File name: Pandora125s1_Cordoba_20191213_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250324T140907.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20191213_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20191213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191213T105843.9Z 7286.457452 264 1 33.79 2 68.10 104.45 99.32 292.06 0.00 1 0.00 1 0 17 9.613e-02 1.076e-02 7.449e-02 6.972e-03 3.145926e-01 3.533797e-03 3.308031e-03 -6.000000e+00 5.451478e-02 229.17 -2.00 3.11 -2.00 319.67 0.00e+00 -3.209507e-04 9.578424e-04 1.078102e-04 -6.000000e+00 2.433205e-03 286.75 -2.00 20.00 -2.00 318.85 0.00e+00 2.657 0.000 302.00 328.00 3 3.9001e+00 1.0151e-02 2.9340e-02 -6.0000e+00 1.3575e-01 4.0832e-02 1.1895e-02 1.4707e-02 -6.0000e+00 1.4718e-01 -2.6796e-03 8.6216e-03 7.2172e-03 -6.0000e+00 8.7819e-02 -4.0223e-03 4.4848e-03 2.0696e-03 -6.0000e+00 3.7427e-02 5.6470e-04 -8.6072e-04 2.1020e-04 2.2481e-05 -6.0000e+00 2.4882e-03 -1.5296e-03 0.0000e+00 12 9 9 12 9 1 99.77 20.92 0.18 -0.00153 -0.00800 17 5 1 5 0 1867.720 26.51 20.01 20.92 37296 -24941 -19033 4883 -26492 -204 6514 63601 -20389 37737 -8318 -7797 -30125 -5118 649 13099 -3969 -808 -3922 -3005 19745 -16191 17352 -12246 9692 -3544 8551 -11485 8611 1089 6040 -2112 2907 12924 -3697 3445 -14094 2251 -1111 4826 -6929 5895 -1394 2394 -3843 2331 -2839 -622 3036 -2021 -47 2208 696 -3799 1802 -1529 4159 -1126 2798 -1101 4521 1088 2088 2714 -644 1985 239 -448 -427 690 -484 1268 -987 3126 -129 1419 347 -1953 1637 -393 66 -1587 576 -3452 1148 -1834 933 -1410 490 -1146 505 5 -473 591 352 922 -1088 1419 1193 605 -1268 -374 -1154 1387 -1462 -467 -474 -2112 613 -614 406 -94 822 -834 439 -756 724 -779 -149 53 -686 95 287 872 1024 1113 -583 1289 -262 841 574 1046 -494 -796 561 -278 355 -301 -52 -287 538 -719 -489 740 -1060 -809 167 -1112 -6 185 1147 -976 1104 -391 -364 -1942 -300 42 848 -327 -67 -355 -281 1593 -1867 1437 -1446 989 -436 951 -1498 852 112 618 -271 391 1686 -547 446 -2291 359 -222 1091 -1983 1577 -416 700 -1193 682 -868 -182 888 -622 -15 742 254 -1540 722 -650 1715 -493 1152 -462 1823 484 1009 1415 -359 1068 120 -219 -218 396 -314 853 -686 2019 -81 788 184 -995 826 -228 43 -1188 457 -2989 1011 -1791 940 -1512 519 -1202 486 4 -406 479 301 868 -1170 1661 1431 775 -1559 -416 -1200 1425 -1680 -567 -600 -2853 849 -925 646 -154 1309 -1267 642 -1046 973 -1105 -225 85 -1143 155 455 1322 1572 1630 -820 1771 -392 1355 983 1844 -901 -1517 1119 -592 772 -672 -117 -632 1127 -1463 -964 SU 20191213T110825.0Z 7286.464179 267 1 50.09 2 66.10 103.39 101.16 290.96 0.00 1 0.00 1 0 25 2.175e-02 4.996e-03 5.019e-03 6.908e-04 2.925054e-01 3.470750e-04 3.092722e-03 -6.000000e+00 1.233239e-02 229.17 -2.00 3.11 -2.00 319.35 0.00e+00 2.439473e-04 8.474730e-05 9.814256e-05 -6.000000e+00 5.504466e-04 286.75 -2.00 20.00 -2.00 318.50 0.00e+00 2.450 0.000 302.00 328.00 3 1.5469e-01 9.8289e-04 2.7110e-02 -6.0000e+00 3.0710e-02 3.6545e-02 1.1407e-03 1.3660e-02 -6.0000e+00 3.3295e-02 -7.6576e-03 7.8450e-04 6.6632e-03 -6.0000e+00 1.9867e-02 -5.0012e-03 4.0531e-04 1.8692e-03 -6.0000e+00 8.4667e-03 3.0109e-02 -7.8499e-04 2.0574e-05 2.0487e-05 -6.0000e+00 5.6288e-04 -1.4706e-03 0.0000e+00 10 0 0 10 0 0 97.96 20.95 0.23 -0.00147 -0.00737 1493 297 1 5 0 33.476 26.62 20.01 20.95 -8392 -5186 -6042 -5729 -12014 -7496 -8106 -2001 -5079 -1412 -4050 -6948 -2402 -4388 -1269 -1157 -1218 -2127 -1081 -2175 -441 -2005 -391 -1287 -719 -1241 -925 -1082 -1601 -429 -275 1232 739 1573 -2492 -1989 -1663 -542 151 668 -144 -513 -77 -752 -272 -428 -581 -449 -273 -260 1210 823 1227 1388 870 1077 951 619 233 398 866 1583 1583 2038 820 -59 206 -148 504 1171 454 349 15 104 364 -126 498 -376 336 -25 -198 -822 -1562 -1657 -1078 -858 -570 -341 -298 143 -3 535 -13 691 780 446 243 635 128 -162 -177 -792 -423 21 -100 -988 -555 -917 -342 13 84 56 113 200 80 324 303 203 22 -88 -630 -263 -22 282 622 989 374 1215 628 441 523 8 91 -111 -231 -367 -171 175 -36 -140 71 -306 -359 -346 -237 -295 -286 -569 -310 -345 -89 -267 -78 -231 -406 -147 -319 -104 -107 -121 -221 -117 -247 -51 -234 -47 -165 -98 -179 -136 -152 -210 -53 -36 173 114 258 -407 -320 -280 -104 35 183 -45 -169 -26 -262 -94 -149 -200 -151 -90 -86 410 303 480 573 377 476 432 299 111 186 408 790 865 1200 503 -34 109 -76 267 700 304 248 11 73 251 -79 277 -197 179 -15 -136 -633 -1309 -1455 -1002 -857 -603 -374 -329 153 -3 485 -11 577 681 433 263 765 158 -201 -219 -903 -446 22 -116 -1235 -722 -1254 -489 21 136 93 184 304 119 448 414 289 33 -145 -1068 -439 -36 439 916 1384 532 1705 950 724 850 14 156 -197 -437 -736 -352 368 -77 -291 151 -629 -719 SU 20191213T111925.1Z 7286.471819 272 1 24.27 2 63.82 102.19 103.26 289.73 0.00 1 0.00 1 0 17 2.787e-02 6.126e-03 1.813e-02 3.278e-03 2.671027e-01 1.643539e-03 2.856425e-03 -6.000000e+00 1.581108e-02 229.17 -2.00 3.11 -2.00 318.89 0.00e+00 2.112837e-04 3.500344e-04 1.786862e-04 -6.000000e+00 7.055764e-04 286.75 -2.00 20.00 -2.00 318.02 0.00e+00 2.253 0.000 302.00 328.00 3 2.9450e+00 4.5349e-03 2.4903e-02 -6.0000e+00 3.9373e-02 4.7682e-02 5.1949e-03 1.2535e-02 -6.0000e+00 4.2683e-02 -6.5755e-03 3.3922e-03 6.0937e-03 -6.0000e+00 2.5468e-02 -2.5491e-03 1.7459e-03 1.7245e-03 -6.0000e+00 1.0857e-02 2.2985e-03 -5.8338e-04 9.6948e-05 1.8863e-05 -6.0000e+00 7.2148e-04 -3.1859e-03 0.0000e+00 12 1 1 12 1 1 99.95 20.97 0.13 -0.00319 -0.00757 51 21 1 5 0 463.514 26.62 20.01 20.97 -8186 1349 1404 5427 -19469 -3953 -10324 10745 -3602 2230 2379 -8821 -1455 -632 623 1470 2865 -3223 3844 -4034 -2026 -939 3795 -1617 -483 870 -1334 -2856 -2799 -1384 -2274 5659 -58 2740 -2467 481 -5090 2060 -606 2088 349 -948 -1409 -1075 802 103 -723 -1113 340 -1071 859 583 665 682 357 1641 909 1212 94 637 -1086 1781 573 2516 154 -183 -71 -3 564 712 422 524 407 -693 963 -1283 971 -832 506 -106 -110 -881 -2028 -1677 -993 -309 -264 60 -239 629 88 793 -246 887 4 656 -55 650 115 -149 220 -576 -594 -186 137 -1118 -251 -1230 -343 129 97 92 205 5 -417 559 230 -98 -64 -45 -888 -149 -93 625 248 794 528 1283 820 362 595 -158 392 -257 -289 -487 27 279 212 -97 -68 -392 -506 -495 84 92 334 -1366 -216 -612 575 -253 160 171 -702 -123 -61 69 172 351 -434 530 -624 -317 -145 557 -263 -83 155 -246 -512 -463 -216 -370 925 -11 536 -512 91 -1067 463 -169 673 122 -353 -545 -445 324 42 -293 -442 130 -412 337 247 300 325 178 822 469 626 48 319 -595 1010 339 1575 101 -119 -42 -2 330 473 313 410 322 -537 691 -849 597 -484 296 -70 -83 -695 -1745 -1503 -941 -313 -284 67 -269 683 95 775 -221 747 3 636 -59 781 150 -195 270 -651 -667 -211 169 -1397 -324 -1679 -486 195 155 150 325 8 -608 751 305 -136 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