File name: Pandora125s1_Cordoba_20191216_L2Fit_fout2c3d20170323p1-8.txt File generation date: 20250228T141414.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20191216_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20191216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 214 355 Nominal wavelengths inside fitting window [nm]: 305.0972 305.2384 305.3797 305.5210 305.6622 305.8035 305.9447 306.0859 306.2272 306.3684 306.5095 306.6507 306.7919 306.9330 307.0742 307.2153 307.3564 307.4975 307.6386 307.7797 307.9208 308.0619 308.2029 308.3439 308.4850 308.6260 308.7670 308.9080 309.0490 309.1899 309.3309 309.4719 309.6128 309.7537 309.8946 310.0355 310.1764 310.3173 310.4582 310.5990 310.7399 310.8807 311.0215 311.1624 311.3032 311.4439 311.5847 311.7255 311.8662 312.0070 312.1477 312.2884 312.4291 312.5698 312.7105 312.8512 312.9919 313.1325 313.2732 313.4138 313.5544 313.6950 313.8356 313.9762 314.1168 314.2573 314.3979 314.5384 314.6789 314.8194 314.9599 315.1004 315.2409 315.3814 315.5218 315.6623 315.8027 315.9431 316.0835 316.2239 316.3643 316.5047 316.6451 316.7854 316.9257 317.0661 317.2064 317.3467 317.4870 317.6273 317.7675 317.9078 318.0481 318.1883 318.3285 318.4687 318.6089 318.7491 318.8893 319.0295 319.1696 319.3098 319.4499 319.5900 319.7301 319.8702 320.0103 320.1504 320.2904 320.4305 320.5705 320.7105 320.8505 320.9905 321.1305 321.2705 321.4105 321.5504 321.6904 321.8303 321.9702 322.1101 322.2500 322.3899 322.5298 322.6697 322.8095 322.9494 323.0892 323.2290 323.3688 323.5086 323.6484 323.7881 323.9279 324.0676 324.2074 324.3471 324.4868 324.6265 324.7662 324.9058 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191216T101222.9Z 7289.425265 246 1 21.86 2 77.72 109.97 60.25 323.42 0.00 1 0.00 1 0 17 4.761e-01 1.731e-02 2.890e-01 7.901e-03 5.893552e-01 4.349025e-03 5.923009e-03 -6.000000e+00 2.718996e-01 229.19 -2.00 3.11 -2.00 321.42 0.00e+00 3.543142e-03 2.194874e-03 4.511812e-04 -6.000000e+00 1.326703e-02 286.89 -2.00 20.00 -2.00 320.81 0.00e+00 4.566 0.001 302.00 328.00 3 7.2911e-01 1.5574e-02 5.1909e-02 -6.0000e+00 6.7890e-01 2.4911e-01 2.0898e-02 2.8710e-02 -6.0000e+00 7.3667e-01 -3.0033e-01 1.9245e-02 1.4800e-02 -6.0000e+00 4.3826e-01 1.1710e-01 9.0998e-03 6.2625e-03 -6.0000e+00 1.9025e-01 1.5812e-03 4.6000e-04 2.3702e-04 6.6760e-05 -6.0000e+00 1.2554e-02 2.0121e-02 0.0000e+00 12 9 9 12 9 1 97.60 21.05 0.26 0.02012 0.02358 46 21 1 5 0 461.363 26.62 20.00 21.05 -174503 900000 -150009 14856 -81181 -135735 5596 -134803 900000 -117632 900000 -137699 900000 -108485 900000 -85743 134763 -26408 107068 46763 -20554 34047 -11007 146643 -56916 154422 -26049 127611 -44028 900000 -15233 166082 -19375 23692 -7620 20605 36738 -10778 46932 -24063 46317 7243 33182 236 32635 -3079 26225 16105 16231 16934 775 23263 745 18311 4452 26451 1875 20694 -4498 19279 -2413 5074 1967 1934 3444 5241 9366 -4240 10252 -3524 5136 -4517 6570 206 7217 -97 3045 -1250 -353 2452 296 -1203 -6733 2054 -3303 328 -1899 656 -2008 1730 613 92 -1832 -522 -291 -1298 318 -1902 747 -1359 176 -2415 1699 -2133 -706 -384 -250 -1054 -779 -320 -585 1028 -743 1727 -1438 2112 -1419 566 -1007 888 -750 1113 301 1342 711 -268 2154 -23 1248 609 1314 -291 858 -951 237 -401 635 -522 -728 427 -397 -654 -4604 900000 -3636 114 -812 -2350 43 -2853 900000 -2353 900000 -4079 900000 -3798 900000 -3299 1037 -660 824 644 -549 524 -281 1128 -2605 1188 -876 982 -1694 900000 -586 1278 -1060 831 -342 722 1256 -719 2127 -2541 2614 635 2312 23 2467 -337 2172 1516 1587 1778 107 2801 121 2660 