File name: Pandora125s1_Cordoba_20191210_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250324T140858.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20191210_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20191210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191210T093435.0Z 7283.399017 223 1 50.08 2 84.84 113.78 110.77 276.75 0.00 1 0.00 1 0 25 8.724e-01 1.699e-01 5.491e-01 1.327e-01 8.663578e-01 7.746362e-02 1.441224e-02 -6.000000e+00 5.200217e-01 229.14 -2.00 3.11 -2.00 320.00 0.00e+00 -6.727203e-02 1.274702e-02 2.983379e-03 -6.000000e+00 2.677708e-02 286.59 -2.00 20.00 -2.00 318.51 0.00e+00 9.584 0.007 302.00 328.00 3 -4.8577e-02 2.1677e-01 1.2457e-01 -6.0000e+00 1.3000e+00 2.3619e+00 2.5710e-01 1.3537e-01 -6.0000e+00 1.4160e+00 -1.7442e+00 1.4379e-01 1.9299e-02 -6.0000e+00 8.3183e-01 3.8658e-01 7.0143e-02 4.8315e-02 -6.0000e+00 3.5469e-01 1.6895e-05 9.6269e-03 3.5148e-03 4.4584e-04 -6.0000e+00 2.3627e-02 -3.8063e-03 0.0000e+00 12 9 8 11 8 0 -7.13 21.28 1.38 -0.00381 0.06853 21 4 1 5 0 2384.688 26.94 20.00 21.28 3174 192245 900000 -57878 -13620 -11415 900000 -3544 900000 37498 900000 -10951 900000 6633 900000 48696 43030 189452 -26121 900000 48070 900000 -48230 13161 -29280 900000 25142 435005 56678 23598 213358 26465 140459 -26699 367132 -10896 900000 -67587 273295 826 900000 67147 900000 15886 86514 900000 104772 -24174 900000 77876 -20459 900000 -36472 900000 900000 900000 137541 900000 -4015 900000 -135 72835 247453 -15115 48226 -16369 165363 -43438 900000 -34022 78405 5505 72258 -21361 900000 -43476 -54550 13226 -32703 130544 26859 135911 5587 205686 -19788 123663 -10698 46386 -1867 -4991 52740 29211 49796 75393 115972 -11727 -9953 419 41662 -5545 21986 14088 34146 19547 46983 -117 3514 36010 24708 43983 -11697 22943 16338 18116 -1990 3989 -16411 3096 -5633 -14599 11956 -24171 8697 -11200 12185 -20601 -5869 3595 11379 1691 6337 -6117 -656 17876 -8621 -3423 -2180 5758 -1822 6007 -7869 4820 7469 625 24770 900000 -13107 -1755 -1471 900000 -900 900000 10541 900000 -4894 900000 1789 900000 7451 6411 24410 -6836 900000 6194 900000 -18443 3938 -17890 900000 8673 56049 7303 3547 27490 3751 18098 -6536 47304 -2012 900000 -32511 35213 352 900000 16110 900000 4658 11147 900000 13500 -6452 900000 10034 -6119 900000 -15273 900000 900000 900000 17722 900000 -1494 900000 -38 9746 31884 -5468 9082 -5516 21306 -20450 900000 -19639 15759 2327 14896 -10128 900000 -19046 -25479 3124 -13344 16820 7931 17512 2520 26502 -13413 20783 -7012 16891 -1046 -2656 14477 10094 13999 17662 20376 -8311 -7753 326 22448 -4612 13220 8125 15084 10434 20467 -85 2566 20326 18306 30602 -15825 23206 17788 18790 -2397 4369 -22309 3800 -7907 -22573 13622 -37537 9437 -14431 12064 -27243 -7016 4323 14743 2748 10842 -12742 -1394 34420 -23451 -9237 -5929 15494 -5177 14843 -20755 10557 16077 SU 20191210T094856.1Z 7283.408982 226 1 50.11 2 82.03 112.04 113.71 275.09 0.00 1 0.00 1 0 25 5.045e-01 2.819e-02 3.486e-01 1.656e-02 7.776012e-01 9.698699e-03 7.970006e-03 -6.000000e+00 2.921484e-01 229.14 -2.00 3.11 -2.00 322.29 0.00e+00 1.017599e-03 5.586359e-03 1.000000e-02 -6.000000e+00 1.428882e-02 286.59 -2.00 20.00 -2.00 321.80 0.00e+00 6.735 0.002 302.00 328.00 3 3.4105e-01 3.9622e-02 9.8151e-02 -6.0000e+00 7.3148e-01 1.0627e+00 5.0705e-02 9.4198e-02 -6.0000e+00 7.9747e-01 -1.3903e+00 3.6990e-02 2.9668e-02 -6.0000e+00 4.7077e-01 5.4931e-01 1.7475e-02 9.1743e-03 -6.0000e+00 1.9948e-01 2.4027e-04 -2.7564e-03 4.9502e-04 9.9621e-05 -6.0000e+00 1.3528e-02 -3.8925e-03 0.0000e+00 12 8 8 10 0 0 27.75 21.30 0.46 -0.00389 -0.02461 126 25 1 5 0 397.647 26.94 20.00 21.30 -77475 900000 -64916 900000 -50574 900000 -3170 -23798 900000 -92233 18681 -84122 900000 -94324 173088 12315 167221 30344 900000 -23283 900000 27372 11375 2402 23639 112299 -31301 900000 -36160 158287 -68465 41566 10869 900000 105165 25368 22972 45264 100239 11223 210738 40330 233057 15443 71536 34642 14583 20815 93422 5498 44384 39128 38504 45222 68842 78417 17714 76429 12185 39689 12865 41260 -1089 58893 18196 28450 18715 5480 22505 16562 20972 12964 16581 -5524 22967 -11907 15795 -24959 10394 10235 2683 -8317 534 -2394 429 2251 -1057 2359 -618 4545 1271 12581 -6552 2846 -4260 459 -4224 -1407 381 -4612 1712 -6299 2186 -6683 1226 -4449 80 -3378 -1867 -2681 -1282 -2089 -2748 2085 -3503 2912 -1642 1172 -2477 1537 -2790 4102 1544 4633 942 3488 3319 582 1243 -175 2050 -22 1686 -1170 1334 -534 477 248 498 -550 -749 -119 -2742 -4015 900000 -3402 900000 -1776 900000 -57 -540 900000 -4461 301 -3617 900000 -6140 2791 382 2696 888 900000 -1227 900000 781 360 85 704 1811 -1592 900000 -1679 2552 -4725 1126 456 900000 1763 851 785 1429 2155 694 3398 2195 3758 1089 2787 1908 1012 1357 3013 443 2614 2688 2888 3392 4295 4770 2012 4761 1366 3171 1311 3326 -150 5050 2547 3735 2615 884 3283 2937 3977 2797 3424 -1336 3774 -2563 2330 -5453 1743 2046 688 -2756 181 -892 164 947 -484 1077 -291 1971 533 4388 -2646 1065 -1912 243 -2754 -1037 311 -4090 1357 -4864 1381 -4466 809 -3328 64 -2989 -1790 -2954 -1586 -2848 -3889 2772 -4714 3518 -2069 1502 -3716 2327 -4392 5775 2133 6032 1230 4298 3944 729 1762 -291 3993 -48 3781 -2882 3446 -1490 1349 712 1428 -1538 -1952 -286 -6407 SU 20191210T100525.0Z 7283.420429 231 1 50.06 2 78.76 110.09 117.09 273.14 0.00 1 0.00 1 0 17 3.939e-01 1.183e-02 2.064e-01 4.333e-03 6.078746e-01 2.365933e-03 6.145504e-03 -6.000000e+00 2.234418e-01 229.14 -2.00 3.11 -2.00 321.69 0.00e+00 4.951373e-03 1.274596e-03 4.383992e-04 -6.000000e+00 9.964533e-03 286.59 -2.00 20.00 -2.00 321.11 0.00e+00 4.951 0.001 302.00 328.00 3 2.5679e-01 8.8963e-03 5.5751e-02 -6.0000e+00 5.5642e-01 2.4372e-01 1.2199e-02 3.0678e-02 -6.0000e+00 6.0318e-01 -2.9080e-01 1.1622e-02 1.5617e-02 -6.0000e+00 3.5989e-01 1.0883e-01 5.4339e-03 7.2209e-03 -6.0000e+00 1.5343e-01 1.7592e-03 -1.5386e-03 1.2908e-04 7.7730e-05 -6.0000e+00 1.0196e-02 -4.1662e-03 0.0000e+00 12 9 8 11 8 0 28.72 21.30 0.27 -0.00417 -0.01573 386 77 1 5 0 129.671 26.94 19.99 21.30 -169315 -71650 -173308 -41584 -158216 32647 -191761 28724 -115351 -52459 -137974 -34925 -71434 -88098 16949 -56188 5755 -58795 37524 -66502 24477 -35768 749 -42661 721 -52229 31103 -13847 -16169 19767 -30317 43689 -29832 27894 -23322 43348 -24291 22136 -10642 27215 3173 1337 16378 -526 11158 10039 18058 -2888 17876 -2409 17969 1817 20658 8164 11300 1895 4588 6962 -27 4965 -2537 8038 -874 11464 4120 9389 -679 3110 1487 3879 -178 4265 1944 1198 2940 -3959 2581 -6242 298 -3636 1061 -1163 878 -1554 100 575 -728 532 -769 1931 -1383 1232 -2914 391 -2614 1146 -954 953 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