File name: Pandora125s1_Cordoba_20200310_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250324T143218.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200310_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200310 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200310T112202.1Z 7374.473635 243 1 50.21 2 76.01 85.81 95.32 272.35 0.00 1 0.00 1 0 25 3.236e-01 2.033e-02 2.620e-01 1.120e-02 4.536528e-01 5.879266e-03 4.654819e-03 -6.000000e+00 1.835208e-01 228.08 -2.00 3.11 -2.00 321.08 0.00e+00 1.760229e-03 2.527873e-03 4.048661e-04 -6.000000e+00 8.542821e-03 288.10 -2.00 20.00 -2.00 320.36 0.00e+00 4.044 0.001 302.00 328.00 3 2.9364e+00 1.9879e-02 4.4062e-02 -6.0000e+00 4.5514e-01 1.6544e-01 2.5072e-02 2.1345e-02 -6.0000e+00 4.9379e-01 -2.5306e-01 2.0396e-02 1.0760e-02 -6.0000e+00 2.9469e-01 1.0172e-01 9.9927e-03 3.3597e-03 -6.0000e+00 1.2603e-01 3.4519e-04 -1.2126e-03 3.4748e-04 4.0874e-05 -6.0000e+00 8.3942e-03 -1.0349e-03 0.0000e+00 12 8 8 10 0 0 94.20 21.32 0.46 -0.00103 -0.01015 61 12 1 5 0 822.981 26.94 20.00 21.32 -107950 38610 -17687 47738 -89810 900000 -148697 111211 -54580 33775 -62749 -61413 900000 -51536 90003 12220 134104 -1951 115798 -46893 51513 -8283 2545 -30972 73579 -22144 -23725 8511 -20713 51414 -1843 52363 -1228 57681 3386 11332 -8968 16751 -20384 30798 14877 5875 19295 8050 12605 -1705 18112 -5462 26656 -3824 32343 4239 6766 9645 11691 -4557 12440 5225 -1143 7209 -10014 10547 -4944 9398 1807 7556 -4153 7508 4169 -1141 3952 1398 945 4023 5863 -7925 3879 -7541 -202 -7568 3109 -1480 -748 -3778 -1092 -349 -2760 1036 -1413 515 -229 5724 -6149 3340 -2851 2765 -2854 2100 -434 -616 350 -2025 -602 -3614 1150 -2152 855 -2356 666 -1129 1755 -2103 293 -433 157 1176 -1574 1147 -864 875 -925 1671 -543 2708 1277 2083 -624 16 341 593 1356 607 1263 -818 -227 -978 969 -366 885 -1170 163 -1580 235 -3747 422 -310 521 -2837 900000 -8059 1214 -1435 396 -1954 -1913 900000 -2001 1019 351 1464 -75 1508 -3230 1363 -393 108 -1938 1731 -1423 -1574 409 -1249 1482 -98 1853 -84 2368 231 668 -678 1127 -2504 2719 1740 802 2397 1143 1709 -268 2341 -890 3303 -655 4115 785 1320 1955 2442 -1153 2729 1292 -293 1660 -2774 2549 -1551 2827 617 2340 -1356 2143 1364 -451 1661 637 435 1726 2296 -3198 1257 -2755 -72 -3359 1436 -810 -445 -2442 -731 -249 -2143 804 -1133 394 -173 3767 -4230 2045 -1994 2069 -2571 2039 -473 -682 362 -2057 -553 -3432 1128 -2332 943 -2837 832 -1574 2590 -3382 456 -647 230 1604 -2188 1620 -1328 1408 -1541 2653 -854 3988 1938 3007 -880 23 526 1012 2481 1173 2504 -1738 -512 -2350 2345 -915 2202 -2892 403 -3776 534 SS 20200310T112930.0Z 7374.478819 246 1 17.91 2 74.43 84.79 96.83 271.38 0.00 1 0.00 1 0 17 3.655e-01 2.520e-02 2.739e-01 1.775e-02 4.033558e-01 9.071355e-03 4.818760e-03 -6.000000e+00 2.064497e-01 228.08 -2.00 3.11 -2.00 320.57 0.00e+00 7.006536e-03 3.304083e-03 2.878364e-03 -6.000000e+00 9.304153e-03 288.10 -2.00 20.00 -2.00 319.81 0.00e+00 3.658 0.000 302.00 328.00 3 3.8447e+00 2.8369e-02 4.0856e-02 -6.0000e+00 5.1253e-01 1.7904e-01 3.4371e-02 2.1773e-02 -6.0000e+00 5.5598e-01 -2.4010e-01 2.5724e-02 1.2797e-02 -6.0000e+00 3.3231e-01 9.9254e-02 1.3034e-02 5.2666e-03 -6.0000e+00 1.4214e-01 2.0499e-04 -1.4561e-03 5.3517e-04 8.4613e-05 -6.0000e+00 9.4580e-03 -1.5948e-03 0.0000e+00 12 9 9 12 9 1 94.05 21.32 