File name: Pandora125s1_Cordoba_20200210_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250324T142629.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200210_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200210T103043.8Z 7345.438007 235 1 49.61 2 82.26 102.24 84.36 289.90 0.00 1 0.00 1 0 17 8.199e-01 4.669e-02 4.232e-01 2.886e-02 7.217163e-01 1.684546e-02 7.241389e-03 -6.000000e+00 4.858002e-01 229.07 -2.00 3.11 -2.00 322.12 0.00e+00 3.022200e-03 8.824446e-03 8.414214e-03 -6.000000e+00 2.443222e-02 288.64 -2.00 20.00 -2.00 321.55 0.00e+00 6.909 0.003 302.00 328.00 3 1.0199e+00 6.4806e-02 9.2847e-02 -6.0000e+00 1.2141e+00 1.1371e+00 8.2831e-02 8.6143e-02 -6.0000e+00 1.3268e+00 -1.3176e+00 5.9269e-02 2.6893e-02 -6.0000e+00 7.8118e-01 4.9180e-01 2.8262e-02 9.3474e-03 -6.0000e+00 3.2805e-01 1.0240e-04 -1.4841e-03 8.8140e-04 6.4083e-05 -6.0000e+00 2.2674e-02 -2.1432e-04 0.0000e+00 12 9 8 11 8 0 19.17 21.07 0.55 -0.00021 -0.01137 56 11 1 5 0 885.783 26.73 20.01 21.07 359748 71335 8202 900000 -7383 900000 -74157 900000 -81336 900000 -120825 118133 -19066 -10462 -10919 900000 26262 117809 900000 -26934 900000 10474 59818 78116 900000 -16043 900000 -27211 900000 31004 -4330 394115 -1532 900000 -52255 900000 -40346 900000 9155 144601 -2003 900000 33024 73630 98702 647 900000 56900 380390 -7671 299009 23995 268828 -25887 223267 11103 109425 5241 61995 56235 38258 52013 60509 42514 -21917 100843 -28299 64405 -956 29187 18702 10609 8241 44429 239 3311 40640 -13377 25620 -24567 12092 -4107 18922 -5777 14360 -1745 3693 4599 13803 -2946 4277 8017 -10773 -1047 -4820 2818 -8934 764 -5122 6066 -5051 4091 -1284 -5473 2609 -3633 4359 -7732 3103 -4829 2008 -7087 3633 -3434 3897 -3931 -3115 -1009 -1496 1496 -2262 7507 -1023 4743 895 3727 245 6891 -3279 176 75 1746 1781 -1006 3146 -352 68 -765 3061 -3304 1140 -3141 -109 10093 2001 302 900000 -243 900000 -3802 900000 -4800 900000 -10287 3314 -688 -419 -525 900000 1079 3305 900000 -1970 900000 472 1678 2192 900000 -967 900000 -1640 900000 934 -207 11057 -98 900000 -5526 900000 -3439 900000 622 4057 -197 900000 2520 3718 3766 65 900000 3193 10672 -861 8389 2412 7542 -4902 6264 1545 5756 766 4856 4596 3687 4632 5536 5238 -5508 7258 -7111 6442 -206 5323 4198 2692 2112 7422 56 663 5321 -2967 4210 -7910 3183 -1459 5916 -2446 5257 -797 1678 2239 6119 -1492 1878 3149 -4866 -436 -2326 1471 -6438 578 -4576 4954 -4355 2887 -857 -3742 1768 -2795 3438 -7376 2916 -5570 2438 -10184 4779 -4737 4750 -4957 -3899 -1373 -2175 2214 -3460 9998 -1424 6058 1146 4484 294 8482 -5083 302 144 3529 3797 -2352 7581 -929 183 -2107 8115 -8986 2771 -7913 -254 SU 20200210T104042.9Z 7345.444941 238 1 49.87 2 80.18 100.99 86.28 288.54 0.00 1 0.00 1 0 25 5.426e-01 1.629e-02 3.219e-01 1.044e-02 6.191193e-01 5.684528e-03 6.223484e-03 -6.000000e+00 3.075735e-01 229.07 -2.00 3.11 -2.00 321.84 0.00e+00 4.633476e-03 3.187808e-03 4.856735e-04 -6.000000e+00 1.384549e-02 288.64 -2.00 20.00 -2.00 321.25 0.00e+00 5.600 0.001 302.00 328.00 3 1.0100e+00 2.2274e-02 6.1308e-02 -6.0000e+00 7.6523e-01 3.9657e-01 2.9993e-02 3.1326e-02 -6.0000e+00 8.2948e-01 -4.8640e-01 2.6266e-02 1.5434e-02 -6.0000e+00 4.9555e-01 1.8668e-01 1.2221e-02 6.1778e-03 -6.0000e+00 2.1159e-01 4.4775e-04 -1.8862e-03 3.1241e-04 7.1580e-05 -6.0000e+00 1.4046e-02 -5.8419e-05 0.0000e+00 12 8 8 10 0 0 51.07 21.05 0.32 -0.00006 -0.01423 136 27 1 5 0 366.685 26.73 19.98 21.05 -160323 -99987 -147185 -54919 -127855 -159059 87584 -138621 -161177 -85315 -129998 -40074 -131401 208590 -102284 45791 -29419 -7865 -78220 320905 23381 -10852 1505 -23980 56047 -12440 -34680 12098 15616 -52409 121196 36648 9506 17956 30453 -15930 -5931 48716 3207 19684 10353 28907 2218 19207 31861 25278 19984 10696 1751 5889 11524 -5448 26850 11330 19332 17670 23265 3481 -1315 4364 12067 6171 15467 9742 16359 7748 3305 4517 -574 12914 7345 3868 -913 1454 -5504 4853 -342 -1766 3607 143 293 -716 815 -4058 -378 -712 -1261 -2715 790 -653 -1127 145 1464 -317 2502 -87 -343 -1398 -2249 1497 -2645 176 -2577 -1888 -2088 -2297 -3278 -673 -1387 -650 165 -11 929 389 69 -397 -644 423 184 -473 744 492 588 349 811 1960 1347 1324 1416 12 1112 572 99 54 -1516 439 319 99 105 -643 250 -421 -891 -3507 -1433 -3664 -559 -2315 -3676 892 -2823 -4545 -1203 -2902 -408 -3654 2124 -3365 466 -634 -148 -3314 3268 381 -243 29 -635 708 -324 -1144 241 298 -2001 1234 778 307 587 853 -662 -232 1261 165 1028 674 1677 176 1318 1933 1656 1398 834 160 540 1083 -676 2635 1400 2336 2241 2865 522 -210 637 1644 961 2475 1866 3157 1601 684 927 -133 3156 2128 1225 -304 449 -1676 1188 -80 -412 909 44 106 -300 373 -2066 -197 -399 -751 -1701 481 -392 -671 79 744 -164 1384 -57 -261 -1238 -2231 1461 -2547 157 -2138 -1536 -1833 -2159 -3269 -697 -1573 -819 229 -16 1383 564 95 -552 -892 607 282 -769 1200 770 884 510 1134 2782 1842 1847 2211 22 2172 1197 218 126 -3843 1156 862 273 290 -1734 630 -1002 -2194 SU 20200210T104738.0Z 7345.449746 242 1 50.04 2 78.74 100.13 87.61 287.62 0.00 1 0.00 1 0 25 4.746e-01 1.367e-02 2.161e-01 5.804e-03 5.572159e-01 3.144013e-03 5.642828e-03 -6.000000e+00 2.710170e-01 229.07 -2.00 3.11 -2.00 321.54 0.00e+00 1.629497e-03 1.633123e-03 5.354576e-04 -6.000000e+00 1.228200e-02 288.64 -2.00 20.00 -2.00 320.90 0.00e+00 4.942 0.001 302.00 328.00 3 8.8500e-01 1.1657e-02 5.4258e-02 -6.0000e+00 6.7397e-01 2.0421e-01 1.5735e-02 2.7535e-02 -6.0000e+00 7.3118e-01 -2.6490e-01 1.4243e-02 1.3579e-02 -6.0000e+00 4.3513e-01 1.0286e-01 6.6887e-03 4.4869e-03 -6.0000e+00 1.8640e-01 1.0316e-03 -1.3487e-03 1.7636e-04 4.8834e-05 -6.0000e+00 1.2528e-02 -1.2047e-04 0.0000e+00 12 8 8 10 0 0 34.02 21.04 0.38 -0.00012 -0.01026 220 44 1 5 0 227.436 26.62 20.00 21.04 900000 -157689 136840 -156152 -63729 -132490 900000 -135230 -57652 -65228 -133636 20605 -121643 900000 -87748 48791 -83411 324544 3471 49453 -25644 34438 -7207 -12173 -5071 -37112 59406 -34184 60856 -28266 43185 -2314 72177 -2110 47801 -513 13031 10287 1425 9102 607 14703 -8236 29117 -5143 22320 764 22996 736 7082 5923 15725 -222 7673 10410 5965 16700 -2138 19136 -3407 4538 3042 11589 3434 6474 608 3789 2222 -2582 4654 -1665 4876 -348 5701 -1575 3150 -3509 2908 -4505 2494 -1052 -2576 -686 -2432 -1405 -1894 1895 -2011 3003 -1999 1367 -2231 1042 -802 -476 -67 -968 184 -511 393 -1648 378 -2211 1172 -2593 -861 -2164 -335 -1033 143 -15 -114 471 -732 1250 -738 1513 -685 1032 -1170 460 -366 962 266 797 1151 498 1411 99 1132 537 712 -411 488 -933 20 -413 437 -122 65 -46 -692 -253 900000 -3603 774 -3958 -577 -2189 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