File name: Pandora125s1_Cordoba_20190903_L2Fit_fwvt1c3d20170323p1-8.txt File generation date: 20250228T141459.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190903_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190903 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.0835 492.2050 492.3266 492.4481 492.5696 492.6911 492.8125 492.9340 493.0554 493.1768 493.2982 493.4196 493.5409 493.6623 493.7836 493.9049 494.0262 494.1475 494.2687 494.3900 494.5112 494.6324 494.7536 494.8748 494.9959 495.1171 495.2382 495.3593 495.4804 495.6015 495.7225 495.8436 495.9646 496.0856 496.2066 496.3276 496.4486 496.5695 496.6904 496.8113 496.9322 497.0531 497.1740 497.2948 497.4156 497.5364 497.6572 497.7780 497.8988 498.0195 498.1402 498.2609 498.3816 498.5023 498.6229 498.7436 498.8642 498.9848 499.1054 499.2260 499.3465 499.4671 499.5876 499.7081 499.8286 499.9491 500.0695 500.1900 500.3104 500.4308 500.5512 500.6715 500.7919 500.9122 501.0326 501.1529 501.2731 501.3934 501.5137 501.6339 501.7541 501.8743 501.9945 502.1147 502.2348 502.3550 502.4751 502.5952 502.7153 502.8353 502.9554 503.0754 503.1954 503.3154 503.4354 503.5554 503.6753 503.7952 503.9152 504.0351 504.1549 504.2748 504.3946 504.5145 504.6343 504.7541 504.8739 504.9936 505.1134 505.2331 505.3528 505.4725 505.5922 505.7118 505.8315 505.9511 506.0707 506.1903 506.3099 506.4294 506.5490 506.6685 506.7880 506.9075 507.0269 507.1464 507.2658 507.3853 507.5047 507.6240 507.7434 507.8628 507.9821 508.1014 508.2207 508.3400 508.4593 508.5785 508.6977 508.8170 508.9362 509.0553 509.1745 509.2936 509.4128 509.5319 509.6510 509.7701 509.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190903T103509.0Z 7185.441076 427 1 32.01 2 89.72 80.92 123.97 128.83 0.00 1 0.00 1 0 78 2.478e-01 2.009e-01 1.596e-01 1.398e-01 -1.100932e+04 9.310097e+03 1.255393e+03 -6.000000e+00 1.434895e+04 282.29 -2.00 20.00 -2.00 505.33 0.00e+00 1.840113e-02 3.974364e-03 1.238705e-03 -6.000000e+00 7.111210e-03 282.29 -2.00 20.00 -2.00 499.75 0.00e+00 1.865188e+01 3.061626e+00 3.312187e-01 -6.000000e+00 5.100644e+00 227.44 -2.00 3.11 -2.00 501.34 0.00e+00 20.100 0.067 489.00 513.00 1 7.7957e+00 2.2818e-01 4.8042e-02 -6.0000e+00 3.9039e-01 -1.5730e-01 6.1491e-02 4.3169e-03 -6.0000e+00 1.0266e-01 9.4509e-06 -4.1309e-02 1.2457e-02 4.5325e-04 -6.0000e+00 2.8903e-02 1.4187e-01 -1.7150e-03 12 8 8 10 0 0 99.24 21.33 10.55 0.14187 -0.14466 8 2 1 4 0 4000.000 26.94 20.02 21.33 900000 7725 3371 9075 25145 -15597 17835 21024 9787 -20237 -5084 6934 38090 49433 6602 51713 -1499 8454 7557 20161 -9287 9519 -10711 12005 2225 20615 1058 28431 16620 19064 2230 -8873 47935 -32824 22203 24129 24192 894 15924 -30681 5904 20495 19543 6880 9769 19729 -26823 -13091 -10829 5115 -13951 -23662 -26737 98775 -19140 -12863 -19115 2495 -17338 -3347 -12376 -18061 16866 -8252 23759 5595 31480 34050 25300 -16231 9702 7522 23206 46624 12450 31810 -5801 17706 18921 22623 -2003 65782 27356 5850 -7485 35123 30532 11846 3667 -29920 -6365 12512 11061 -32467 59174 -355 4480 4704 16171 47615 -247 -5828 -17359 34668 -16644 13109 -28139 -6757 -36887 816 -17938 8713 -1226 -28623 -10897 11792 29298 1060 14067 -23130 61182 10940 25228 -6278 83343 21433 7758 3086 21759 2118 -3607 35730 10873 7138 -5051 6386 -16190 24581 -27478 -4484 -14543 16336 2015 34301 13486 9639 39588 14138 45276 900000 7598 3357 8474 20349 -19613 16654 19632 10479 -29732 -6457 7770 30825 35081 7068 34767 -1699 8631 7809 18575 -11678 10073 -14003 12555 2577 