File name: Pandora125s1_Cordoba_20191212_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250324T140647.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20191212_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20191212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191212T153802.2Z 7285.651414 5 1 50.37 2 11.02 40.67 164.89 235.32 0.00 1 0.00 1 0 17 8.041e-03 5.555e-03 4.132e-04 2.223e-04 1.256937e-01 1.111773e-04 1.388384e-03 -6.000000e+00 4.565848e-03 229.16 -2.00 3.11 -2.00 316.34 0.00e+00 2.893533e-04 1.232494e-05 1.303930e-05 -6.000000e+00 2.040885e-04 286.70 -2.00 20.00 -2.00 315.51 0.00e+00 1.019 0.000 302.00 328.00 3 -1.2409e-01 2.9023e-04 1.1384e-02 -6.0000e+00 1.1370e-02 2.8704e-02 3.2412e-04 5.8694e-03 -6.0000e+00 1.2329e-02 -1.1609e-03 1.8598e-04 2.8650e-03 -6.0000e+00 7.3511e-03 -5.6946e-03 8.5646e-05 8.1855e-04 -6.0000e+00 3.1555e-03 2.1021e-01 -7.7198e-04 6.3513e-06 9.8017e-06 -6.0000e+00 2.1003e-04 -8.4065e-03 0.0000e+00 10 0 0 10 0 0 36.02 21.81 0.25 -0.00841 -0.01421 4219 840 1 5 0 11.817 27.35 19.96 21.81 900000 -729 -472 -1460 -2869 -1315 -49 1875 2550 1759 -286 -595 456 260 704 258 -843 -416 -149 131 435 -500 248 298 40 150 92 -489 -102 442 1735 1698 2318 1341 -1403 -1216 -908 -560 286 -141 -974 -1174 -980 -1190 -960 -596 -1041 -777 -889 -585 543 830 821 1147 570 694 821 487 337 570 903 1169 1364 1469 573 -423 -24 -437 639 1186 297 298 -34 254 186 44 271 -154 368 220 -554 -722 -1569 -1553 -919 -755 -477 -291 -107 37 80 263 -19 590 777 379 327 539 118 -213 -99 -510 -322 252 -167 -931 -635 -840 -523 47 33 92 61 194 57 302 383 153 152 -61 -488 -200 -11 227 661 931 545 1167 722 455 528 41 95 -30 -265 -348 -268 175 -143 -128 -8 -331 -474 900000 -192 -127 -381 -697 -280 -10 420 638 476 -78 -155 122 77 230 92 -314 -154 -56 50 171 -197 96 118 17 64 40 -202 -40 161 617 630 900 549 -558 -446 -344 -240 145 -80 -620 -782 -667 -820 -654 -402 -724 -515 -562 -356 331 532 552 800 410 503 604 360 245 430 690 940 1119 1274 505 -365 -19 -313 458 947 266 282 -33 238 166 38 205 -106 263 163 -462 -662 -1550 -1593 -995 -834 -559 -354 -131 44 95 281 -19 548 732 388 367 627 147 -267 -124 -589 -349 277 -201 -1209 -857 -1182 -758 68 49 139 93 273 78 377 466 194 207 -90 -714 -311 -17 330 904 1286 710 1474 956 641 775 62 143 -46 -406 -566 -448 298 -248 -219 -14 -571 -799 SU 20191212T154343.2Z 7285.655361 8 1 50.40 2 10.28 34.83 165.81 232.02 0.00 1 0.00 1 0 17 7.955e-03 5.565e-03 4.107e-04 2.193e-04 1.257410e-01 1.093392e-04 1.388791e-03 -6.000000e+00 4.515189e-03 229.16 -2.00 3.11 -2.00 316.30 0.00e+00 2.695161e-04 1.205912e-05 1.408802e-05 -6.000000e+00 2.013419e-04 286.71 -2.00 20.00 -2.00 315.48 0.00e+00 1.016 0.000 302.00 328.00 3 -1.5062e-01 2.8545e-04 1.1365e-02 -6.0000e+00 1.1244e-02 3.0871e-02 3.1871e-04 5.8670e-03 -6.0000e+00 1.2186e-02 -2.2219e-03 1.8262e-04 2.8678e-03 -6.0000e+00 7.2716e-03 -5.3383e-03 8.3519e-05 8.1614e-04 -6.0000e+00 3.1021e-03 2.1531e-01 -7.4741e-04 6.2332e-06 9.7023e-06 -6.0000e+00 2.0590e-04 -7.5995e-03 0.0000e+00 10 0 0 10 0 0 16.94 21.71 0.25 -0.00760 -0.01322 4293 854 1 5 0 11.611 27.26 19.93 21.71 127 -787 -304 -1289 -2846 -1292 127 1811 2428 1856 -290 -668 341 86 867 331 -864 -333 -181 36 383 -590 260 297 110 181 36 -449 -236 418 1543 1724 2318 1308 -1352 -1046 -883 -521 277 -186 -932 -1285 -949 -1241 -939 -628 -991 -902 -942 -643 470 813 802 1180 603 782 874 574 377 561 881 1185 1356 1511 590 -415 -5 -416 610 1192 364 262 -47 201 222 -12 270 -154 381 206 -512 -767 -1591 -1539 -926 -748 -467 -273 -99 83 77 295 -58 618 762 393 307 538 129 -230 -146 -575 -335 174 -207 -934 -653 -807 -469 80 48 133 98 189 81 292 332 130 117 -49 -473 -234 -28 211 677 949 551 1138 734 404 532 59 95 -38 -246 -369 -233 180 -132 -146 -15 -335 -461 30 -209 -82 -338 -696 -277 27 410 614 506 -80 -175 92 26 285 119 -324 -124 -69 14 152 -234 101 118 46 78 16 -187 -94 153 553 643 905 539 -540 -385 -337 -225 141 -107 -596 -862 -648 -859 -642 -426 -692 -601 -598 -393 288 524 542 826 436 569 646 426 275 425 676 957 1117 1316 522 -359 -4 -298 439 956 327 249 -45 189 198 -10 204 -106 274 153 -428 -706 -1577 -1585 -1005 -830 -550 -334 -122 100 91 315 -59 575 720 403 346 628 161 -288 -183 -665 -364 193 -251 -1216 -884 -1137 -681 121 71 201 150 267 110 365 406 165 159 -73 -693 -364 -42 307 927 1313 719 1440 975 571 783 88 142 -59 -379 -600 -390 307 -230 -251 -27 -579 -778 SU 20191212T154914.2Z 7285.659192 11 1 50.39 2 9.66 28.42 166.67 228.44 0.00 1 0.00 1 0 17 7.974e-03 5.575e-03 4.072e-04 2.176e-04 1.253217e-01 1.084213e-04 1.383216e-03 -6.000000e+00 4.525159e-03 229.16 -2.00 3.11 -2.00 316.30 0.00e+00 2.786901e-04 1.196160e-05 1.358339e-05 -6.000000e+00 2.018150e-04 286.71 -2.00 20.00 -2.00 315.47 0.00e+00 1.014 0.000 302.00 328.00 3 -1.6255e-01 2.8310e-04 1.1338e-02 -6.0000e+00 1.1269e-02 3.0097e-02 3.1612e-04 5.8469e-03 -6.0000e+00 1.2214e-02 -1.5107e-03 1.8112e-04 2.8570e-03 -6.0000e+00 7.2880e-03 -5.7072e-03 8.2818e-05 8.1494e-04 -6.0000e+00 3.1086e-03 2.1851e-01 -7.1002e-04 6.1906e-06 9.6656e-06 -6.0000e+00 2.0639e-04 -6.6973e-03 0.0000e+00 10 0 0 10 0 0 22.20 21.60 0.25 -0.00670 -0.01203 4342 864 1 5 0 11.480 27.15 19.92 21.60 201 -740 -448 -1348 -2899 -1241 -89 1850 2424 1887 -327 -633 489 66 784 405 -812 -340 -227 166 392 -605 151 267 34 178 1 -442 -86 353 1629 1633 2259 1366 -1405 -1095 -888 -507 247 -183 -969 -1204 -930 -1200 -900 -591 -1083 -802 -953 -622 469 914 783 1178 581 737 847 529 352 570 921 1174 1367 1472 645 -448 -31 -409 663 1246 349 263 -46 216 198 68 236 -120 361 214 -536 -743 -1586 -1566 -943 -779 -462 -279 -52 27 53 269 -11 577 762 367 314 549 120 -172 -126 -568 -324 186 -207 -938 -668 -807 -497 93 17 131 61 182 81 235 345 116 130 -38 -463 -216 6 233 703 967 541 1145 703 433 528 63 106 -8 -292 -330 -245 179 -142 -155 -24 -339 -470 48 -197 -122 -354 -709 -266 -19 419 614 514 -90 -166 132 20 258 146 -304 -127 -86 64 156 -240 59 106 14 77 0 -183 -34 129 584 610 884 562 -562 -403 -339 -219 126 -105 -621 -807 -636 -831 -616 -421 -757 -534 -605 -380 287 589 530 825 420 537 626 393 257 432 706 949 1127 1283 570 -388 -24 -293 477 1000 314 250 -45 204 177 59 179 -83 259 159 -449 -685 -1573 -1612 -1025 -864 -544 -341 -65 33 62 287 -12 537 720 377 354 640 150 -216 -158 -657 -351 205 -251 -1221 -904 -1138 -722 141 26 197 93 257 109 293 422 148 177 -57 -679 -336 9 339 962 1337 706 1450 934 611 776 95 160 -12 -449 -536 -411 306 -247 -266 -42 -586 -793 SU 20191212T155458.1Z 7285.663173 14 1 50.29 2 9.15 20.98 167.51 224.26 0.00 1 0.00 1 0 17 7.941e-03 5.571e-03 4.076e-04 2.182e-04 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