File name: Pandora125s1_Cordoba_20190930_L2Fit_fwvt1c3d20170323p1-8.txt File generation date: 20250228T141521.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190930_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190930 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.0835 492.2050 492.3266 492.4481 492.5696 492.6911 492.8125 492.9340 493.0554 493.1768 493.2982 493.4196 493.5409 493.6623 493.7836 493.9049 494.0262 494.1475 494.2687 494.3900 494.5112 494.6324 494.7536 494.8748 494.9959 495.1171 495.2382 495.3593 495.4804 495.6015 495.7225 495.8436 495.9646 496.0856 496.2066 496.3276 496.4486 496.5695 496.6904 496.8113 496.9322 497.0531 497.1740 497.2948 497.4156 497.5364 497.6572 497.7780 497.8988 498.0195 498.1402 498.2609 498.3816 498.5023 498.6229 498.7436 498.8642 498.9848 499.1054 499.2260 499.3465 499.4671 499.5876 499.7081 499.8286 499.9491 500.0695 500.1900 500.3104 500.4308 500.5512 500.6715 500.7919 500.9122 501.0326 501.1529 501.2731 501.3934 501.5137 501.6339 501.7541 501.8743 501.9945 502.1147 502.2348 502.3550 502.4751 502.5952 502.7153 502.8353 502.9554 503.0754 503.1954 503.3154 503.4354 503.5554 503.6753 503.7952 503.9152 504.0351 504.1549 504.2748 504.3946 504.5145 504.6343 504.7541 504.8739 504.9936 505.1134 505.2331 505.3528 505.4725 505.5922 505.7118 505.8315 505.9511 506.0707 506.1903 506.3099 506.4294 506.5490 506.6685 506.7880 506.9075 507.0269 507.1464 507.2658 507.3853 507.5047 507.6240 507.7434 507.8628 507.9821 508.1014 508.2207 508.3400 508.4593 508.5785 508.6977 508.8170 508.9362 509.0553 509.1745 509.2936 509.4128 509.5319 509.6510 509.7701 509.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190930T100008.1Z 7212.416760 398 1 32.13 2 89.72 93.07 107.78 109.65 0.00 1 0.00 1 0 15 7.383e-02 7.050e-02 4.643e-02 4.568e-02 5.347823e+03 3.182292e+03 4.901067e+02 -6.000000e+00 4.291133e+03 283.20 -2.00 20.00 -2.00 505.36 0.00e+00 9.022310e-04 1.289461e-03 2.752116e-05 -6.000000e+00 2.115488e-03 283.20 -2.00 20.00 -2.00 500.26 0.00e+00 2.075770e+00 9.373991e-01 1.698828e-02 -6.000000e+00 1.504997e+00 228.28 -2.00 3.11 -2.00 501.93 0.00e+00 20.071 0.067 489.00 513.00 1 8.1486e+00 7.2052e-02 2.9286e-02 -6.0000e+00 1.1556e-01 9.9188e-02 1.7955e-02 1.7290e-03 -6.0000e+00 2.9825e-02 2.9893e-05 5.3380e-03 5.0603e-03 5.0621e-05 -6.0000e+00 8.6133e-03 8.7992e-02 -5.8864e-04 12 8 8 10 0 0 76.60 21.17 6.61 0.08799 0.12502 8 2 1 4 0 4000.000 26.73 20.01 21.17 -5827 -1218 -7131 1967 -5661 -3702 -11629 5338 656 20783 -2649 6402 -2585 2107 -925 -4344 1743 -6915 5624 -7447 8763 -12391 8880 -6571 9738 -1386 787 -4281 4424 2463 -2529 9097 6841 10159 -9252 9979 5730 1365 930 6385 6774 5697 56 904 894 -8647 3425 -7148 4750 -10996 -8076 5346 2304 36326 7471 -3339 -4539 -3419 -178 -1963 1167 3947 2673 8937 -9527 6173 -9140 -2478 -4010 4261 -267 1952 3313 6328 3483 3385 220 -6737 6452 596 -2540 2214 3111 782 -4296 4628 3448 2608 -351 8746 4754 -1815 -4785 14114 -2320 13249 -2146 3207 -3778 -652 394 -14161 9168 -3353 3723 -2456 -1028 -15155 8938 -5714 7141 -10962 177 -2839 14561 5379 11114 11439 5066 -963 -1808 11268 -4462 -1872 -16510 1546 -5597 12329 -1668 -4290 -2487 11911 2790 -4299 4499 -5228 10621 -781 7664 -1576 10423 -12799 8050 3654 -3364 -4560 -3130 -2945 -6343 -5974 -1219 -7804 2025 -6449 -4217 -14524 5646 723 18517 -2942 6407 -2798 2160 -978 -4807 1851 -8186 5971 -9089 9126 -14648 9285 -8047 10142 -1473 810 -4550 4590 2555 -2747 8919 7041 10373 -10661 9490 5641 1389 943 6119 