20020 1159 26194 17382 19463 2443 -10633 34615 -47950 20456 20378 20983 1000 15448 -47270 6266 18713 18066 7303 10257 19139 -42246 -18228 -14831 5955 -19425 -35647 -40584 41710 -25777 -16149 -25743 2762 -23943 -4087 -16668 -25766 16939 -10642 22235 6258 26946 27980 22233 -21118 9523 7383 19069 29798 11083 23235 -6157 14751 15332 17299 -1920 31532 19044 5007 -7261 22047 19862 9193 3055 -34489 -5739 9282 8331 -38165 28364 -316 3885 4134 12734 27171 -223 -5387 -17434 20179 -15956 9276 -29866 -5706 -41257 615 -16173 6066 -966 -30707 -10198 9152 19728 967 11399 -27190 30724 8989 17851 -6090 33291 16144 6817 2888 17135 2055 -3746 25283 9928 6761 -5361 5977 -18847 19076 -36378 -4811 -17594 14728 2116 26229 12774 9571 29367 13553 31520 SO 20190903T103930.0Z 7185.444097 431 1 32.01 2 88.80 80.35 123.27 127.93 0.00 1 0.00 1 0 28 1.421e-01 1.206e-01 1.112e-01 1.061e-01 7.849832e+03 7.686189e+03 1.987681e+02 -6.000000e+00 8.242526e+03 282.29 -2.00 20.00 -2.00 505.28 0.00e+00 -1.115198e-03 2.998464e-03 1.349295e-04 -6.000000e+00 4.106486e-03 282.29 -2.00 20.00 -2.00 500.23 0.00e+00 1.872922e+00 2.199904e+00 1.960637e-01 -6.000000e+00 2.878920e+00 227.44 -2.00 3.11 -2.00 501.89 0.00e+00 18.200 0.050 489.00 513.00 1 9.2819e+00 1.6953e-01 3.0095e-02 -6.0000e+00 2.2210e-01 9.3217e-02 4.1908e-02 3.3189e-03 -6.0000e+00 5.6483e-02 1.2562e-05 -4.0993e-03 1.1486e-02 1.2213e-04 -6.0000e+00 1.6837e-02 -1.1794e-01 2.1357e-03 12 8 8 10 0 0 46.75 21.35 -0.99 -0.11794 -0.14638 8 2 1 4 0 4000.000 26.94 20.01 21.35 2412 -8930 11263 2569 5469 4189 2067 6856 -14375 12830 17515 5627 4009 -4646 -10005 18982 18 -16475 -4563 9049 -13602 5131 12402 17057 -1661 9018 -12289 10218 -5753 17890 -7067 1323 -8903 -1440 -2281 -1536 17705 11094 10757 -2808 15479 -10495 14181 -1978 -8648 23472 -15378 -4727 17612 1481 8817 18599 -1157 900000 -1758 -1468 -12206 2165 5657 -4324 14348 -11438 -12964 -7314 -10453 -6269 11688 33163 -5910 -16470 12804 -11555 14288 23452 631 -1844 -1087 21227 -1423 10943 -6233 -13516 -5878 -752 -9792 7015 39676 -1104 -2278 14506 6096 -20695 -16540 -5229 -4430 1527 16766 -1538 1915 -4622 -6503 38153 -15884 -1237 1877 1056 -16693 26523 -4197 16380 6378 -4466 210 27281 10401 18410 7168 1357 8962 -13046 -4567 -11858 -1555 23384 15779 25476 -6926 2209 57685 14836 -2771 4545 -6490 -6530 -7102 6060 30344 27015 15428 -17670 -5335 -10597 6009 48609 -11482 -58 -3504 -8983 900000 2369 -10123 10747 2742 5787 4550 2304 7254 -18604 12484 16050 5741 4128 -5223 -12003 17394 20 -22412 -5560 9660 -18247 5719 12888 16920 -1977 9542 -14473 10232 -6630 16225 -8345 1474 -10331 -1571 -2509 -1663 15638 10376 10061 -3015 13940 -12360 13140 -2159 -10036 19512 -18510 -4994 14489 1398 7636 14657 -1132 900000 -1811 -1525 -14164 2175 5487 -4643 12798 -13173 -15043 -7917 -11496 -6514 10020 22687 -5937 -18398 10755 -12508 12002 17871 596 -1757 -1016 15808 -1331 9097 -6207 -14630 -5955 -729 -10430 6318 25768 -1080 -2269 12310 5648 -24910 -18763 -5162 -4219 1335 12341 -1345 1626 -4282 -6363 24779 -18157 -1231 1804 1015 -19081 19752 -4289 13759 5965 -4680 211 21025 9547 15623 6766 1340 8071 -14461 -4627 -12938 -1535 18022 13117 19193 -7197 2085 30971 12076 -2663 4054 -6519 -6673 -7441 5668 22598 21055 13627 -21882 -5867 -12296 5880 30729 -13026 -58 -3580 -9724 900000 SO 20190903T104343.0Z 7185.447026 435 1 32.01 2 87.92 79.79 122.57 127.08 0.00 1 0.00 1 0 15 5.994e-02 5.955e-02 5.153e-02 5.071e-02 1.317293e+03 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