File name: Pandora125s1_Cordoba_20191221_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250324T141002.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20191221_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20191221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191221T093758.5Z 7294.401371 285 1 50.92 2 84.92 114.47 44.02 61.89 0.00 1 0.00 1 0 25 6.773e-01 1.384e-01 4.615e-01 1.121e-01 8.246913e-01 6.099589e-02 8.692508e-03 -6.000000e+00 3.866497e-01 229.19 -2.00 3.11 -2.00 319.37 0.00e+00 -5.636013e-03 9.276881e-03 3.284399e-03 -6.000000e+00 1.773916e-02 287.14 -2.00 20.00 -2.00 318.21 0.00e+00 9.693 0.007 302.00 328.00 3 -7.1275e-01 1.6474e-01 1.0158e-01 -6.0000e+00 9.6244e-01 2.6447e+00 1.8853e-01 4.7048e-02 -6.0000e+00 1.0444e+00 -1.9679e+00 1.0519e-01 1.7859e-02 -6.0000e+00 6.2198e-01 5.2849e-01 5.3699e-02 9.9293e-03 -6.0000e+00 2.6586e-01 2.5464e-05 1.7862e-03 2.9614e-03 1.4814e-04 -6.0000e+00 1.7907e-02 -4.3066e-04 0.0000e+00 12 8 8 10 0 0 11.29 20.90 1.18 -0.00043 0.01299 27 5 1 5 0 1885.655 26.51 20.03 20.90 243219 24778 115868 38903 277153 -18050 -17961 71593 -18166 5945 -7527 37129 -16980 9562 -22483 159272 9111 67350 14222 -3544 900000 900000 43993 65912 900000 -10043 22972 20601 53662 48305 40633 -85034 96139 -34692 155162 -5564 -68294 900000 10561 48938 -10512 66615 51886 900000 -26901 -25112 264090 85517 -30309 -27278 -35417 87827 120542 33940 112288 12652 900000 -9431 53615 23725 281011 15458 -13113 -1241 168075 21406 92465 -15399 -1236 53422 38196 90440 211024 -6945 16881 83781 -22880 8786 -2535 -21920 59059 63714 10376 41817 40768 22448 63670 9840 4578 -11011 -3541 63329 -40137 62658 8204 10391 9669 36348 19850 13085 -21690 8054 11086 13158 -25327 -3847 537 -6770 8999 9147 12381 -4945 26139 -1281 7175 -20867 14103 -7632 9831 1415 12211 567 -1303 -9511 -6691 -13336 -1859 8653 -14063 13556 -8946 -302 -5249 2013 -2913 392 1860 3676 -3330 3919 -1787 -3291 16594 26550 9754 17248 10681 30254 -5732 -5466 9525 -6135 1561 -2131 6586 -5677 2773 -10047 17386 3263 13325 4808 -1348 900000 900000 8056 9980 900000 -3289 5015 4123 6639 5976 5914 -48888 10495 -13255 16938 -1299 -29820 900000 2703 9763 -4075 12036 10923 900000 -10802 -9301 28828 9668 -10871 -9678 -15035 11718 13158 8508 13165 4041 900000 -3546 10130 5478 30675 3829 -4735 -438 18347 5932 12516 -6186 -464 13063 11675 16586 23036 -3033 5067 11051 -7909 2198 -784 -9671 13431 16329 4925 15084 15479 10654 20549 5464 2607 -6898 -1968 16654 -28479 16478 4193 6032 6525 22484 15787 11087 -24015 5819 6915 7934 -23961 -3079 452 -6540 8202 9486 13988 -7125 27963 -1756 8576 -31662 15963 -11225 12821 2065 15575 769 -1722 -13224 -9211 -18925 -2278 10128 -23965 20223 -18608 -620 -12065 4626 -7580 1038 5243 10314 -9963 10392 -4659 -8093 32392 SU 20191221T095203.0Z 7294.411146 288 1 50.07 2 82.17 112.76 41.44 58.57 0.00 1 0.00 1 0 25 5.332e-01 2.401e-02 4.133e-01 1.484e-02 7.502350e-01 8.380825e-03 7.569788e-03 -6.000000e+00 3.026648e-01 229.19 -2.00 3.11 -2.00 322.24 0.00e+00 1.135124e-02 5.189837e-03 2.868804e-03 -6.000000e+00 1.386114e-02 287.14 -2.00 20.00 -2.00 321.75 0.00e+00 6.844 0.003 302.00 328.00 3 3.1495e-02 3.5292e-02 8.0121e-02 -6.0000e+00 7.5372e-01 9.5241e-01 4.4517e-02 5.6665e-02 -6.0000e+00 8.1727e-01 -1.1377e+00 3.4982e-02 1.8247e-02 -6.0000e+00 