File name: Pandora125s1_Cordoba_20190820_L2Fit_fwvt1c3d20170323p1-8.txt File generation date: 20250228T141520.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190820_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.0835 492.2050 492.3266 492.4481 492.5696 492.6911 492.8125 492.9340 493.0554 493.1768 493.2982 493.4196 493.5409 493.6623 493.7836 493.9049 494.0262 494.1475 494.2687 494.3900 494.5112 494.6324 494.7536 494.8748 494.9959 495.1171 495.2382 495.3593 495.4804 495.6015 495.7225 495.8436 495.9646 496.0856 496.2066 496.3276 496.4486 496.5695 496.6904 496.8113 496.9322 497.0531 497.1740 497.2948 497.4156 497.5364 497.6572 497.7780 497.8988 498.0195 498.1402 498.2609 498.3816 498.5023 498.6229 498.7436 498.8642 498.9848 499.1054 499.2260 499.3465 499.4671 499.5876 499.7081 499.8286 499.9491 500.0695 500.1900 500.3104 500.4308 500.5512 500.6715 500.7919 500.9122 501.0326 501.1529 501.2731 501.3934 501.5137 501.6339 501.7541 501.8743 501.9945 502.1147 502.2348 502.3550 502.4751 502.5952 502.7153 502.8353 502.9554 503.0754 503.1954 503.3154 503.4354 503.5554 503.6753 503.7952 503.9152 504.0351 504.1549 504.2748 504.3946 504.5145 504.6343 504.7541 504.8739 504.9936 505.1134 505.2331 505.3528 505.4725 505.5922 505.7118 505.8315 505.9511 506.0707 506.1903 506.3099 506.4294 506.5490 506.6685 506.7880 506.9075 507.0269 507.1464 507.2658 507.3853 507.5047 507.6240 507.7434 507.8628 507.9821 508.1014 508.2207 508.3400 508.4593 508.5785 508.6977 508.8170 508.9362 509.0553 509.1745 509.2936 509.4128 509.5319 509.6510 509.7701 509.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190820T105140.0Z 7171.452546 249 1 32.01 2 89.73 75.14 56.90 299.96 0.00 1 0.00 1 0 15 2.339e-01 1.780e-01 1.871e-01 1.684e-01 1.376592e+04 1.296026e+04 1.397498e+03 -6.000000e+00 1.359128e+04 281.99 -2.00 20.00 -2.00 505.33 0.00e+00 3.146986e-03 4.748187e-03 1.347455e-04 -6.000000e+00 6.713024e-03 281.99 -2.00 20.00 -2.00 500.07 0.00e+00 -2.533783e+00 3.489003e+00 3.315694e-02 -6.000000e+00 4.793151e+00 226.83 -2.00 3.11 -2.00 501.77 0.00e+00 20.123 0.067 489.00 513.00 1 9.7124e+00 2.6592e-01 2.9608e-02 -6.0000e+00 3.6693e-01 2.0244e-01 6.8259e-02 1.9971e-03 -6.0000e+00 9.5160e-02 7.8815e-06 -2.6190e-03 1.7728e-02 1.4739e-04 -6.0000e+00 2.7252e-02 -8.8555e-02 2.3766e-04 12 9 8 11 8 0 89.18 21.47 13.28 -0.08855 -0.10672 8 2 1 4 0 4000.000 27.05 20.01 21.47 -6454 998 -7956 3199 28324 -6269 15932 -14089 23214 -20322 517 -16920 -1392 21243 84717 7584 62619 -1027 -9207 -1635 248 404 1818 36230 -212 -17730 -20325 822 29334 13435 -12102 11126 -13424 -9613 14503 -2256 2843 4738 18515 26145 -3474 5169 22824 -17076 4340 -13455 1849 2117 -4674 12353 9889 17276 -7393 25530 -12314 59675 14309 -16498 13138 29212 69107 -20562 3103 -5770 -27020 2550 25101 -6742 14375 -2510 -3124 43687 419 27941 900000 1480 -5188 1411 -3813 43187 5581 50383 -15796 35092 11787 27330 8043 -24592 -21675 7461 22196 28299 28780 14759 24298 -15091 41710 -19917 61804 6640 8471 -23654 19272 -493 14441 8154 -2997 10534 -5133 -22447 28195 23982 -10673 30272 -22215 44595 5502 -11616 4142 -15697 -4410 -3558 33420 2117 -7089 -17843 -370 17330 32868 -10895 10245 -11042 62249 51470 2822 -7240 -253 -5643 -16788 -27815 -5286 61909 13484 1629 34829 24377 652 -9271 6486 -7065 1018 -9068 3358 23786 -7615 15769 -19015 21583 -28951 590 -22583 -1566 18795 39383 7620 36623 -1155 -11459 -1912 287 467 2072 29339 -248 -22667 -26543 937 24634 12894 -14700 