File name: Pandora125s1_Cordoba_20191016_L2Fit_fwvt1c3d20170323p1-8.txt File generation date: 20250228T141508.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20191016_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20191016 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.0835 492.2050 492.3266 492.4481 492.5696 492.6911 492.8125 492.9340 493.0554 493.1768 493.2982 493.4196 493.5409 493.6623 493.7836 493.9049 494.0262 494.1475 494.2687 494.3900 494.5112 494.6324 494.7536 494.8748 494.9959 495.1171 495.2382 495.3593 495.4804 495.6015 495.7225 495.8436 495.9646 496.0856 496.2066 496.3276 496.4486 496.5695 496.6904 496.8113 496.9322 497.0531 497.1740 497.2948 497.4156 497.5364 497.6572 497.7780 497.8988 498.0195 498.1402 498.2609 498.3816 498.5023 498.6229 498.7436 498.8642 498.9848 499.1054 499.2260 499.3465 499.4671 499.5876 499.7081 499.8286 499.9491 500.0695 500.1900 500.3104 500.4308 500.5512 500.6715 500.7919 500.9122 501.0326 501.1529 501.2731 501.3934 501.5137 501.6339 501.7541 501.8743 501.9945 502.1147 502.2348 502.3550 502.4751 502.5952 502.7153 502.8353 502.9554 503.0754 503.1954 503.3154 503.4354 503.5554 503.6753 503.7952 503.9152 504.0351 504.1549 504.2748 504.3946 504.5145 504.6343 504.7541 504.8739 504.9936 505.1134 505.2331 505.3528 505.4725 505.5922 505.7118 505.8315 505.9511 506.0707 506.1903 506.3099 506.4294 506.5490 506.6685 506.7880 506.9075 507.0269 507.1464 507.2658 507.3853 507.5047 507.6240 507.7434 507.8628 507.9821 508.1014 508.2207 508.3400 508.4593 508.5785 508.6977 508.8170 508.9362 509.0553 509.1745 509.2936 509.4128 509.5319 509.6510 509.7701 509.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191016T094027.0Z 7228.403090 218 1 32.01 2 89.72 100.24 71.54 301.65 0.00 1 0.00 1 0 22 1.449e-01 1.295e-01 1.274e-01 1.217e-01 -1.437110e+03 7.594266e+03 6.815800e+02 -6.000000e+00 8.448826e+03 283.89 -2.00 20.00 -2.00 505.17 0.00e+00 9.626370e-03 3.446468e-03 5.668975e-04 -6.000000e+00 4.167286e-03 283.89 -2.00 20.00 -2.00 499.94 0.00e+00 4.017956e+00 2.529892e+00 1.351100e-01 -6.000000e+00 2.965314e+00 228.61 -2.00 3.11 -2.00 501.56 0.00e+00 20.065 0.067 489.00 513.00 1 8.8963e+00 1.9510e-01 3.3563e-02 -6.0000e+00 2.2756e-01 1.1035e-01 4.8859e-02 2.1769e-03 -6.0000e+00 5.9018e-02 1.0798e-05 1.3535e-02 1.3291e-02 2.6673e-04 -6.0000e+00 1.6878e-02 -5.1936e-02 -8.7130e-05 12 8 8 10 0 0 96.60 21.32 3.22 -0.05194 0.04195 8 2 1 4 0 4000.000 26.94 19.98 21.32 -9312 1977 -103 -12901 16098 1397 10373 -9186 -6655 2863 30483 11879 -11433 -7860 10295 24137 1762 -1391 -87 -10431 9711 41900 -562 24575 18104 2449 -1272 -4051 22154 -15143 33788 5437 -1249 -7117 5637 -6514 111 -8074 23510 -962 -2820 -8526 -16827 -2153 -502 10895 -3183 -9045 14830 13517 -17460 -19544 -11554 -404 1175 -7580 42039 -4777 750 -4567 10824 19515 -5190 1254 -2858 11185 -5331 -8703 9713 15403 2721 -13372 -1569 10248 15377 27813 12318 9916 -10756 2200 -975 -7942 -3764 -12401 7180 -22381 17363 5135 7493 482 -15670 -5699 18246 -22826 -9735 -1500 -2616 36483 1200 14226 -16841 -10781 -4085 17729 -17357 4088 -4700 17681 6116 -6174 4720 5928 427 5946 9982 9172 16778 -1361 -19841 -753 20105 15168 20640 -3252 24422 10256 -7070 35897 2705 28055 20235 274 -18189 5491 18243 33242 -3326 4015 -21028 14037 26522 20525 4937 19202 -15350 -8207 -5511 -14651 -11072 -10399 2015 -111 -16227 15535 1590 10910 -11753 -8227 3167 25120 11592 -13884 -9119 9935 20414 1891 -1568 -98 -13121 10004 31348 -646 22117 17471 2761 -1476 -4744 