File name: Pandora125s1_Cordoba_20191016_L2Fit_fwvt1c5d20170323p1-8.txt File generation date: 20250324T135335.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20191016_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20191016 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2356 492.3572 492.4787 492.6001 492.7216 492.8431 492.9645 493.0859 493.2073 493.3287 493.4501 493.5714 493.6927 493.8141 493.9354 494.0566 494.1779 494.2992 494.4204 494.5416 494.6628 494.7840 494.9052 495.0263 495.1474 495.2686 495.3897 495.5107 495.6318 495.7529 495.8739 495.9949 496.1159 496.2369 496.3579 496.4788 496.5997 496.7206 496.8415 496.9624 497.0833 497.2041 497.3250 497.4458 497.5666 497.6874 497.8081 497.9289 498.0496 498.1703 498.2910 498.4117 498.5323 498.6530 498.7736 498.8942 499.0148 499.1354 499.2560 499.3765 499.4970 499.6175 499.7380 499.8585 499.9790 500.0994 500.2198 500.3403 500.4606 500.5810 500.7014 500.8217 500.9420 501.0624 501.1826 501.3029 501.4232 501.5434 501.6636 501.7838 501.9040 502.0242 502.1444 502.2645 502.3846 502.5047 502.6248 502.7449 502.8649 502.9850 503.1050 503.2250 503.3450 503.4649 503.5849 503.7048 503.8247 503.9446 504.0645 504.1844 504.3042 504.4241 504.5439 504.6637 504.7835 504.9032 505.0230 505.1427 505.2624 505.3821 505.5018 505.6215 505.7411 505.8607 505.9803 506.0999 506.2195 506.3391 506.4586 506.5781 506.6976 506.8171 506.9366 507.0561 507.1755 507.2949 507.4143 507.5337 507.6531 507.7725 507.8918 508.0111 508.1304 508.2497 508.3690 508.4882 508.6074 508.7267 508.8459 508.9650 509.0842 509.2034 509.3225 509.4416 509.5607 509.6798 509.7988 509.9179 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191016T094027.0Z 7228.403090 218 1 32.01 2 89.72 100.24 71.54 301.65 0.00 1 0.00 1 0 29 1.448e-01 1.294e-01 1.274e-01 1.217e-01 -1.471154e+03 7.585490e+03 6.762162e+02 -6.000000e+00 8.438581e+03 283.89 -2.00 20.00 -2.00 505.17 0.00e+00 9.636904e-03 3.441994e-03 5.633876e-04 -6.000000e+00 4.163973e-03 283.89 -2.00 20.00 -2.00 499.92 0.00e+00 4.031362e+00 2.527880e+00 1.327178e-01 -6.000000e+00 2.964171e+00 228.61 -2.00 3.11 -2.00 501.55 0.00e+00 20.065 0.067 489.00 513.00 1 9.9417e+00 1.9488e-01 3.3474e-02 -6.0000e+00 2.2741e-01 1.1007e-01 4.8826e-02 2.1559e-03 -6.0000e+00 5.9066e-02 3.7921e-06 1.5757e-02 1.3277e-02 2.6160e-04 -6.0000e+00 1.6848e-02 -6.6934e-02 -2.5953e-04 12 8 8 10 0 0 96.60 21.32 3.22 -0.06693 0.04236 8 2 1 4 0 4000.000 26.94 19.98 21.32 -9251 2118 58 -12762 16203 1464 10394 -9218 -6732 2764 30384 11790 -11503 -7900 10298 24186 1841 -1317 -50 -10425 9709 41911 -539 24603 18111 2424 -1341 -4164 22028 -15219 33798 5524 -1127 -7026 5666 -6538 71 -8109 22292 -935 -2764 -8458 -16761 -2105 -484 10878 -3232 -9120 14736 13421 -17532 -19560 -11504 -304 1280 -7503 42077 -4765 755 -4558 10837 19519 -5205 1216 -2914 11121 -5390 -8758 9665 15372 2717 -13357 -1553 10240 15335 27753 12264 9880 -10773 2194 -975 -7942 -3765 -12405 7169 -22400 17343 5122 7497 509 -15627 -5656 18270 -22826 -9757 -1536 -2667 36432 1163 14219 -16812 -10731 -4049 17729 -17387 4043 -4729 17678 6144 -6127 4774 5977 468 5975 9998 9175 16764 -1387 -19871 -773 20101 15181 20662 -3230 24441 10270 -7056 35909 2712 28050 20222 263 -18188 5510 18278 33282 -3289 4044 -21005 14054 26538 20542 4950 19206 -15358 -8223 -5526 -14651 -11051 -10332 2159 62 -16051 15636 1667 10932 -11793 -8321 3057 25037 11505 -13969 -9165 9937 20454 1976 -1485 -57 -13112 10000 31354 -620 22141 17476 2733 -1555 -4875 19345 -18977 25652 5630 -1258 -7821 6143 -7343 74 -9107 20060 -976 -2967 -9752 -21323 -2343 -534 10703 -3630 -10695 13328 12005 -20910 -23523 -12806 -308 1311 -8575 29692 -5399 811 -5164 10556 17460 -5949 1293 -3186 10390 -5839 -9661 8742 12986 2592 -15001 -1558 9160 12955 20411 10360 8445 -11242 2006 -921 -8051 -3667 -13192 6270 -26270 13617 4531 6482 476 -17395 -5790 14889 -28131 -10473 -1496 -2571 23174 1028 10882 -17544 -10665 -3823 13568 -18835 3496 -4418 13177 5190 -5967 4270 5406 456 5582 9042 8389 14162 -1392 -23700 -753 15782 12523 16223 -3242 18704 9085 -7434 24625 2588 20630 15877 248 -20426 4874 14351 22824 -3301 3819 -25678 12152 20309 16741 4723 15843 -17707 -8664 -5547 -15872 -11533 SO 20191016T094444.0Z 7228.406065 222 1 32.00 2 88.82 99.68 72.31 300.95 0.00 1 0.00 1 0 22 9.568e-02 9.171e-02 7.980e-02 7.755e-02 5.320721e+03 5.540582e+03 1.098807e+03 -6.000000e+00 5.576300e+03 283.89 -2.00 20.00 -2.00 505.32 0.00e+00 1.686322e-03 2.213633e-03 1.019524e-04 -6.000000e+00 2.745035e-03 283.89 -2.00 20.00 -2.00 499.90 0.00e+00 2.475102e+00 1.637866e+00 1.241806e-01 -6.000000e+00 1.946840e+00 228.61 -2.00 3.11 -2.00 501.62 0.00e+00 18.220 0.050 489.00 513.00 1 9.9610e+00 1.2641e-01 2.7522e-02 -6.0000e+00 1.4957e-01 1.1643e-01 3.1949e-02 1.7710e-03 -6.0000e+00 3.8502e-02 6.0249e-06 3.6442e-03 8.4923e-03 1.6937e-04 -6.0000e+00 1.1159e-02 4.5992e-02 -3.5887e-04 12 9 8 11 8 0 -747.65 21.31 2.73 0.04599 0.07127 8 2 1 4 0 4000.000 26.94 19.99 21.31 17984 -6686 5411 7617 988 11190 -3193 -3008 -1968 9825 21883 6235 -17962 13273 -2054 5440 12098 5564 16402 -13899 -11573 -2085 5318 -1506 10109 10282 7201 241 -14241 15122 -2689 -7240 2576 -7915 -9963 -9030 -908 -2557 -3347 -4111 -8229 5670 -73 1314 -1940 4737 -5323 1711 11114 9867 -15642 5546 -1528 -18005 18223 -16141 14815 6 -655 20874 23331 13883 17178 -4497 -2870 2404 -7882 -1220 -13436 12785 -798 -885 -11224 -282 436 995 -6533 -4466 354 6036 6419 6318 -1972 -5136 1350 164 10670 20733 -3251 -3969 6350 -406 24588 7122 1485 16248 -7633 -5122 14126 -6162 -406 -2552 -2173 11408 6894 6361 12157 -5873 -12905 16383 -8658 68 -6077 -4841 -14813 9377 -1863 2681 -9246 -5858 740 -8177 22186 -1282 -4282 1697 -11159 -1290 -4937 -2532 -3142 1104 -8884 226 -4549 -111 9338 -3492 3477 10510 -4733 9410 -410 14982 13221 -2159 -3984 16136 17680 15278 -7435 5494 7786 1106 11516 -3837 -3614 -2324 10179 19800 6503 -23572 12651 -2284 5674 12032 6034 16200 -18719 -15268 -2506 5950 -1810 10822 10936 7809 275 -18296 14205 -3009 -8601 2847 -9121 -11859 -10634 -978 -2769 -3624 -4477 -9378 5672 -78 1397 -2138 4858 -5965 1755 10133 8871 -17727 5022 -1490 -21089 15229 -19416 13225 6 -685 17577 19203 12570 15009 -4840 -2998 2344 -8384 -1197 -14717 10685 -763 -852 -12081 -273 417 933 -6494 -4298 323 5197 5527 5480 -1873 -5073 1256 154 9052 15884 -3170 -3921 5709 -393 18525 6313 1363 12550 -7297 -4670 10464 -5579 -352 -2326 -2036 9534 6067 5598 10006 -5763 -13644 13070 -8990 65 -6271 -4965 -16881 8431 -1875 2563 -9835 -5934 694 -8335 16715 -1226 -4229 1579 -11798 -1233 -4876 -2421 -2984 993 -8775 205 -4378 -104 8099 -3493 3280 9316 -4915 8520 -410 12805 11384 -2133 -3935 12872 13880 SO 20191016T094900.0Z 7228.409028 226 1 32.01 2 87.93 99.12 73.08 300.27 0.00 1 0.00 1 0 15 1.013e-01 1.028e-01 5.992e-02 5.790e-02 8.484866e+03 4.324678e+03 3.841239e+02 -6.000000e+00 5.905394e+03 283.89 -2.00 20.00 -2.00 505.23 0.00e+00 5.861604e-03 1.628320e-03 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