File name: Pandora125s1_Cordoba_20191207_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250324T140901.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20191207_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20191207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191207T101537.4Z 7280.427516 282 1 50.70 2 76.59 108.48 137.68 234.55 0.00 1 0.00 1 0 25 3.186e-01 2.126e-02 3.201e-01 1.791e-02 5.348445e-01 9.746095e-03 5.831388e-03 -6.000000e+00 1.844737e-01 229.12 -2.00 3.11 -2.00 321.29 0.00e+00 9.866883e-03 4.441104e-03 2.011417e-03 -6.000000e+00 8.467807e-03 286.44 -2.00 20.00 -2.00 320.64 0.00e+00 4.207 0.001 302.00 328.00 3 3.4403e+00 3.3558e-02 4.7542e-02 -6.0000e+00 4.6067e-01 3.5229e-01 4.2588e-02 2.5366e-02 -6.0000e+00 5.0091e-01 -3.9394e-01 3.5995e-02 1.6301e-02 -6.0000e+00 2.9616e-01 1.5693e-01 1.7622e-02 9.6305e-03 -6.0000e+00 1.2713e-01 1.4652e-04 -1.5324e-03 5.4583e-04 1.2524e-04 -6.0000e+00 8.6448e-03 -1.6366e-03 0.0000e+00 12 8 8 10 0 0 99.79 20.98 0.31 -0.00164 -0.01315 21 4 1 5 0 2414.099 26.62 20.00 20.98 900000 900000 -37971 -91814 900000 -93312 900000 60214 900000 71416 1185 153595 -12505 -61352 -81568 -73749 -19339 900000 42505 28594 -55846 70635 7940 -20525 4788 31259 -43107 -22637 27528 900000 -11930 -25017 -13226 -43086 195186 -5697 -1507 -13816 -9789 9861 25985 16087 10563 12583 -12743 -11353 11016 31068 -4976 13247 5621 10883 21613 10602 11030 38346 -1765 -9267 8957 -8445 1099 -3267 12338 10093 13611 11029 11015 10312 4062 9518 9106 -2400 -1350 8644 -5614 6156 -5725 -1757 -10959 5364 -446 284 -6003 -4975 2878 -6748 -973 -1892 3131 -2433 3031 -4904 5059 -1490 5957 1827 1749 -2588 -200 -794 -2087 -599 -3007 4294 -3443 -1258 -2244 -114 -566 -432 185 -790 1863 -452 25 27 168 81 -490 716 -16 -1530 1055 2659 1496 1127 -454 2005 -145 612 -562 1759 -1159 -85 667 -657 -103 554 -490 253 1041 -1002 -1395 900000 900000 -685 -2816 900000 -2301 900000 1050 900000 1245 21 2679 -218 -1987 -4064 -4088 -699 900000 953 794 -3679 1277 262 -915 170 868 -2534 -1053 775 900000 -576 -1628 -878 -4219 3404 -344 -90 -1056 -888 867 2175 1582 1149 1387 -1831 -1639 1291 3138 -734 1675 821 1661 3204 1872 2028 5461 -381 -2234 1745 -1915 231 -775 2816 2640 3664 2960 2798 2722 1207 3063 3284 -1022 -568 3138 -2167 1889 -1878 -537 -3931 1911 -196 141 -3490 -3016 1709 -4719 -679 -1381 2296 -1835 2022 -3263 2841 -881 3548 1299 1431 -2525 -210 -853 -2258 -576 -2686 3532 -3296 -1257 -2373 -126 -673 -567 266 -1209 2926 -696 36 37 225 114 -735 1124 -26 -2404 1648 3949 2150 1559 -609 2653 -218 1017 -1028 3320 -2335 -179 1479 -1559 -264 1437 -1289 640 2471 -2286 -3074 SU 20191207T104710.0Z 7280.449421 295 1 16.02 2 70.16 104.91 142.70 225.71 0.00 1 0.00 1 0 25 9.548e-02 9.899e-03 6.256e-02 5.085e-03 3.701875e-01 2.582173e-03 3.867805e-03 -6.000000e+00 5.414022e-02 229.12 -2.00 3.11 -2.00 319.90 0.00e+00 -6.610544e-04 7.701659e-04 2.148876e-04 -6.000000e+00 2.413769e-03 286.44 -2.00 20.00 -2.00 319.11 0.00e+00 2.915 0.000 302.00 328.00 3 2.7179e+00 7.5689e-03 3.2839e-02 -6.0000e+00 1.3482e-01 4.4297e-02 8.9957e-03 1.7430e-02 -6.0000e+00 1.4617e-01 -3.3370e-02 6.8089e-03 8.4938e-03 -6.0000e+00 8.7208e-02 6.5924e-03 3.5125e-03 2.5585e-03 -6.0000e+00 3.7162e-02 1.3470e-03 -8.0900e-04 1.5170e-04 2.7847e-05 -6.0000e+00 2.4714e-03 -1.9169e-03 