6493 5567 58 944 937 -9932 3449 -7864 4535 -11974 -8343 4765 2123 24249 6826 -3474 -4841 -3622 -183 -2050 1184 3901 2672 8332 -10552 5756 -9783 -2449 -3978 3862 -253 1819 3076 5735 3234 3106 206 -6658 5558 544 -2406 2015 2831 735 -4277 4228 3189 2431 -338 7731 4414 -1814 -4925 11895 -2258 10771 -1985 2751 -3424 -572 347 -14840 7864 -3338 3484 -2436 -997 -16842 7833 -5860 6525 -12142 177 -2943 12761 5196 10155 10366 4837 -963 -1800 9792 -4543 -1864 -19087 1493 -5803 10667 -1655 -4335 -2439 9995 2549 -4233 4110 -5361 9466 -792 7231 -1646 9718 -15131 7745 3665 -3588 -4846 -3222 -2988 -6647 SO 20190930T100425.0Z 7212.419734 402 1 32.01 2 88.80 92.51 106.94 109.03 0.00 1 0.00 1 0 15 5.098e-02 3.678e-02 1.936e-02 1.919e-02 4.410668e+03 1.297186e+03 2.864451e+02 -6.000000e+00 2.964222e+03 283.20 -2.00 20.00 -2.00 505.34 0.00e+00 6.809196e-04 5.430332e-04 3.667900e-05 -6.000000e+00 1.460313e-03 283.20 -2.00 20.00 -2.00 500.33 0.00e+00 1.615119e+00 3.933480e-01 4.338122e-02 -6.000000e+00 1.036696e+00 228.28 -2.00 3.11 -2.00 501.99 0.00e+00 18.184 0.049 489.00 513.00 1 7.5447e+00 3.0268e-02 2.6305e-02 -6.0000e+00 7.9648e-02 9.6229e-02 7.5969e-03 1.6973e-03 -6.0000e+00 2.0474e-02 7.4105e-05 -5.3325e-03 2.1429e-03 2.1469e-05 -6.0000e+00 5.9454e-03 1.0044e-02 1.1021e-04 12 8 8 10 0 0 -58.83 21.17 6.18 0.01004 -0.02694 8 2 1 4 0 4000.000 26.73 20.00 21.17 -1533 -4977 -1370 -1930 128 -2982 2638 1189 5283 669 1036 590 -1505 -867 -3093 1756 -180 2985 703 190 842 1668 -3886 -2120 -3616 291 1651 -334 1113 -3398 -274 -2938 50 293 837 1230 5002 1696 -2163 4160 52 118 -3408 8152 -1008 2358 -1012 1752 -2008 1765 -2698 -314 -3514 53053 -991 -4314 2474 1305 2057 -1349 -1193 -3491 2929 2480 667 -139 2164 -3991 -3948 -1515 -5420 149 -727 -1025 -4308 5704 -3020 306 422 -1078 -1047 -27 -1486 -3317 -545 -3725 794 150 2759 606 3794 35 4826 -314 2790 1740 -2535 73 -2941 -221 -2743 -688 9 -701 -3139 -198 1552 -2577 -178 -627 -151 1425 1457 -1854 5496 -2558 4683 905 4829 3412 3537 -2553 2323 511 1299 453 -2615 2659 -1470 2777 -4582 535 -3348 4319 -1120 3055 -1116 -2143 215 545 -137 -2444 762 -1983 2674 -2236 -840 -1640 -828 -1503 -5128 -1400 -2044 136 -3352 2849 1313 5587 734 1117 630 -1620 -918 -3340 1818 -194 3172 779 214 948 1867 -4224 -2271 -3942 304 1691 -344 1204 -3756 -291 -2949 50 300 866 1276 4967 1724 -2263 4066 53 121 -3656 7866 -1072 2423 -1066 1770 -2063 1703 -2653 -296 -3407 32271 -972 -4479 2441 1312 2055 -1394 -1233 -3701 2913 2467 668 -138 2075 -4014 -3921 -1455 -5390 141 -699 -997 -4332 5137 -2923 283 386 -1001 -976 -25 -1413 -3241 -523 -3705 756 143 2580 582 3559 34 4543 -309 2622 1616 -2399 65 -2681 -194 -2496 -629 8 -679 -3161 -194 1478 -2539 -172 -611 -148 1395 1440 -1907 5285 -2680 4577 916 4652 3287 3357 -2556 2213 497 1258 443 -2633 2536 -1458 2622 -4608 504 -3251 3883 -1074 2857 -1108 -2185 217 553 -141 -2588 784 -2096 2680 -2322 -844 -1636 -814 SO 20190930T100830.0Z 7212.422570 406 1 32.01 2 87.94 91.98 106.14 108.46 0.00 1 0.00 1 0 29 1.730e-02 1.723e-02 6.850e-03 6.838e-03 3.511810e+03 4.385879e+02 1.389962e+02 -6.000000e+00 1.005786e+03 283.20 -2.00 20.00 -2.00 505.36 0.00e+00 2.534406e-03 1.940987e-04 1.130451e-04 -6.000000e+00 4.956404e-04 283.20 -2.00 20.00 -2.00 500.70 0.00e+00 9.635777e-01 1.369029e-01 5.170117e-02 -6.000000e+00 3.522207e-01 228.28 -2.00 3.11 -2.00 502.28 0.00e+00 15.888 0.033 489.00 513.00 1 6.7624e+00 1.0487e-02 2.2970e-02 -6.0000e+00 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