4.8794e-01 4.4069e-01 1.6723e-02 1.3146e-02 -6.0000e+00 2.0885e-01 2.9356e-04 -2.2756e-03 4.2882e-04 1.3560e-04 -6.0000e+00 1.3936e-02 -1.0714e-03 0.0000e+00 12 8 8 10 0 0 19.57 20.95 0.39 -0.00107 -0.01817 149 30 1 5 0 335.990 26.62 20.00 20.95 27295 -51201 -71804 900000 -142057 47514 -166897 48278 -23517 12506 -77890 47150 -50528 -51948 60295 -35886 154802 -30111 11720 -43065 900000 -17168 900000 -54833 60366 -37862 107982 30127 299188 82102 64432 -6720 -40556 158789 -13371 144301 -10899 195292 60319 48413 34720 60663 74402 38816 7502 88043 60956 9359 88541 6751 50401 23289 37181 70839 40089 32567 39867 37172 42631 24827 -7971 21767 3835 58141 12388 34033 11770 15400 20056 23112 18026 8566 19126 -1287 2649 -14682 1877 -17822 11620 -10440 5357 -3438 2414 -1651 2728 -303 1430 7352 -2973 1836 -4068 -2092 -5427 -2660 -5107 -3842 -4199 -724 645 1466 -155 -1459 -4085 1100 -5588 -6151 -873 -2358 -261 -381 -978 -2459 226 -1836 358 -445 1118 -869 -369 1181 -297 1277 1544 2885 -35 3758 2085 2349 52 2077 485 909 806 -188 -752 -495 -139 240 323 -349 628 -1210 -1315 395 -1164 -2114 900000 -7152 687 -8492 698 -340 181 -1585 682 -947 -1329 872 -1198 2239 -1139 306 -1964 900000 -554 900000 -2409 873 -1446 1562 540 4327 1187 932 -241 -2370 2296 -645 2087 -466 2824 1636 1721 1569 2230 2466 1871 514 2713 2491 653 2895 522 2725 1830 2759 4191 3373 2997 3433 3225 3335 2220 -990 2161 517 5445 1996 4383 1832 2333 3108 3979 3637 1988 3951 -321 575 -3344 330 -3789 2033 -2733 1425 -1153 850 -676 1129 -137 671 3357 -1510 862 -1895 -889 -2272 -1162 -2560 -2238 -2888 -560 553 1284 -131 -1118 -2862 753 -4378 -5175 -734 -2161 -257 -428 -1254 -3479 318 -2590 471 -565 1485 -1234 -554 1834 -466 1887 2178 3898 -46 4695 2547 3147 81 3675 972 1959 1837 -460 -1992 -1383 -397 692 931 -975 1621 -2952 -3280 SU 20191221T100153.0Z 7294.417975 291 1 50.08 2 80.24 111.59 39.69 56.05 0.00 1 0.00 1 0 25 4.687e-01 1.388e-02 2.607e-01 6.127e-03 6.441209e-01 3.384141e-03 6.420401e-03 -6.000000e+00 2.676082e-01 229.19 -2.00 3.11 -2.00 321.88 0.00e+00 4.262609e-03 1.948595e-03 2.133535e-03 -6.000000e+00 1.211192e-02 287.14 -2.00 20.00 -2.00 321.31 0.00e+00 5.630 0.001 302.00 328.00 3 8.7649e-02 1.3347e-02 6.4335e-02 -6.0000e+00 6.6602e-01 3.6709e-01 1.8294e-02 3.9860e-02 -6.0000e+00 7.2218e-01 -4.4661e-01 1.7047e-02 1.6138e-02 -6.0000e+00 4.3000e-01 1.7139e-01 7.8783e-03 7.8536e-03 -6.0000e+00 1.8341e-01 1.0712e-03 -1.3949e-03 1.8247e-04 7.1836e-05 -6.0000e+00 1.2194e-02 -8.9814e-04 0.0000e+00 12 8 8 10 0 0 27.62 20.92 0.36 -0.00090 -0.01138 310 62 1 5 0 161.518 26.51 19.98 20.92 -13680 -143217 900000 -153055 93574 -198469 900000 -188748 -101562 -163679 -71077 -139751 67080 -18305 4810 18627 -41951 74063 -71667 220996 -74031 -25976 -97108 6638 -46872 47128 -4390 -22660 -9663 -44653 4861 -23411 27815 -12004 78607 -17641 17299 -19879 25852 1373 24157 19228 14391 28190 10816 29029 -2809 26450 -1851 16717 11287 14289 4436 15914 12731 16962 12457 15188 12155 5568 12860 5254 10812 3745 9044 3158 6841 -3 8757 7657 6027 266 6665 1994 2439 4321 -1789 1747 -5034 3413 -5168 633 -2373 249 -2979 -554 -565 -1383 157 -1740 1633 -2326 -732 -3548 767 -2751 368 -1305 -92 591 -295 -547 -128 747 -1446 -12 -3123 199 -1809 295 -910 -547 -244 -513 -69 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