1427 505.2624 505.3821 505.5018 505.6215 505.7411 505.8607 505.9803 506.0999 506.2195 506.3391 506.4586 506.5781 506.6976 506.8171 506.9366 507.0561 507.1755 507.2949 507.4143 507.5337 507.6531 507.7725 507.8918 508.0111 508.1304 508.2497 508.3690 508.4882 508.6074 508.7267 508.8459 508.9650 509.0842 509.2034 509.3225 509.4416 509.5607 509.6798 509.7988 509.9179 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190818T105350.0Z 7169.454051 247 1 32.01 2 89.73 74.37 68.16 277.74 0.00 1 0.00 1 0 22 3.086e-02 3.056e-02 2.105e-02 2.095e-02 6.776744e+03 1.446166e+03 5.229130e+02 -6.000000e+00 1.785067e+03 281.94 -2.00 20.00 -2.00 505.43 0.00e+00 7.640972e-04 5.953751e-04 2.543427e-05 -6.000000e+00 8.814614e-04 281.94 -2.00 20.00 -2.00 500.71 0.00e+00 1.382043e+00 4.193225e-01 3.937061e-02 -6.000000e+00 6.271545e-01 226.74 -2.00 3.11 -2.00 502.31 0.00e+00 20.127 0.067 489.00 513.00 1 8.4081e+00 3.2149e-02 2.9572e-02 -6.0000e+00 4.8163e-02 7.2677e-02 8.0122e-03 1.9303e-03 -6.0000e+00 1.2393e-02 2.4172e-05 1.1442e-03 2.3078e-03 5.2043e-05 -6.0000e+00 3.5990e-03 -3.6662e-03 -3.1752e-05 12 8 8 10 0 0 -670.85 21.38 4.83 -0.00367 0.00427 8 2 1 4 0 4000.000 26.94 20.02 21.38 -2592 3958 -5187 -1408 -1336 2356 -510 2091 -1297 247 -1438 -3457 436 -4432 1842 -3476 90 4745 1861 -1794 3970 770 422 -1188 2910 4003 1518 -217 -1517 593 4199 -1767 674 -1476 -4182 1771 -591 4668 -2300 1940 2701 -355 -1780 2330 -45 -3210 1582 -2033 2316 -7041 192 -5605 540 4983 -428 -6184 2097 5986 2415 -1875 1963 3097 2037 119 -1169 474 6601 -4753 2446 6437 1508 929 3992 -7280 1179 -3870 2139 -2768 1842 -1772 404 -2383 -1199 -4017 3340 1062 -594 2239 -2795 5443 -2545 6866 -744 7736 -3317 2922 213 2843 -4819 -2366 -981 -1424 1782 -2826 4784 -4936 2119 -3131 -3122 1684 1074 -504 2170 2988 -1638 5834 -633 2947 -1578 3303 -6844 1940 -4647 4170 -1952 5706 322 -480 -1602 -2489 418 -2951 3125 -844 187 -2977 2713 -1471 617 -2823 -1623 -906 2857 2349 -2262 2651 -526 383 -1052 -2456 3588 -5312 -1431 -1393 2417 -546 2193 -1400 260 -1519 -3676 441 -4671 1824 -3670 93 4815 1979 -1831 3843 771 426 -1222 2881 3909 1506 -215 -1489 558 3799 -1719 657 -1509 -4463 1783 -606 4494 -2356 1900 2637 -360 -1854 2351 -47 -3431 1596 -2092 2234 -7272 181 -5502 500 4490 -418 -6545 2073 5721 2396 -1942 1964 3071 2041 121 -1189 468 6038 -4811 2279 5723 1408 879 3700 -7606 1129 -3851 1975 -2655 1679 -1676 375 -2298 -1155 -4018 3129 1023 -582 2133 -2805 5063 -2589 6411 -750 7077 -3318 2678 196 2489 -4491 -2148 -892 -1341 1685 -2875 4565 -5183 2058 -3191 -3192 1659 1078 -520 2196 3019 -1744 5805 -674 3018 -1673 3288 -7443 1921 -4919 4057 -2026 5493 327 -490 -1652 -2571 414 -2992 2965 -837 186 -3115 2732 -1569 653 -3123 -1787 -996 3034 2502 -2503 2752 -554 395 -1099 SO 20190818T105811.0Z 7169.457072 251 1 32.01 2 88.84 73.79 69.07 277.15 0.00 1 0.00 1 0 15 1.293e-02 