770 3783 345 3063 -831 3004 -501 1101 497 527 908 1296 2216 -1225 2948 -1308 1853 -1803 2243 69 2155 -28 836 -384 -126 1000 141 -645 -4045 1200 -2181 221 -1357 460 -1406 1092 362 55 -1109 -340 -218 -1130 312 -1973 825 -1450 167 -2123 1414 -1988 -692 -393 -272 -1250 -1025 -464 -905 1572 -1115 2375 -1931 2928 -2126 884 -1686 1465 -1219 1707 451 1904 976 -354 2829 -35 2077 1116 2536 -596 1832 -2210 574 -1004 1597 -1333 -1803 985 -939 -1492 SU 20191216T101809.0Z 7289.429271 249 1 50.04 2 76.57 109.31 60.96 322.13 0.00 1 0.00 1 0 25 3.818e-01 1.872e-02 3.063e-01 1.316e-02 5.527566e-01 7.168440e-03 5.695612e-03 -6.000000e+00 2.201595e-01 229.19 -2.00 3.11 -2.00 321.36 0.00e+00 4.801792e-03 3.434749e-03 9.116179e-04 -6.000000e+00 1.002568e-02 286.89 -2.00 20.00 -2.00 320.72 0.00e+00 4.200 0.001 302.00 328.00 3 1.8599e+00 2.5212e-02 4.7965e-02 -6.0000e+00 5.5060e-01 2.6731e-01 3.2813e-02 2.6439e-02 -6.0000e+00 5.9824e-01 -2.5338e-01 2.9184e-02 1.4232e-02 -6.0000e+00 3.5398e-01 8.7286e-02 1.4029e-02 6.0315e-03 -6.0000e+00 1.5116e-01 7.2157e-04 1.7810e-05 4.0022e-04 7.3437e-05 -6.0000e+00 1.0195e-02 2.0383e-02 0.0000e+00 12 8 8 10 0 0 98.06 21.04 0.32 0.02038 0.02052 81 16 1 5 0 617.711 26.62 19.99 21.04 151970 -32572 900000 -190187 -115051 -129493 900000 -73644 900000 -152014 -77500 -87706 -36427 -67122 -51095 900000 -53262 -32597 19514 20722 -53729 75880 -60037 69288 -31423 97951 -32406 57341 21894 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-1842 481 -1299 -545 -2027 -1436 -1057 -33 2334 -212 -350 -2002 518 -826 452 -2561 -436 -1941 -587 -655 -312 982 -2289 -1292 -3308 -486 -2372 1736 -922 857 972 1033 -622 933 604 -1142 2107 -679 -427 -828 555 -2009 2924 -1972 3803 1488 892 2533 1804 2226 2922 2322 -2450 -1626 -1450 892 -1574 504 -106 -975 -1330 -474 SU 20191216T102446.8Z 7289.433875 252 1 49.67 2 75.24 108.55 61.80 320.68 0.00 1 0.00 1 0 25 3.135e-01 1.681e-02 2.430e-01 1.114e-02 5.087437e-01 6.026445e-03 5.187782e-03 -6.000000e+00 1.824327e-01 229.19 -2.00 3.11 -2.00 321.10 0.00e+00 -1.791462e-04 2.680606e-03 4.673890e-04 -6.000000e+00 8.607266e-03 286.89 -2.00 20.00 -2.00 320.45 0.00e+00 3.845 0.000 302.00 328.00 3 2.2456e+00 2.0414e-02 4.3986e-02 -6.0000e+00 4.5569e-01 1.5541e-01 2.6077e-02 2.4335e-02 -6.0000e+00 4.9522e-01 -1.4554e-01 2.3148e-02 1.2132e-02 -6.0000e+00 2.9079e-01 5.2013e-02 1.1391e-02 3.4920e-03 -6.0000e+00 1.2387e-01 7.4651e-04 7.3098e-04 3.4434e-04 4.2197e-05 -6.0000e+00 8.6439e-03 2.1979e-02 0.0000e+00 12 8 8 10 0 0 99.80 21.02 0.46 0.02198 0.02747 50 10 1 5 0 993.341 26.62 19.99 21.02 -137781 -58106 -154624 900000 -112311 900000 900000 900000 177109 42283 900000 -51204 99487 -55998 5767 -42494 20157 -44009 3117 -2969 8349 38755 22250 6946 8635 52842 -27298 -4480 3352 -50225 4734 46579 -28090 -13404 -12648 -828 25945 14206 19655 -4562 18429 -11236 985 -683 18489 3568 6241 1792 17598 -13624 22431 3275 319 5389 -6859 19400 -5884 9011 835 -2514 3297 10192 2917 -859 1736 2986 9635 391 5756 -4888 7992 -1110 2063 671 4743 5200 559 565 -613 -3737 -571 -638 -5077 151 -2190 1459 -4292 1731 -281 2280 669 1076 -541 1929 425 -1418 3226 -209 -378 -878 2263 -3570 376 -3286 -1549 -3536 -1213 -1858 580 -121 127 636 -1225 2457 -1683 1036 -578 -102 -364 613 -393 1050 1201 518 510 505 2273 1135 876 385 1291 -278 1030 -228 -570 -1209 276 -42 -388 190 -1126 406 -3558 -766 -5394 900000 -2133 900000 900000 900000 1922 459 900000 -988 1080 -1688 111 -1486 405 -1804 84 -88 221 763 555 229 299 1213 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