19457 -18883 25645 5541 -1394 -7923 6112 -7317 116 -9068 20903 -1004 -3027 -9831 -21408 -2397 -554 10721 -3575 -10609 13414 12092 -20825 -23505 -12862 -410 1203 -8664 29667 -5413 805 -5175 10543 17457 -5932 1334 -3124 10450 -5776 -9601 8786 13014 2596 -15019 -1575 9167 12991 20457 10407 8476 -11225 2011 -921 -8052 -3667 -13189 6280 -26249 13634 4543 6479 451 -17444 -5834 14871 -28132 -10451 -1461 -2522 23208 1061 10888 -17576 -10716 -3858 13569 -18804 3535 -4391 13180 5167 -6014 4222 5362 416 5555 9029 8387 14175 -1366 -23665 -733 15787 12514 16207 -3265 18691 9072 -7449 24619 2581 20635 15889 258 -20429 4857 14325 22798 -3339 3791 -25707 12138 20298 16729 4711 15841 -17698 -8646 -5533 -15873 -11555 SO 20191016T094444.0Z 7228.406065 222 1 32.00 2 88.82 99.68 72.31 300.95 0.00 1 0.00 1 0 15 9.552e-02 9.159e-02 7.979e-02 7.754e-02 5.287033e+03 5.528718e+03 1.105835e+03 -6.000000e+00 5.567805e+03 283.89 -2.00 20.00 -2.00 505.33 0.00e+00 1.723678e-03 2.212120e-03 1.048418e-04 -6.000000e+00 2.740052e-03 283.89 -2.00 20.00 -2.00 499.91 0.00e+00 2.477021e+00 1.637338e+00 1.255434e-01 -6.000000e+00 1.941943e+00 228.61 -2.00 3.11 -2.00 501.63 0.00e+00 18.220 0.050 489.00 513.00 1 8.9139e+00 1.2637e-01 2.7559e-02 -6.0000e+00 1.4923e-01 1.1641e-01 3.1935e-02 1.7796e-03 -6.0000e+00 3.8358e-02 1.7157e-05 2.5261e-03 8.4887e-03 1.7183e-04 -6.0000e+00 1.1138e-02 5.5124e-02 -1.6485e-04 12 9 8 11 8 0 -747.65 21.31 2.73 0.05512 0.07265 8 2 1 4 0 4000.000 26.94 19.99 21.31 17974 -6713 5383 7595 973 11183 -3191 -2997 -1950 9846 21902 6251 -17951 13276 -2061 5423 12073 5541 16384 -13912 -11584 -2097 5307 -1515 10105 10283 7208 252 -14231 15125 -2697 -7256 2558 -7929 -9970 -9032 -909 -2557 -3347 -4110 -8226 5676 -65 1325 -1926 4754 -5304 1730 11134 9887 -15620 5569 -1503 -17977 18252 -16112 14843 34 -627 20904 22595 13914 17207 -4471 -2845 2427 -7859 -1197 -13413 12056 -768 -853 -11193 -257 453 1007 -6519 -4448 377 6063 6448 6346 -1945 -5113 1367 175 10679 20743 -3236 -3948 6376 -383 24605 7129 1490 16255 -7624 -5108 14151 -6118 -342 -2480 -2116 11436 6894 6344 12143 -5873 -12886 16414 -8622 -552 -6041 -4804 -14776 9409 -1846 2682 -9257 -5867 746 -8152 22222 -1244 -4247 1728 -11129 -1262 -4916 -3185 -3142 1112 -8857 278 -4480 -38 9403 -3436 3523 10546 -4703 9434 -397 14977 13194 -2202 -4023 16125 17707 15267 -7463 5465 7762 1088 11506 -3834 -3601 -2303 10199 19814 6518 -23554 12653 -2291 5655 12006 6007 16180 -18734 -15280 -2519 5937 -1820 10817 10936 7815 287 -18279 14205 -3018 -8619 2827 -9135 -11865 -10635 -978 -2768 -3623 -4475 -9373 5677 -69 1409 -2121 4875 -5943 1774 10150 8888 -17700 5041 -1465 -21053 15251 -19379 13249 35 -655 17600 18738 12595 15032 -4811 -2972 2366 -8358 -1175 -14689 10150 -734 -821 -12046 -249 433 944 -6479 -4280 344 5220 5551 5504 -1847 -5049 1272 165 9059 15889 -3155 -3899 5731 -371 18535 6318 1367 12553 -7287 -4656 10481 -5538 -297 -2261 -1982 9556 6066 5582 9993 -5763 -13623 13092 -8951 -534 -6233 -4927 -16837 8457 -1858 2564 -9844 -5942 699 -8308 16740 -1189 -4194 1608 -11766 -1206 -4855 -3064 -2983 1000 -8746 252 -4311 -36 8155 -3437 3323 9347 -4882 8540 -397 12799 11360 -2175 -3973 12862 13899 SO 20191016T094900.0Z 7228.409028 226 1 32.01 2 87.93 99.12 73.08 300.27 0.00 1 0.00 1 0 15 1.012e-01 1.027e-01 5.991e-02 5.788e-02 8.407474e+03 4.314642e+03 3.692165e+02 -6.000000e+00 5.903340e+03 283.89 -2.00 20.00 -2.00 505.23 0.00e+00 5.851796e-03 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