0.38 -0.00159 -0.01254 7 5 1 5 0 2218.234 26.94 20.00 21.32 -120163 -3745 48310 -61420 109205 -96526 -60474 -51970 12339 -47997 46697 -85316 -77147 -18888 49689 41262 -7469 235295 26025 105949 3436 156380 -36817 73699 44675 40219 6534 1938 -14656 20546 13350 8440 26795 -34077 33055 -33333 3115 4615 12630 15316 10182 26622 4823 7694 2536 8486 12834 6670 1271 20480 11274 16328 10336 6749 9464 8834 6252 1641 6519 -8207 1138 3046 9788 1648 11042 -1743 6362 3959 9347 -1153 4243 6596 -6785 4112 -3316 -1983 -9180 -9415 -7958 1069 -6675 2884 -960 -807 1765 -3296 -3694 -3258 -277 -1122 3346 -397 1606 -2525 2440 -2806 -568 -416 2117 -3058 -3052 -721 -3099 1654 290 -608 -1232 -2677 -1275 310 -713 1372 -204 239 -142 2259 1851 -1849 1420 662 1186 188 3527 -920 64 1922 2559 2040 -166 -466 704 2817 -619 -1136 -518 -970 -465 1569 -847 899 -1317 -1659 257 -8510 -97 836 -2996 1890 -5317 -2284 -1922 262 -1964 808 -5275 -5024 -841 1352 1429 -462 4073 1287 2445 227 2707 -3490 2369 1989 1923 464 139 -1180 1156 878 665 1971 -4985 2375 -4328 291 483 1454 2135 1670 3929 923 1472 515 1647 2397 1319 265 3564 2270 3407 2458 1765 2649 2532 1870 513 1893 -2715 350 990 3304 666 4258 -731 2288 1416 3512 -548 2135 3419 -4042 2114 -1712 -909 -4076 -3988 -3477 490 -3813 1685 -635 -560 1269 -2679 -3198 -2920 -258 -1030 2744 -310 1133 -1798 1761 -2405 -540 -446 2426 -3732 -3516 -787 -3183 1625 313 -707 -1512 -3519 -1760 458 -1155 2268 -338 374 -207 3012 2453 -2652 2108 1057 1924 303 5701 -1501 98 2785 3499 2811 -255 -789 1267 5179 -1210 -2334 -1125 -2240 -1096 3703 -2064 2102 -3000 -3610 572 SS 20200310T114007.1Z 7374.486193 249 1 50.20 2 72.18 83.33 98.98 270.00 0.00 1 0.00 1 0 25 1.176e-01 1.146e-02 1.391e-01 8.576e-03 3.670083e-01 4.376340e-03 3.871817e-03 -6.000000e+00 6.640486e-02 228.08 -2.00 3.11 -2.00 320.43 0.00e+00 -5.166320e-05 1.518330e-03 6.916215e-04 -6.000000e+00 2.992701e-03 288.10 -2.00 20.00 -2.00 319.63 0.00e+00 3.223 0.000 302.00 328.00 3 3.6117e+00 1.3504e-02 3.5413e-02 -6.0000e+00 1.6486e-01 2.9736e-02 1.6406e-02 1.7820e-02 -6.0000e+00 1.7883e-01 -5.4547e-02 1.2823e-02 8.6256e-03 -6.0000e+00 1.0689e-01 1.8395e-02 6.5226e-03 2.4316e-03 -6.0000e+00 4.5721e-02 4.2482e-04 -1.0169e-03 2.6316e-04 2.8003e-05 -6.0000e+00 3.0422e-03 -1.5774e-03 0.0000e+00 12 8 8 10 0 0 96.65 21.33 0.20 -0.00158 -0.00922 36 7 1 5 0 1394.477 26.94 20.00 21.33 8085 -37590 40590 -15008 -27228 740 -52486 6060 52701 -38729 -23555 -30576 -39737 -22893 -12902 2609 1759 -32773 4826 -1328 -22623 16366 11347 -8441 -15921 394 -7910 2471 -4592 5292 -17286 -6031 10872 -1758 5886 -912 16386 -6145 3766 3876 6003 3033 4068 2968 11981 -7672 2739 -2248 -1945 -1824 -2513 4643 1150 6484 -1739 1593 -2306 3170 -717 -746 1165 4373 4829 4515 1593 2261 3517 -4666 1348 1365 -192 -226 849 -1405 -321 -4663 307 1324 -464 -1436 1758 -2312 -293 -1192 -753 -27 -671 240 -817 -120 -1728 1277 -204 141 1267 881 1285 325 893 -755 621 -477 25 -1356 990 -1598 -546 -2113 -155 -593 110 1015 -1312 1364 -902 1050 -621 832 -1544 358 -1924 54 -53 715 1610 977 2056 1173 1068 46 603 -419 305 -99 -640 -678 736 663 129 -379 -526 -53 -569 120 -1025 561 -357 -657 12 -1536 111 695 -1395 -743 -1043 -1662 -957 -600 120 88 -2445 262 -80 -1748 854 626 -604 -1326 29 -659 186 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