1.276e-02 1.018e-02 1.015e-02 6.621895e+03 6.891406e+02 4.161057e+02 -6.000000e+00 7.479691e+02 281.94 -2.00 20.00 -2.00 505.39 0.00e+00 9.201176e-04 2.864537e-04 5.060083e-05 -6.000000e+00 3.692263e-04 281.94 -2.00 20.00 -2.00 500.83 0.00e+00 1.801122e+00 2.021871e-01 5.836234e-02 -6.000000e+00 2.625076e-01 226.74 -2.00 3.11 -2.00 502.37 0.00e+00 18.292 0.050 489.00 513.00 1 7.8520e+00 1.5476e-02 2.6719e-02 -6.0000e+00 2.0164e-02 3.6302e-02 3.9218e-03 1.9202e-03 -6.0000e+00 5.1808e-03 5.2574e-05 -2.5233e-04 1.1282e-03 3.7232e-05 -6.0000e+00 1.5074e-03 -1.8943e-02 1.4234e-04 12 8 8 10 0 0 40.67 21.39 1.72 -0.01894 -0.02069 8 2 1 4 0 4000.000 26.94 19.98 21.39 -2995 117 -396 -59 -1746 -333 248 -503 1673 -3024 793 -1884 339 -787 742 -921 -238 -1155 -344 2415 -446 1590 -16 2402 -951 1304 -567 1037 -1445 457 -1025 673 -1094 1908 123 -796 804 299 2212 -2064 1078 -1493 1136 734 1062 203 209 569 -1176 1910 489 -126 -1364 5925 -1064 2859 150 -2569 -1330 141 -176 190 972 740 277 -982 2108 -387 164 -960 464 218 -595 -1308 1468 18 -1283 240 1248 -962 -1201 494 -2516 784 -1102 579 -1815 194 -1161 -259 990 -226 2243 1053 313 -24 911 -307 -1431 -2009 35 -615 1214 618 -748 -258 -232 695 -467 240 282 965 -1529 2308 403 2902 -1374 280 1411 1122 -90 -943 1058 -1206 1012 -714 -138 1456 730 129 -978 -303 -1279 -1990 489 -395 -1367 336 -468 2213 -903 1400 314 -352 22 -1491 -1288 -1239 -209 -2841 110 -386 -59 -1825 -351 242 -496 1607 -3012 750 -1808 315 -734 682 -870 -228 -1142 -344 2370 -452 1585 -16 2394 -983 1314 -577 1021 -1425 434 -983 643 -1093 1900 127 -828 818 303 2183 -2123 1079 -1548 1160 760 1101 212 216 576 -1187 1823 463 -119 -1301 5353 -1058 2799 153 -2708 -1387 145 -182 197 998 757 281 -996 2044 -380 158 -931 443 210 -585 -1305 1421 18 -1243 226 1161 -915 -1151 470 -2490 759 -1095 568 -1827 191 -1163 -259 987 -230 2227 1046 307 -23 845 -282 -1312 -1849 33 -585 1175 618 -768 -263 -235 694 -474 244 291 1000 -1640 2398 430 3040 -1508 301 1486 1167 -93 -985 1084 -1270 1046 -753 -144 1501 756 133 -1012 -308 -1307 -2058 501 -384 -1367 335 -478 2221 -942 1437 326 -369 22 -1542 -1308 -1242 -207 SO 20190818T110216.0Z 7169.459907 255 1 32.01 2 88.00 73.25 69.92 276.60 0.00 1 0.00 1 0 22 5.951e-03 5.897e-03 3.422e-03 3.411e-03 8.347169e+03 2.353978e+02 5.697608e+02 -6.000000e+00 3.442011e+02 281.94 -2.00 20.00 -2.00 505.39 0.00e+00 1.121049e-03 9.629310e-05 6.824428e-05 -6.000000e+00 1.699952e-04 281.94 -2.00 20.00 -2.00 500.87 0.00e+00 1.290788e+00 6.794976e-02 6.077711e-02 -6.000000e+00 1.210392e-01 226.74 -2.00 3.11 -2.00 502.39 0.00e+00 16.085 0.034 489.00 513.00 1 6.9523e+00 5.2265e-03 2.3378e-02 -6.0000e+00 9.2935e-03 2.4890e-03 1.2984e-03 1.9263e-03 -6.0000e+00 2.3944e-03 1.8100e-04 3.5678e-03 3.7440e-04 6.4099e-05 -6.0000e+00 6.9413e-04 -3.1080e-04 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