0.0000e+00 12 9 9 12 1 1 54.37 20.97 0.33 -0.00192 -0.00800 26 17 1 5 0 587.077 26.62 19.99 20.97 -15516 -41169 -9797 10961 -16526 21917 -45047 -2529 -54136 794 -37697 1950 -22866 4185 -24800 14907 -7182 -2913 -8419 -11523 7925 -4996 -3018 -17225 -3833 -5674 10485 -17549 7198 -3748 4347 2671 6858 1608 -7219 836 -6573 6087 -7001 5398 -3478 4165 611 2530 -2924 2253 61 3916 -1239 100 645 -597 4718 122 5764 -373 2265 585 3931 2410 537 899 3050 1704 1107 2496 736 1428 -611 2593 -582 2120 -2191 1659 -950 235 1025 -318 377 -1090 -103 -735 -506 -3485 -624 -2052 9 -1490 -634 312 489 -491 1247 456 332 2506 -1647 1488 -970 96 -874 -40 -1034 548 -865 -1288 -924 -885 172 20 194 -571 140 108 892 152 706 -88 456 -254 141 -150 -444 553 86 1511 260 2040 186 1094 472 205 -320 370 -748 -104 -136 171 -12 -470 38 -908 97 -351 -1395 -274 246 -439 364 -1511 -63 -2590 24 -1715 60 -1014 167 -1563 726 -473 -194 -626 -924 543 -389 -247 -1735 -366 -586 942 -2007 598 -337 383 267 733 196 -926 93 -833 789 -1259 1032 -822 973 154 637 -776 608 17 1020 -338 27 184 -189 1524 44 2064 -146 892 236 1498 913 210 374 1369 849 577 1217 339 679 -291 1367 -354 1328 -1445 1017 -599 132 513 -152 186 -621 -67 -536 -401 -2987 -554 -1986 9 -1580 -671 318 464 -431 989 379 293 2241 -1727 1696 -1232 122 -1050 -43 -1127 593 -1032 -1528 -1142 -1149 234 30 307 -944 225 164 1337 214 980 -129 705 -422 238 -251 -721 858 127 2114 379 2913 293 1724 799 362 -582 696 -1517 -221 -297 381 -27 -1036 81 -1833 203 SU 20191207T105359.0Z 7280.454155 298 1 50.05 2 68.76 104.16 143.70 223.54 0.00 1 0.00 1 0 25 4.264e-02 5.023e-03 2.007e-02 1.728e-03 3.463618e-01 8.787760e-04 3.640313e-03 -6.000000e+00 2.418033e-02 229.12 -2.00 3.11 -2.00 319.97 0.00e+00 5.168128e-04 2.637737e-04 2.884833e-04 -6.000000e+00 1.078017e-03 286.44 -2.00 20.00 -2.00 319.17 0.00e+00 2.734 0.000 302.00 328.00 3 1.5289e+00 2.5807e-03 3.0828e-02 -6.0000e+00 6.0213e-02 2.7728e-02 3.0664e-03 1.6402e-02 -6.0000e+00 6.5284e-02 -9.9050e-03 2.3280e-03 8.0096e-03 -6.0000e+00 3.8949e-02 -3.6881e-03 1.2026e-03 2.3269e-03 -6.0000e+00 1.6598e-02 5.3915e-03 -8.5853e-04 5.1873e-05 2.4925e-05 -6.0000e+00 1.1037e-03 -2.1711e-03 0.0000e+00 10 0 0 10 0 0 98.51 20.97 0.28 -0.00217 -0.00862 319 63 1 5 0 156.882 26.62 20.00 20.97 -11563 -19110 -8237 -11837 -16626 -20063 -10140 -17028 -3229 -9701 -6254 -9906 -12391 -5346 -6769 -1226 -159 2379 -4506 -1453 -4765 -1523 -4234 -1868 -3115 -451 -2561 457 -5243 -4572 -305 -928 1531 1146 -1456 -2750 -2953 -2931 880 615 -327 -365 -640 -936 -545 563 -1133 -607 170 989 737 1324 1158 1774 631 981 490 389 733 538 1248 891 1849 2297 1708 322 200 -646 438 1677 527 156 231 202 -29 185 657 -499 103 494 -918 -757 -1407 -1594 -783 -822 -304 -418 -3 269 309 400 232 586 527 670 326 567 -57 -465 -233 -669 -455 -124 -371 -932 -702 -678 -320 108 -163 -83 -100 359 166 498 479 93 79 -273 -604 -306 37 12 494 677 673 1199 776 424 488 36 153 39 -386 -381 -223 278 -1 -47 -82 -150 -447 -274 -566 -234 -344 -456 -522 -245 -496 -98 -344 -218 -360 -516 -245 -372 -73 -10 156 -336 -110 -386 -119 -342 -156 -284 -42 -251 44 -498 -419 -28 -97 173 141 -177 -318 -360 -414 145 122 -74 -88 -161 -253 -147 151 -308 -162 45 259 204 397 374 605 228 363 187 150 291 210 491 376 851 1149 892 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