10678 -15316 -10836 14354 -2450 2931 4755 16035 20846 -3725 5116 19139 -21596 4475 -16647 1957 2211 -5140 11207 8972 14249 -7724 19302 -13880 33633 12982 -20638 12281 23291 37049 -27135 3242 -6584 -37885 2629 20358 -7415 12647 -2587 -3221 28225 420 21509 900000 1485 -5491 1377 -3879 27309 5140 29781 -18239 24602 10532 21039 7519 -31776 -27114 6974 18002 21785 22155 12984 19039 -17011 25801 -22177 29735 5477 6870 -26988 14835 -481 12507 7622 -3131 9557 -5433 -28388 21704 19451 -12325 23304 -29011 30038 5521 -13892 4214 -19205 -4729 -3717 23889 2066 -7601 -21339 -372 14532 23494 -11981 9014 -11840 31661 29009 2599 -7465 -247 -5895 -19847 -37088 -5668 34041 12049 1635 24896 19101 636 -9813 5795 SO 20190820T105602.0Z 7171.455579 253 1 32.01 2 88.83 74.57 57.70 299.12 0.00 1 0.00 1 0 50 1.719e-01 1.497e-01 1.184e-01 1.114e-01 2.461607e+03 7.486249e+03 5.094924e+01 -6.000000e+00 9.946189e+03 281.99 -2.00 20.00 -2.00 505.36 0.00e+00 1.711457e-03 3.188246e-03 3.124033e-05 -6.000000e+00 4.915795e-03 281.99 -2.00 20.00 -2.00 500.12 0.00e+00 5.463367e+00 2.301629e+00 4.793483e-02 -6.000000e+00 3.505837e+00 226.83 -2.00 3.11 -2.00 501.82 0.00e+00 18.271 0.050 489.00 513.00 1 9.0105e+00 1.7824e-01 2.6457e-02 -6.0000e+00 2.6904e-01 2.6639e-02 4.2357e-02 1.6701e-03 -6.0000e+00 6.9552e-02 1.2148e-05 4.8612e-02 1.2626e-02 2.1899e-05 -6.0000e+00 2.0048e-02 -6.9213e-02 2.4060e-04 12 9 8 11 8 0 98.98 21.48 1.34 -0.06921 0.26798 8 2 1 4 0 4000.000 27.05 20.02 21.48 3324 12388 7870 1433 -13029 43004 -19310 25207 -3762 7809 -11963 7196 20153 -14100 -2078 7357 -3379 -1757 286 -30486 11703 -5145 21137 -13070 35195 -6910 32035 15 9395 2524 24194 20191 -7191 21139 -6662 11348 2433 21648 -7920 12979 -5198 4712 -5016 7019 7551 -7116 6951 -6423 -772 -14784 468 -12309 3032 1378 44704 -15945 -8407 -9238 6189 22080 -14807 8645 -1899 12416 -20476 28438 11247 -5134 2256 23234 -18096 8864 21151 29375 7004 829 10750 -20160 24066 -20761 15836 -11120 19259 -10540 10417 -6249 19536 11336 16702 -7899 -10467 17572 -14146 10186 -10078 34413 -5110 3068 -4602 -1870 -21056 9599 4675 61886 30480 -14598 -10462 -6426 18141 -10353 18405 -14118 50480 8882 16980 13138 -11776 -11324 -2535 2069 -14104 4033 -1170 32130 22579 29736 -1087 19381 8632 12863 -13744 9100 -8847 29568 -11489 2735 39203 -7063 -3901 -17743 19994 10884 1747 -26437 -1509 -4967 622 12301 18991 3363 11797 8040 1592 -16931 31992 -26624 22003 -4329 7901 -14596 7209 17792 -17762 -2371 7808 -4056 -2091 335 -44629 12305 -6430 20338 -16162 28976 -7791 26056 15 9412 2525 21839 17808 -8435 18645 -7693 10835 2522 18502 -9145 12273 -5955 4927 -5792 7148 7553 -8088 6700 -6891 -765 -16669 455 -13878 3005 1416 30080 -19717 -9632 -10668 6134 18671 -18041 8254 -1986 11064 -24948 20945 9715 -5182 2113 17746 -21061 7899 16540 20834 6114 761 8895 -22730 17506 -23786 12671 -11729 15060 -11117 8904 -6307 15277 9689 13668 -8331 -11325 14220 -15435 8521 -10080 21591 -4693 2594 -4268 -1734 -24314 8292 4251 31512 21063 -15796 -10939 -6544 14680 -11296 15229 -16303 30753 8238 14513 11588 -13170 -12459 -2535 1975 -15902 3814 -1170 23079 17861 21901 -1087 15684 7692 10877 -15121 8026 -9492 22045 -13163 2761 27804 -8027 -4328 -22748 17634 10490 1826 -36057 -1578 -5329 634 11297 16577 SO 20190820T110013.0Z 7171.458484 257 1 32.01 2 87.97 74.01 58.47 298.33 0.00 1 0.00 1 0 22 1.009e-01 9.417e-02 8.054e-02 7.815e-02 1.873685e+04 6.407288e+03 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